{"id":"https://openalex.org/W2102716005","doi":"https://doi.org/10.1002/oms.1210220809","title":"Stereocontrolled regiospecificity of the water loss from trans\u2010sobrerol radical cation upon electron ionization","display_name":"Stereocontrolled regiospecificity of the water loss from trans\u2010sobrerol radical cation upon electron ionization","publication_year":1987,"publication_date":"1987-08-01","ids":{"openalex":"https://openalex.org/W2102716005","doi":"https://doi.org/10.1002/oms.1210220809","mag":"2102716005"},"language":"en","primary_location":{"id":"doi:10.1002/oms.1210220809","doi":"https://doi.org/10.1002/oms.1210220809","is_oa":false,"landing_page_url":"https://doi.org/10.1002/oms.1210220809","pdf_url":null,"source":{"id":"https://openalex.org/S4210228587","display_name":"Organic Mass Spectrometry","issn_l":"0030-493X","issn":["0030-493X","2376-3884"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic Mass Spectrometry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5024870033","display_name":"Antonio Selva","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I93860229","display_name":"Politecnico di Milano","ror":"https://ror.org/01nffqt88","country_code":"IT","type":"education","lineage":["https://openalex.org/I93860229"]}],"countries":["IT"],"is_corresponding":true,"raw_author_name":"Antonio Selva","raw_affiliation_strings":["CNR, Centro di per Studio per le Sostanze Organiche Naturali, c/o Dipartimento di Chimica del Politecnico, Piazza L. da Vinci 32, 1-20133 Milano, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNR, Centro di per Studio per le Sostanze Organiche Naturali, c/o Dipartimento di Chimica del Politecnico, Piazza L. da Vinci 32, 1-20133 Milano, Italy","institution_ids":["https://openalex.org/I93860229"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5083173977","display_name":"Francesco Ferrario","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I93860229","display_name":"Politecnico di Milano","ror":"https://ror.org/01nffqt88","country_code":"IT","type":"education","lineage":["https://openalex.org/I93860229"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Francesco Ferrario","raw_affiliation_strings":["CNR, Centro di per Studio per le Sostanze Organiche Naturali, c/o Dipartimento di Chimica del Politecnico, Piazza L. da Vinci 32, 1-20133 Milano, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CNR, Centro di per Studio per le Sostanze Organiche Naturali, c/o Dipartimento di Chimica del Politecnico, Piazza L. da Vinci 32, 1-20133 Milano, Italy","institution_ids":["https://openalex.org/I93860229"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067668437","display_name":"Paolo Ventura","orcid":"https://orcid.org/0000-0003-1893-1914","observed_orcids":["https://orcid.org/0000-0003-1893-1914"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Paolo Ventura","raw_affiliation_strings":["Laboration di Ricerca Camillo Corvi S.p.A., 1-29100 Piacenza, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboration di Ricerca Camillo Corvi S.p.A., 1-29100 Piacenza, Italy","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5036368451","display_name":"Renato Pellegata","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Renato Pellegata","raw_affiliation_strings":["Laboration di Ricerca Camillo Corvi S.p.A., 1-29100 Piacenza, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboration di Ricerca Camillo Corvi S.p.A., 1-29100 Piacenza, Italy","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5024870033"],"corresponding_institution_ids":["https://openalex.org/I93860229"],"apc_list":null,"apc_paid":null,"fwci":0.5425,"has_fulltext":false,"cited_by_count":7,"citation_normalized_percentile":{"value":0.60783709,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":"22","issue":"8","first_page":"523","last_page":"529"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10523","display_name":"Atomic and Molecular Physics","score":0.0,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/radical-cations","display_name":"radical cations","score":0.6769999861717224},{"id":"https://openalex.org/keywords/electron-impact-ionization","display_name":"electron impact ionization","score":0.8420000076293945},{"id":"https://openalex.org/keywords/water-loss","display_name":"water loss","score":0.9049999713897705},{"id":"https://openalex.org/keywords/regiospecificity","display_name":"regiospecificity","score":0.8090000152587891},{"id":"https://openalex.org/keywords/18o-labeling","display_name":"18O labeling","score":0.824999988079071},{"id":"https://openalex.org/keywords/deuterium-labeling","display_name":"deuterium