{"id":"https://openalex.org/W2094925512","doi":"https://doi.org/10.1063/1.478550","title":"Evidence for phase separation during the crystallization of hyperquenched glassy clathrate hydrate forming solutions","display_name":"Evidence for phase separation during the crystallization of hyperquenched glassy clathrate hydrate forming solutions","publication_year":1999,"publication_date":"1999-04-01","ids":{"openalex":"https://openalex.org/W2094925512","doi":"https://doi.org/10.1063/1.478550","mag":"2094925512"},"language":"en","primary_location":{"id":"doi:10.1063/1.478550","doi":"https://doi.org/10.1063/1.478550","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.478550","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5002577767","display_name":"Christopher A. Tulk","orcid":"https://orcid.org/0000-0003-3400-3878","observed_orcids":["https://orcid.org/0000-0003-3400-3878"]},"institutions":[{"id":"https://openalex.org/I4210135718","display_name":"Steacie Institute for Molecular Sciences","ror":"https://ror.org/02tjxem41","country_code":"CA","type":"facility","lineage":["https://openalex.org/I4210135718","https://openalex.org/I4210159778"]},{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"C. A. Tulk","raw_affiliation_strings":["Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario\u2009K1A\u20090R6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario\u2009K1A\u20090R6, Canada","institution_ids":["https://openalex.org/I4210135718","https://openalex.org/I4210159778"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5011509212","display_name":"Yong Ba","orcid":"https://orcid.org/0000-0003-1079-4708","observed_orcids":["https://orcid.org/0000-0003-1079-4708"]},"institutions":[{"id":"https://openalex.org/I4210135718","display_name":"Steacie Institute for Molecular Sciences","ror":"https://ror.org/02tjxem41","country_code":"CA","type":"facility","lineage":["https://openalex.org/I4210135718","https://openalex.org/I4210159778"]},{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Y. Ba","raw_affiliation_strings":["Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario\u2009K1A\u20090R6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario\u2009K1A\u20090R6, Canada","institution_ids":["https://openalex.org/I4210135718","https://openalex.org/I4210159778"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5016173567","display_name":"Dennis D. Klug","orcid":"https://orcid.org/0000-0003-2911-8726","observed_orcids":["https://orcid.org/0000-0003-2911-8726"]},"institutions":[{"id":"https://openalex.org/I4210135718","display_name":"Steacie Institute for Molecular Sciences","ror":"https://ror.org/02tjxem41","country_code":"CA","type":"facility","lineage":["https://openalex.org/I4210135718","https://openalex.org/I4210159778"]},{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"D. D. Klug","raw_affiliation_strings":["Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario\u2009K1A\u20090R6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario\u2009K1A\u20090R6, Canada","institution_ids":["https://openalex.org/I4210135718","https://openalex.org/I4210159778"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5018339818","display_name":"Graham E. McLaurin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210135718","display_name":"Steacie Institute for Molecular Sciences","ror":"https://ror.org/02tjxem41","country_code":"CA","type":"facility","lineage":["https://openalex.org/I4210135718","https://openalex.org/I4210159778"]},{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"G. McLaurin","raw_affiliation_strings":["Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario\u2009K1A\u20090R6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario\u2009K1A\u20090R6, Canada","institution_ids":["https://openalex.org/I4210135718","https://openalex.org/I4210159778"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5089988046","display_name":"John A. Ripmeester","orcid":"https://orcid.org/0000-0002-4091-5120","observed_orcids":["https://orcid.org/0000-0002-4091-5120"]},"institutions":[{"id":"https://openalex.org/I4210135718","display_name":"Steacie Institute for Molecular Sciences","ror":"https://ror.org/02tjxem41","country_code":"CA","type":"facility","lineage":["https://openalex.org/I4210135718","https://openalex.org/I4210159778"]},{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"J. A. Ripmeester","raw_affiliation_strings":["Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario\u2009K1A\u20090R6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario\u2009K1A\u20090R6, Canada","institution_ids":["https://openalex.org/I4210135718","https://openalex.org/I4210159778"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":1.1206,"has_fulltext":false,"cited_by_count":26,"citation_normalized_percentile":{"value":0.75936924,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":97},"biblio":{"volume":"110","issue":"13","first_page":"6475","last_page":"6483"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10995","display_name":"Methane