{"id":"https://openalex.org/W2104339773","doi":"https://doi.org/10.1002/pol.1964.100020526","title":"Some considerations of the kinetics of the acid hydrolysis of poly\u2010 and oligosaccharides. II. The trisaccharides, isomaltotriitol, panitol, and isomaltotriose","display_name":"Some considerations of the kinetics of the acid hydrolysis of poly\u2010 and oligosaccharides. II. The trisaccharides, isomaltotriitol, panitol, and isomaltotriose","publication_year":1964,"publication_date":"1964-05-01","ids":{"openalex":"https://openalex.org/W2104339773","doi":"https://doi.org/10.1002/pol.1964.100020526","mag":"2104339773"},"language":"en","primary_location":{"id":"doi:10.1002/pol.1964.100020526","doi":"https://doi.org/10.1002/pol.1964.100020526","is_oa":false,"landing_page_url":"https://doi.org/10.1002/pol.1964.100020526","pdf_url":null,"source":{"id":"https://openalex.org/S4210208317","display_name":"Journal of Polymer Science Part A General Papers","issn_l":"0449-2951","issn":["0449-2951","1542-6246"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310317825","host_organization_name":"Inderscience Publishers","host_organization_lineage":["https://openalex.org/P4310317825"],"host_organization_lineage_names":["Inderscience Publishers"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part A: General Papers","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5032894564","display_name":"Alexander Meller","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210131365","display_name":"Amcor (Australia)","ror":"https://ror.org/02ras5d14","country_code":"AU","type":"company","lineage":["https://openalex.org/I4210131365"]}],"countries":["AU"],"is_corresponding":true,"raw_author_name":"Alexander Meller","raw_affiliation_strings":["Research Laboratory, Australian Paper Manufacturers Limited, Melbourne, Australia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Research Laboratory, Australian Paper Manufacturers Limited, Melbourne, Australia","institution_ids":["https://openalex.org/I4210131365"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5032894564"],"corresponding_institution_ids":["https://openalex.org/I4210131365"],"apc_list":null,"apc_paid":null,"fwci":0.4765,"has_fulltext":false,"cited_by_count":3,"citation_normalized_percentile":{"value":0.56345762,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"2","issue":"5","first_page":"2373","last_page":"2384"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10835","display_name":"Carbohydrate Chemistry and Synthesis","score":0.7836999893188477,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10835","display_name":"Carbohydrate Chemistry and Synthesis","score":0.7836999893188477,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12192","display_name":"Polysaccharides Composition and Applications","score":0.09300000220537186,"subfield":{"id":"https://openalex.org/subfields/1106","display_name":"Food Science"},"field":{"id":"https://openalex.org/fields/11","display_name":"Agricultural and Biological Sciences"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.03999999910593033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/acid-hydrolysis-kinetics","display_name":"acid hydrolysis kinetics","score":0.8920000195503235},{"id":"https://openalex.org/keywords/isomaltotriose","display_name":"isomaltotriose","score":0.9710000157356262},{"id":"https://openalex.org/keywords/isomaltose","display_name":"isomaltose","score":0.9459999799728394},{"id":"https://openalex.org/keywords/trisaccharides","display_name":"trisaccharides","score":0.8069999814033508},{"id":"https://openalex.org/keywords/parallel-and-consecutive-reactions","display_name":"parallel and consecutive reactions","score":0.6759999990463257},{"id":"https://openalex.org/keywords/rate-equations","display_name":"rate