{"id":"https://openalex.org/W2103994571","doi":"https://doi.org/10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.0.co;2-w","title":"The Combination of Spontaneous Resolution and Asymmetric Catalysis: A Model for the Generation of Optical Activity from a Fully Racemic System","display_name":"The Combination of Spontaneous Resolution and Asymmetric Catalysis: A Model for the Generation of Optical Activity from a Fully Racemic System","publication_year":2001,"publication_date":"2001-03-16","ids":{"openalex":"https://openalex.org/W2103994571","doi":"https://doi.org/10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.0.co;2-w","mag":"2103994571","pmid":"https://pubmed.ncbi.nlm.nih.gov/11268079"},"language":"en","primary_location":{"id":"doi:10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.0.co;2-w","doi":"https://doi.org/10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.0.co;2-w","is_oa":false,"landing_page_url":"https://doi.org/10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.0.co;2-w","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5047512027","display_name":"O. Tissot","orcid":"https://orcid.org/0000-0003-2912-7702","observed_orcids":["https://orcid.org/0000-0003-2912-7702"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Olivier Tissot","raw_affiliation_strings":["Laboratoire de Chimie de Coordination du CNRS 205, Route de Narbonne, 31077 Toulouse Cedex (France)","Laboratoire de Chimie de Coordination du CNRS 205 route de Narbonne, 31077 Toulouse Cedex (France) Fax: (+33)\u20095 61 55 30 03"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Chimie de Coordination du CNRS 205, Route de Narbonne, 31077 Toulouse Cedex (France)","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]},{"raw_affiliation_string":"Laboratoire de Chimie de Coordination du CNRS 205 route de Narbonne, 31077 Toulouse Cedex (France) Fax: (+33)\u20095 61 55 30 03","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5083132388","display_name":"Maryse Gouygou","orcid":"https://orcid.org/0000-0001-9429-537X","observed_orcids":["https://orcid.org/0000-0001-9429-537X"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Maryse Gouygou","raw_affiliation_strings":["Laboratoire de Chimie de Coordination du CNRS 205, Route de Narbonne, 31077 Toulouse Cedex (France)","Laboratoire de Chimie de Coordination du CNRS 205 route de Narbonne, 31077 Toulouse Cedex (France) Fax: (+33)\u20095 61 55 30 03"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Chimie de Coordination du CNRS 205, Route de Narbonne, 31077 Toulouse Cedex (France)","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]},{"raw_affiliation_string":"Laboratoire de Chimie de Coordination du CNRS 205 route de Narbonne, 31077 Toulouse Cedex (France) Fax: (+33)\u20095 61 55 30 03","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042999296","display_name":"F. Dallemer","orcid":"https://orcid.org/0000-0002-2147-0613","observed_orcids":["https://orcid.org/0000-0002-2147-0613"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Fr\u00e9d\u00e9ric Dallemer","raw_affiliation_strings":["Rhodia Recherches, Centre de Recherche de Lyon 85, Avenue des Freres Perret, BP 62, 69192 Saint-Fons Cedex (France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Rhodia Recherches, Centre de Recherche de Lyon 85, Avenue des Freres Perret, BP 62, 69192 Saint-Fons Cedex (France)","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5012368264","display_name":"Jean\u2010Claude Daran","orcid":"https://orcid.org/0000-0003-4833-7895","observed_orcids":["https://orcid.org/0000-0003-4833-7895"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Jean-Claude Daran","raw_affiliation_strings":["Laboratoire de Chimie de Coordination du CNRS 205, Route de Narbonne, 31077 Toulouse Cedex (France)","Laboratoire de Chimie de Coordination du CNRS 205 route de Narbonne, 31077 Toulouse Cedex (France) Fax: (+33)\u20095 61 55 30 03"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Chimie de Coordination du CNRS 205, Route de Narbonne, 31077 Toulouse Cedex (France)","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]},{"raw_affiliation_string":"Laboratoire de Chimie de Coordination du CNRS 205 route de Narbonne, 31077 Toulouse Cedex (France) Fax: (+33)\u20095 61 55 30 03","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111200746","display_name":"Gilbert G. A. Balavoine","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Gilbert G. A. Balavoine","raw_affiliation_strings":["Laboratoire de Chimie de Coordination du CNRS 205 route de Narbonne, 31077 Toulouse Cedex (France) Fax: (+33)\u20095 61 55 30 03"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Chimie de Coordination du CNRS 205 route de Narbonne, 31077 Toulouse Cedex (France) Fax: (+33)\u20095 