Hydrates and Related Phenomena","score":0.8842999935150146,"subfield":{"id":"https://openalex.org/subfields/2304","display_name":"Environmental Chemistry"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10995","display_name":"Methane Hydrates and Related Phenomena","score":0.8842999935150146,"subfield":{"id":"https://openalex.org/subfields/2304","display_name":"Environmental Chemistry"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10474","display_name":"Material Dynamics and Properties","score":0.03200000151991844,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12202","display_name":"nanoparticles nucleation surface interactions","score":0.018400000408291817,"subfield":{"id":"https://openalex.org/subfields/1902","display_name":"Atmospheric Science"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/clathrate-hydrates","display_name":"clathrate hydrates","score":0.8700000047683716},{"id":"https://openalex.org/keywords/tetrahydrofuran","display_name":"tetrahydrofuran","score":0.8679999709129333},{"id":"https://openalex.org/keywords/hyperquenching","display_name":"hyperquenching","score":0.921999990940094},{"id":"https://openalex.org/keywords/glassy-solutions","display_name":"glassy solutions","score":0.6119999885559082},{"id":"https://openalex.org/keywords/phase-separation","display_name":"phase separation","score":0.8669999837875366},{"id":"https://openalex.org/keywords/crystallization","display_name":"crystallization","score":0.7419999837875366},{"id":"https://openalex.org/keywords/ice-ic","display_name":"ice Ic","score":0.7559999823570251},{"id":"https://openalex.org/keywords/amorphous-ice","display_name":"amorphous ice","score":0.6000000238418579},{"id":"https://openalex.org/keywords/hydrogen-bonding","display_name":"hydrogen bonding","score":0.5720000267028809},{"id":"https://openalex.org/keywords/fictive-temperature","display_name":"fictive temperature","score":0.6370000243186951},{"id":"https://openalex.org/keywords/annealing","display_name":"annealing","score":0.5709999799728394},{"id":"https://openalex.org/keywords/crystal-nucleation","display_name":"crystal nucleation","score":0.4970000088214874}],"concepts":[{"id":"https://openalex.org/C100402318","wikidata":"https://www.wikidata.org/wiki/Q864080","display_name":"Clathrate hydrate","level":3,"score":0.8739168643951416},{"id":"https://openalex.org/C203036418","wikidata":"https://www.wikidata.org/wiki/Q284256","display_name":"Crystallization","level":2,"score":0.7490299940109253},{"id":"https://openalex.org/C2781060337","wikidata":"https://www.wikidata.org/wiki/Q462174","display_name":"Hydrate","level":2,"score":0.7110101580619812},{"id":"https://openalex.org/C2776701986","wikidata":"https://www.wikidata.org/wiki/Q278332","display_name":"Tetrahydrofuran","level":3,"score":0.6290035843849182},{"id":"https://openalex.org/C56052488","wikidata":"https://www.wikidata.org/wiki/Q103382","display_name":"Amorphous solid","level":2,"score":0.6191582679748535},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5433713793754578},{"id":"https://openalex.org/C40003534","wikidata":"https://www.wikidata.org/wiki/Q862228","display_name":"Raman spectroscopy","level":2,"score":0.5412177443504333},{"id":"https://openalex.org/C2777855556","wikidata":"https://www.wikidata.org/wiki/Q4339544","display_name":"Annealing (glass)","level":2,"score":0.5014913082122803},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.47615763545036316},{"id":"https://openalex.org/C38743072","wikidata":"https://www.wikidata.org/wiki/Q504492","display_name":"Water of crystallization","level":2,"score":0.47191479802131653},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.38781553506851196},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.33800947666168213},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.17921683192253113},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12974143028259277},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.08816730976104736},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1063/1.478550","doi":"https://doi.org/10.1063/1.478550","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.478550","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":37,"referenced_works":["https://openalex.org/W604100514