equations","score":0.7720000147819519},{"id":"https://openalex.org/keywords/glucose","display_name":"glucose","score":0.32600000500679016},{"id":"https://openalex.org/keywords/sorbitol","display_name":"sorbitol","score":0.996999979019165},{"id":"https://openalex.org/keywords/hydrolysis-rate-constants","display_name":"hydrolysis rate constants","score":0.6499999761581421},{"id":"https://openalex.org/keywords/oligosaccharides","display_name":"oligosaccharides","score":0.8360000252723694},{"id":"https://openalex.org/keywords/polysaccharides","display_name":"polysaccharides","score":0.8560000061988831},{"id":"https://openalex.org/keywords/hydrolysis-yield","display_name":"hydrolysis yield","score":0.4180000126361847}],"concepts":[{"id":"https://openalex.org/C2777129622","wikidata":"https://www.wikidata.org/wiki/Q28487684","display_name":"Isomaltose","level":4,"score":0.9636510014533997},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8449382781982422},{"id":"https://openalex.org/C94412978","wikidata":"https://www.wikidata.org/wiki/Q103135","display_name":"Hydrolysis","level":2,"score":0.8449364900588989},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.6547908186912537},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.5033561587333679},{"id":"https://openalex.org/C16993767","wikidata":"https://www.wikidata.org/wiki/Q4674072","display_name":"Acid hydrolysis","level":3,"score":0.4997289180755615},{"id":"https://openalex.org/C2776779347","wikidata":"https://www.wikidata.org/wiki/Q245280","display_name":"Sorbitol","level":2,"score":0.49407246708869934},{"id":"https://openalex.org/C37263863","wikidata":"https://www.wikidata.org/wiki/Q786897","display_name":"Autocatalysis","level":3,"score":0.43988341093063354},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.4195411205291748},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.28908076882362366},{"id":"https://openalex.org/C2778197599","wikidata":"https://www.wikidata.org/wiki/Q170002","display_name":"Maltose","level":3,"score":0.2607918977737427},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.16525158286094666},{"id":"https://openalex.org/C181199279","wikidata":"https://www.wikidata.org/wiki/Q8047","display_name":"Enzyme","level":2,"score":0.09910720586776733},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/pol.1964.100020526","doi":"https://doi.org/10.1002/pol.1964.100020526","is_oa":false,"landing_page_url":"https://doi.org/10.1002/pol.1964.100020526","pdf_url":null,"source":{"id":"https://openalex.org/S4210208317","display_name":"Journal of Polymer Science Part A General Papers","issn_l":"0449-2951","issn":["0449-2951","1542-6246"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310317825","host_organization_name":"Inderscience Publishers","host_organization_lineage":["https://openalex.org/P4310317825"],"host_organization_lineage_names":["Inderscience Publishers"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part A: General Papers","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":9,"referenced_works":["https://openalex.org/W1575580665","https://openalex.org/W1987345816","https://openalex.org/W1994951398","https://openalex.org/W2007957829","https://openalex.org/W2035147977","https://openalex.org/W2045571802","https://openalex.org/W2085830877","https://openalex.org/W2315581908","https://openalex.org/W2323545986"],"related_works":["https://openalex.org/W2323545986","https://openalex.org/W2324209258","https://openalex.org/W1570764790","https://openalex.org/W2094631358","https://openalex.org/W1982796217","https://openalex.org/W4239852205","https://openalex.org/W2138609027","https://openalex.org/W2094464803","https://openalex.org/W2312215444","https://openalex.org/W2329329641"],"abstract_inverted_index":{"Abstract":[0],"On":[1],"the