61 55 30 03","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":5510,"currency":"USD","value_usd":5510},"apc_paid":null,"fwci":5.9247,"has_fulltext":false,"cited_by_count":73,"citation_normalized_percentile":{"value":0.97507839,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":99},"biblio":{"volume":"40","issue":"6","first_page":"1076","last_page":"1078"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.9473000168800354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.9473000168800354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.024000000208616257,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13115","display_name":"Axial and Atropisomeric Chirality Synthesis","score":0.020400000736117363,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/spontaneous-resolution","display_name":"spontaneous resolution","score":0.9200000166893005},{"id":"https://openalex.org/keywords/asymmetric-catalysis","display_name":"asymmetric catalysis","score":0.9340000152587891},{"id":"https://openalex.org/keywords/enantiomerically-pure-ligands","display_name":"enantiomerically pure ligands","score":0.6489999890327454},{"id":"https://openalex.org/keywords/palladium-complexes","display_name":"palladium complexes","score":0.6869999766349792},{"id":"https://openalex.org/keywords/asymmetric-allylic-substitution","display_name":"asymmetric allylic substitution","score":0.8550000190734863},{"id":"https://openalex.org/keywords/chiral-auxiliaries","display_name":"chiral auxiliaries","score":0.8029999732971191}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6023375391960144},{"id":"https://openalex.org/C138268822","wikidata":"https://www.wikidata.org/wiki/Q1051925","display_name":"Resolution (logic)","level":2,"score":0.5437092185020447},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.4464883506298065},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.4175776243209839},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.23692944645881653},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.11093932390213013},{"id":"https://openalex.org/C154945302","wikidata":"https://www.wikidata.org/wiki/Q11660","display_name":"Artificial intelligence","level":1,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.0.co;2-w","doi":"https://doi.org/10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.0.co;2-w","is_oa":false,"landing_page_url":"https://doi.org/10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.0.co;2-w","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"doi:10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.3.co;2-n","doi":"https://doi.org/10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.3.co;2-n","is_oa":false,"landing_page_url":"https://doi.org/10.1002/1521-3773(20010316)40:6<1076::aid-anie10760>3.3.co;2-n","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"pmid:11268079","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/11268079","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"},{"id":"mag:3215752136","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/11268079","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"PubMed","raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":11,"referenced_works":["https://openalex.org/W1963983906","https://openalex.org/W1966693513","https://openalex.org/W1986001811","https://openalex.org/W1989299398","https://openalex.org/W1999329475","https://openalex.org/W2000201317","https://openalex.org/W2017441561","https://openalex.org/W2023224512","https://openalex.org/W2028846358","https://openalex.org/W2096030987","https://openalex.org/W2132320121"],"related_works":["https://openalex.org/W2950456467","https://openalex.org/W2082632336","https://openalex.org/W2009952870","https://openalex.org/W2026982722","https://openalex.org/W3215752136","https://openalex.org/W2901497264","https://openalex.org/W2951894857","https://openalex.org/W618582661","https://openalex.org/W2018088870","https://openalex.org/W1926650703"],"abstract_inverted_index":{"Enantiomerically":[0],"pure":[1,33],"BIPHOS":[2],"was":[3,25],"obtained":[4],"by":[5],"spontaneous":[6],"resolution":[7],"through":[8],"the":[9,16,28,31],"crystallization":[10],"of":[11,18,30],"a":[12],"racemic":[13],"mixture,":[14],"without":[15],"use":[17],"chemical":[19],"or":[20],"physical":[21],"chiral":[22],"auxiliaries,":[23],"and":[24],"used":[26],"in":[27,44],"synthesis":[29],"enantiomerically":[32],"complex":[34,39],"[PdCl2(biphos)]":[35],"(see":[36],"scheme).":[37],"The":[38],"proved":[40],"to":[41],"be":[42],"efficient":[43],"catalytic":[45],"asymmetric":[46],"allylic":[47],"substitutions":[48],"with":[49],"80":[50],"%":[51],"ee.":[52]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":8}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}