labeling","score":0.9929999709129333},{"id":"https://openalex.org/keywords/monomethyl-ether","display_name":"monomethyl ether","score":0.7099999785423279},{"id":"https://openalex.org/keywords/metastable-ions","display_name":"metastable ions","score":0.6840000152587891}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8137423992156982},{"id":"https://openalex.org/C205759337","wikidata":"https://www.wikidata.org/wiki/Q1748259","display_name":"Electron ionization","level":4,"score":0.6778366565704346},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.6753268837928772},{"id":"https://openalex.org/C198291218","wikidata":"https://www.wikidata.org/wiki/Q190382","display_name":"Ionization","level":3,"score":0.6065530776977539},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.5672051310539246},{"id":"https://openalex.org/C2776920199","wikidata":"https://www.wikidata.org/wiki/Q408028","display_name":"Epoxide","level":3,"score":0.5509874820709229},{"id":"https://openalex.org/C162356407","wikidata":"https://www.wikidata.org/wiki/Q180809","display_name":"Mass spectrometry","level":2,"score":0.498523473739624},{"id":"https://openalex.org/C58364064","wikidata":"https://www.wikidata.org/wiki/Q102296","display_name":"Deuterium","level":2,"score":0.476868212223053},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.4767383337020874},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4490825831890106},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.32342416048049927},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.23173120617866516},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.09620165824890137},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.06881466507911682},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.06777647137641907},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/oms.1210220809","doi":"https://doi.org/10.1002/oms.1210220809","is_oa":false,"landing_page_url":"https://doi.org/10.1002/oms.1210220809","pdf_url":null,"source":{"id":"https://openalex.org/S4210228587","display_name":"Organic Mass Spectrometry","issn_l":"0030-493X","issn":["0030-493X","2376-3884"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic Mass Spectrometry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":13,"referenced_works":["https://openalex.org/W1965249378","https://openalex.org/W2008766135","https://openalex.org/W2027089577","https://openalex.org/W2041086468","https://openalex.org/W2042886825","https://openalex.org/W2049390181","https://openalex.org/W2054129417","https://openalex.org/W2067254690","https://openalex.org/W2081033420","https://openalex.org/W2109811266","https://openalex.org/W2951107618","https://openalex.org/W3204165005","https://openalex.org/W4232880435"],"related_works":["https://openalex.org/W1978568878","https://openalex.org/W2045376729","https://openalex.org/W1973651420","https://openalex.org/W2141069439","https://openalex.org/W4246208667","https://openalex.org/W2016281069","https://openalex.org/W1996003355","https://openalex.org/W2084961020","https://openalex.org/W2093454260","https://openalex.org/W2071936328"],"abstract_inverted_index":{"Abstract":[0],"Water":[1],"loss":[2,94],"from":[3,21,65],"frans\u2010sobrerol":[4],"upon":[5],"electron":[6],"impact":[7],"ionization":[8],"selectively":[9],"involves":[10],"the":[11,43],"tertiary":[12],"OH":[13],"group,":[14],"predominantly":[15],"occurring":[16],"by":[17,31,50,93],"a":[18,25],"stereocontrolled":[19],"H\u2010transfer":[20],"C(5)":[22],"position":[23],"in":[24,74],"rate\u2010determining":[26],"step":[27],"process,":[28],"as":[29],"proved":[30],"18O":[32],"and":[33,53,81],"deuterium":[34],"labelling.":[35],"Monomethyl":[36],"ethers":[37],"behave":[38],"accordingly.":[39],"Ionic":[40],"structures":[41],"of":[42,86,95],"water\u2010loss":[44],"product":[45],"or":[46],"products":[47],"are":[48,69],"investigated":[49],"metastable":[51],"ion":[52,57],"collision":[54],"activation":[55],"mass\u2010analysed":[56],"kinetic":[58],"energy":[59],"spectroscopy,":[60],"using":[61],"model":[62],"ions":[63,89],"generated":[64],"some":[66],"substrates,":[67],"which":[68],"chemically":[70],"related":[71],"to":[72,90],"fralts\u2010sobrerol":[73],"condensed":[75],"phase,":[76],"i.e.":[77],"\u03b1\u2010pinane":[78],"epoxide,":[79],"cis\u2010sobrerol":[80,87],"pinol.":[82],"A":[83],"substantial":[84],"conversion":[85],"molecular":[88],"ionized":[91],"pinol":[92],"water":[96],"has":[97],"been":[98],"demonstrated.":[99]},"counts_by_year":[{"year":2018,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}