{"id":"https://openalex.org/W2094630859","doi":"https://doi.org/10.1021/ja0171005","title":"A Symmetric Derivative of the Trimetallic Nitride Endohedral Metallofullerene, Sc3N@C80","display_name":"A Symmetric Derivative of the Trimetallic Nitride Endohedral Metallofullerene, Sc3N@C80","publication_year":2001,"publication_date":"2001-12-29","ids":{"openalex":"https://openalex.org/W2094630859","doi":"https://doi.org/10.1021/ja0171005","mag":"2094630859","pmid":"https://pubmed.ncbi.nlm.nih.gov/11804475"},"language":"en","primary_location":{"id":"doi:10.1021/ja0171005","doi":"https://doi.org/10.1021/ja0171005","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja0171005","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5072413518","display_name":"Erick B. Iezzi","orcid":"https://orcid.org/0000-0002-4018-7450","observed_orcids":["https://orcid.org/0000-0002-4018-7450"]},"institutions":[{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Erick B. Iezzi","raw_affiliation_strings":["Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061","Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, 24061, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061","institution_ids":["https://openalex.org/I859038795"]},{"raw_affiliation_string":"Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, 24061, USA","institution_ids":["https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007941647","display_name":"James C. Duchamp","orcid":"https://orcid.org/0000-0001-7619-3353","observed_orcids":["https://orcid.org/0000-0001-7619-3353"]},"institutions":[{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James C. Duchamp","raw_affiliation_strings":["Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061","institution_ids":["https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5061171102","display_name":"Kim C. Harich","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Kim Harich","raw_affiliation_strings":["Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061","institution_ids":["https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112140960","display_name":"Tom Glass","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Tom E. Glass","raw_affiliation_strings":["Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061","institution_ids":["https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5063904325","display_name":"Hon Man Lee","orcid":"https://orcid.org/0000-0002-9557-3914","observed_orcids":["https://orcid.org/0000-0002-9557-3914"]},"institutions":[{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Hon Man Lee","raw_affiliation_strings":["Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061","institution_ids":["https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009326683","display_name":"Marilyn M. Olmstead","orcid":"https://orcid.org/0000-0002-6160-1622","observed_orcids":["https://orcid.org/0000-0002-6160-1622"]},"institutions":[{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Marilyn M. Olmstead","raw_affiliation_strings":["Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061","institution_ids":["https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067879544","display_name":"Alan L. Balch","orcid":"https://orcid.org/0000-0002-8813-6281","observed_orcids":["https://orcid.org/0000-0002-8813-6281"]},"institutions":[{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Alan L. Balch","raw_affiliation_strings":["Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061","institution_ids":["https://openalex.org/I859038795"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5071786154","display_name":"Harry C. Dorn","orcid":"https://orcid.org/0000-0002-3150-5314","observed_orcids":["https://orcid.org/0000-0002-3150-5314"]},"institutions":[{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Harry C. Dorn","raw_affiliation_strings":["Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061","institution_ids":["https://openalex.org/I859038795"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I859038795"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.8649,"has_fulltext":false,"cited_by_count":161,"citation_normalized_percentile":{"value":0.94250614,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"124","issue":"4","first_page":"524","last_page":"525"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10956","display_name":"Fullerene Chemistry and Applications","score":0.9955999851226807,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10956","display_name":"Fullerene Chemistry and Applications","score":0.9955999851226807,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12557","display_name":"Inorganic Chemistry and Materials","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12055","display_name":"Boron Compounds in Chemistry","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/2741","display_name":"Radiology, Nuclear Medicine and