","https://openalex.org/W1605674029","https://openalex.org/W1964534713","https://openalex.org/W1964766625","https://openalex.org/W1967013564","https://openalex.org/W1967622410","https://openalex.org/W1970714918","https://openalex.org/W1988684658","https://openalex.org/W1993758547","https://openalex.org/W1994734562","https://openalex.org/W2001092115","https://openalex.org/W2008265869","https://openalex.org/W2012519960","https://openalex.org/W2018277370","https://openalex.org/W2018433176","https://openalex.org/W2024942774","https://openalex.org/W2025325563","https://openalex.org/W2027580422","https://openalex.org/W2031322243","https://openalex.org/W2033421363","https://openalex.org/W2045173898","https://openalex.org/W2051245466","https://openalex.org/W2051552929","https://openalex.org/W2052098108","https://openalex.org/W2054418709","https://openalex.org/W2055821679","https://openalex.org/W2056383388","https://openalex.org/W2059639436","https://openalex.org/W2065514160","https://openalex.org/W2067826422","https://openalex.org/W2071582294","https://openalex.org/W2091575538","https://openalex.org/W2093333143","https://openalex.org/W2095040085","https://openalex.org/W2159880492","https://openalex.org/W2486629449","https://openalex.org/W2952815280"],"related_works":["https://openalex.org/W4410402515","https://openalex.org/W2021820516","https://openalex.org/W2083870782","https://openalex.org/W4410349641","https://openalex.org/W2164572866","https://openalex.org/W3011379823","https://openalex.org/W2277290188","https://openalex.org/W2038493157","https://openalex.org/W2951592630","https://openalex.org/W2329154022"],"abstract_inverted_index":{"Tetrahydrofuran,":[0],"a":[1,35,240],"water-soluble":[2],"cyclic":[3],"ether":[4],"molecule,":[5],"is":[6],"well":[7],"known":[8],"for":[9],"its":[10],"ability":[11],"to":[12,40,43,219],"form":[13],"clathrate":[14,116,162,231],"hydrates":[15],"(cubic":[16],"structure":[17,178],"II,":[18],"melting":[19],"point":[20],"277.5":[21],"K).":[22],"An":[23],"aqueous":[24],"solution":[25,144],"of":[26,37,47,50,96,109,129,152,179,188,201,229],"THF":[27,111,199,208,244],"(17:1":[28],"molecular":[29,127],"ratio)":[30],"was":[31,57,82,119],"hyperquenched":[32],"(cooled":[33],"at":[34,84],"rate":[36],"106":[38],"Ks\u22121)":[39],"77":[41],"K":[42,170,225],"give":[44],"recoverable":[45],"samples":[46,167],"\u223c1":[48],"g":[49],"metastable":[51],"amorphous":[52,80],"material.":[53],"The":[54],"crystallization":[55,118],"process":[56,196],"studied":[58],"on":[59],"three":[60],"complementary":[61],"length":[62],"scales":[63],"by":[64],"x-ray":[65],"powder":[66],"diffraction,":[67],"quadrupole":[68],"echo":[69],"double":[70],"resonance":[71],"(QEDOR)":[72],"NMR":[73],"spectroscopy,":[74],"and":[75,88,112,135,247],"Raman":[76],"spectroscopy":[77],"as":[78],"the":[79,97,103,122,125,136,143,153,166,173,180,185,198,202,207,212,243],"material":[81],"annealed":[83],"temperatures":[85],"between":[86,132,168],"80":[87],"190":[89],"K.":[90],"Results":[91],"show":[92],"that":[93,156,172,194,215],"phase":[94],"separation":[95],"two":[98],"components":[99],"occurred":[100],"predominantly":[101],"during":[102],"annealing":[104],"process,":[105,124],"resulting":[106],"in":[107,160,211,242],"clusters":[108],"crystalline":[110,161,189,230],"ice":[113,190,248],"Ic":[114],"before":[115],"hydrate":[117,163,232],"initiated.":[120],"During":[121],"hyperquenching":[123],"decreasing":[126],"mobility":[128],"water":[130,181],"molecules":[131,182],"room":[133],"temperature":[134,138,140],"fictive":[137],"(the":[139],"below":[141],"which":[142,234],"becomes":[145],"structurally":[146],"immobilized":[147],"upon":[148],"hyperquenching)":[149],"inhibits":[150],"growth":[151,228],"crystal":[154],"nuclei":[155],"normally":[157],"would":[158],"result":[159],"formation.":[164],"Annealing":[165],"110\u2013140":[169],"showed":[171],"local":[174],"hydrogen":[175],"bonded":[176],"O\u2013H--O":[177],"changed":[183],"toward":[184],"arrangement":[186],"characteristic":[187],"Ic.":[191,249],"We":[192],"propose":[193],"this":[195],"forces":[197],"out":[200],"glassy":[203],"solution,":[204],"thus":[205],"increasing":[206],"cluster":[209,245],"size":[210],"deposit":[213],"so":[214],"these":[216],"become":[217],"visible":[218],"diffraction.":[220],"Further":[221],"annealing,":[222],"above":[223],"150\u2013160":[224],"caused":[226],"large-scale":[227],"material,":[233],"then":[235],"could":[236],"be":[237],"associated":[238],"with":[239],"reduction":[241],"size,":[246]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":4},{"year":2016,"cited_by_count":1}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}