":[2,5,14,23,46,84,95,106,116,125,129,132,137,153,162,181,191,197,239,246,255,274,298,301,309,314,323,328,335,349,356,360,365,369,377,381,391,394,405,408,411],"basis":[3,299],"of":[4,8,17,36,98,100,109,111,128,131,146,155,176,196,200,242,245,258,276,281,293,300,362,364,368,376,393,407,413],"rate":[6,29,97,108,177,207,257,294,346,361],"data":[7],"Jones,":[9],"Dimler,":[10],"and":[11,41,56,64,68,77,103,119,136,142,148,166,169,171,223,228,236,252,268,318,416],"Rist":[12],"on":[13,297],"acid\u2010catalyzed":[15],"hydrolysis":[16,99,110,133,156,199,259,277,363],"isomaltotriitol":[18],"it":[19],"is":[20,52,61,70,94,105,218,254,372,388],"shown":[21],"that":[22,264,375],"kinetics":[24,195],"can":[25,202],"be":[26,204,333,385],"described":[27,205],"by":[28,32,174,206,291],"equations":[30,178,208,295],"derived":[31,296],"assuming":[33],"a":[34,211,344],"combination":[35],"two":[37,85,247,350],"interdependent":[38],"simultaneous":[39],"(\u201cparallel\u201d)":[40],"consecutive":[42],"reactions":[43],"according":[44],"to":[45,180,210,332,384,390],"scheme:":[47,213],"magnified":[48,214],"image":[49,215],"where":[50,216],"A":[51],"isomaltotriitol;":[53,92],"(B),":[54],"B,":[55],"B*":[57],"are":[58,66,79,88,185,225,230,238],"glucose;":[59,226],"C":[60],"isomaltitol;":[62],"D":[63],"(D)":[65],"sorbitol;":[67],"E":[69],"isomaltose":[71,112,231,261],"present":[72],"at":[73,82,232,343,355],"any":[74,233],"instant;":[75,234],"k1":[76,118,165],"k2":[78,141,170],"specific":[80,96,107,240,256],"rates":[81,241],"which":[83],"glucosidic":[86,248,282,336,366],"bonds":[87,249,337,351],"hydrolytically":[89],"cleaved":[90],"in":[91,186,250,279,338,410],"k3":[93,120,167],"isomaltitol":[101],"(known);":[102],"k4":[104,172,253],"(known).":[113,262],"Values":[114],"for":[115,140,164,273,285,316,404],"constants":[117],"have":[121,157,288],"been":[122,159,289],"computed":[123],"from":[124],"experimental":[126,192,310],"values":[127,139,163,272,315],"composition":[130],"reaction":[134],"mixture":[135],"known":[138],"k4.":[143],"The":[144,194],"yields":[145],"glucose":[147],"sorbitol":[149],"as":[150,152],"well":[151],"extent":[154,275],"then":[158],"calculated":[160,290,324],"using":[161],"(computed)":[168],"(known)":[173],"means":[175,292],"corresponding":[179,209],"above":[182,302],"scheme.":[183,303],"They":[184,304],"very":[187],"good":[188,306],"agreement":[189,307],"with":[190,308],"values.":[193,311,325],"acid":[198],"isomaltotriose":[201,339],"also":[203],"kinetic":[212],"A\u2033":[217],"isomaltotriose;":[219],"(B\u2033),":[220],"B\u2033,":[221],"B\u2033*,":[222],"B**\u2033":[224],"(C\u2033)":[227],"C\u2033":[229],"k5":[235,265,317],"k6":[237,269,319],"hydrolytic":[243],"cleavage":[244,284],"isomaltotriose,":[251],"if":[260],"Assuming":[263],"=":[266,270],"k4/1.3":[267],"k4/1.5,":[271],"(expressed":[278],"terms":[280],"bond":[283],"100":[286],"bonds)":[287],"show":[305],"However,":[312],"transposing":[313],"does":[320],"not":[321,353],"alter":[322],"Thus,":[326],"only":[327],"following":[329],"conclusions":[330],"seem":[331],"permissible:":[334],"most":[340],"likely":[341],"hydrolyze":[342,354],"lower":[345],"than":[347,374],"isomaltose;":[348],"do":[352],"same":[357],"rate;":[358],"whether":[359],"link":[367],"reducing":[370],"unit":[371,379],"slower":[373],"nonreducing":[378],"or":[380],"reverse,":[382],"remains":[383],"established.":[386],"Attention":[387],"drawn":[389],"role":[392],"theoretical":[395],"carbohydrate":[396],"structural":[397],"chemist":[398],"who":[399],"may":[400],"offer":[401],"an":[402],"explanation":[403],"deductions":[406],"kineticist":[409],"field":[412],"both":[414],"trisaccharide":[415],"disaccharide":[417],"hydrolysis.":[418]},"counts_by_year":[{"year":2016,"cited_by_count":1}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}