Imaging"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/sc3n-c80","display_name":"Sc3N@C80","score":0.9070000052452087},{"id":"https://openalex.org/keywords/13c-labeling","display_name":"13C labeling","score":0.8180000185966492},{"id":"https://openalex.org/keywords/scandium-nitride","display_name":"scandium nitride","score":0.6669999957084656}],"concepts":[{"id":"https://openalex.org/C2780860830","wikidata":"https://www.wikidata.org/wiki/Q17042087","display_name":"Metallofullerene","level":3,"score":0.9904811382293701},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9066390991210938},{"id":"https://openalex.org/C2776923573","wikidata":"https://www.wikidata.org/wiki/Q2294884","display_name":"Derivatization","level":3,"score":0.8280849456787109},{"id":"https://openalex.org/C111771559","wikidata":"https://www.wikidata.org/wiki/Q66295","display_name":"Derivative (finance)","level":2,"score":0.7041120529174805},{"id":"https://openalex.org/C194760766","wikidata":"https://www.wikidata.org/wiki/Q410851","display_name":"Nitride","level":3,"score":0.6215574741363525},{"id":"https://openalex.org/C163111631","wikidata":"https://www.wikidata.org/wiki/Q1952454","display_name":"Carbon-13 NMR","level":2,"score":0.5390073657035828},{"id":"https://openalex.org/C162356407","wikidata":"https://www.wikidata.org/wiki/Q180809","display_name":"Mass spectrometry","level":2,"score":0.511108934879303},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.47428804636001587},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.46174436807632446},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.32363516092300415},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.30809712409973145},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.20809406042099},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.19271138310432434},{"id":"https://openalex.org/C162862793","wikidata":"https://www.wikidata.org/wiki/Q178026","display_name":"Fullerene","level":2,"score":0.17911893129348755},{"id":"https://openalex.org/C162324750","wikidata":"https://www.wikidata.org/wiki/Q8134","display_name":"Economics","level":0,"score":0.0},{"id":"https://openalex.org/C106159729","wikidata":"https://www.wikidata.org/wiki/Q2294553","display_name":"Financial economics","level":1,"score":0.0},{"id":"https://openalex.org/C2779227376","wikidata":"https://www.wikidata.org/wiki/Q6505497","display_name":"Layer (electronics)","level":2,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ja0171005","doi":"https://doi.org/10.1021/ja0171005","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja0171005","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:11804475","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/11804475","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":21,"referenced_works":["https://openalex.org/W129203059","https://openalex.org/W1494168269","https://openalex.org/W1674015533","https://openalex.org/W1977717369","https://openalex.org/W1980672327","https://openalex.org/W1987878875","https://openalex.org/W1993024603","https://openalex.org/W2003824479","https://openalex.org/W2009998634","https://openalex.org/W2013091112","https://openalex.org/W2013450848","https://openalex.org/W2017647960","https://openalex.org/W2057349631","https://openalex.org/W2059967334","https://openalex.org/W2060869584","https://openalex.org/W2089449432","https://openalex.org/W2090424147","https://openalex.org/W2092157139","https://openalex.org/W2134304437","https://openalex.org/W2134909467","https://openalex.org/W4393818646"],"related_works":["https://openalex.org/W2592175432","https://openalex.org/W1972639352","https://openalex.org/W1998621346","https://openalex.org/W4244583327","https://openalex.org/W2042476195","https://openalex.org/W1964723698","https://openalex.org/W1966911130","https://openalex.org/W2119492879","https://openalex.org/W1965609410","https://openalex.org/W1613238598"],"abstract_inverted_index":{"The":[0,22,39,54],"reaction":[1,23],"of":[2,13],"Sc3N@C80":[3,73],"with":[4,64],"6,7-dimethoxyisochroman-3-one":[5],"(13C":[6],"labeled)":[7],"provides":[8],"the":[9,14,67,72],"first":[10],"functionalized":[11],"derivative":[12],"trimetallic":[15],"nitride":[16],"template":[17],"(TNT)":[18],"endohedral":[19],"metallofullerene":[20],"family.":[21],"mixture":[24],"is":[25,62],"dominated":[26],"by":[27,37,45],"a":[28],"single":[29],"13C":[30,40,48],"labeled":[31,41],"monoadduct":[32,42,61],"product":[33],"that":[34],"was":[35,43],"purified":[36],"HPLC.":[38],"characterized":[44],"1H":[46],"NMR,":[47,49],"and":[50],"MALDI-TOF":[51],"mass":[52],"spectrometry.":[53],"proposed":[55],"structure":[56],"for":[57],"this":[58],"novel":[59],"symmetric":[60],"consistent":[63],"derivatization":[65],"at":[66],"[5,6]":[68],"ring":[69],"juncture":[70],"on":[71],"cage.":[74]},"counts_by_year":[{"year":2025,"cited_by_count":4},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":7},{"year":2013,"cited_by_count":11},{"year":2012,"cited_by_count":8}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}