{"id":"https://openalex.org/W2092898280","doi":"https://doi.org/10.1021/jp9007625","title":"Long-Time Scale Ionic Dynamics in Dense Clay Sediments Measured by the Frequency Variation of the7Li Multiple-Quantum NMR Relaxation Rates in Relation with a Multiscale Modeling","display_name":"Long-Time Scale Ionic Dynamics in Dense Clay Sediments Measured by the Frequency Variation of the7Li Multiple-Quantum NMR Relaxation Rates in Relation with a Multiscale Modeling","publication_year":2009,"publication_date":"2009-05-19","ids":{"openalex":"https://openalex.org/W2092898280","doi":"https://doi.org/10.1021/jp9007625","mag":"2092898280"},"language":"en","primary_location":{"id":"doi:10.1021/jp9007625","doi":"https://doi.org/10.1021/jp9007625","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp9007625","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5106469701","display_name":"Patrice Porion","orcid":"https://orcid.org/0000-0003-4380-5995","observed_orcids":["https://orcid.org/0000-0003-4380-5995"]},"institutions":[{"id":"https://openalex.org/I12449238","display_name":"Universit\u00e9 d'Orl\u00e9ans","ror":"https://ror.org/014zrew76","country_code":"FR","type":"education","lineage":["https://openalex.org/I12449238"]},{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210090075","display_name":"Interfaces, Confinement, Mat\u00e9riaux et Nanostructures","ror":"https://ror.org/008h1f725","country_code":"FR","type":"education","lineage":["https://openalex.org/I12449238","https://openalex.org/I1294671590","https://openalex.org/I4210090075","https://openalex.org/I4210098836","https://openalex.org/I4210113334","https://openalex.org/I4210139971"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Patrice Porion","raw_affiliation_strings":["Centre de Recherche sur la Mati\u00e8re Divis\u00e9e, CNRS - Universit\u00e9 d\u2019Orl\u00e9ans, 1b rue de la F\u00e9rollerie, 45071 Orl\u00e9ans Cedex 02, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre de Recherche sur la Mati\u00e8re Divis\u00e9e, CNRS - Universit\u00e9 d\u2019Orl\u00e9ans, 1b rue de la F\u00e9rollerie, 45071 Orl\u00e9ans Cedex 02, France","institution_ids":["https://openalex.org/I12449238","https://openalex.org/I1294671590","https://openalex.org/I4210090075"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111519585","display_name":"A. M. Faug\u00e8re","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I12449238","display_name":"Universit\u00e9 d'Orl\u00e9ans","ror":"https://ror.org/014zrew76","country_code":"FR","type":"education","lineage":["https://openalex.org/I12449238"]},{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210090075","display_name":"Interfaces, Confinement, Mat\u00e9riaux et Nanostructures","ror":"https://ror.org/008h1f725","country_code":"FR","type":"education","lineage":["https://openalex.org/I12449238","https://openalex.org/I1294671590","https://openalex.org/I4210090075","https://openalex.org/I4210098836","https://openalex.org/I4210113334","https://openalex.org/I4210139971"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Anne Marie Faug\u00e8re","raw_affiliation_strings":["Centre de Recherche sur la Mati\u00e8re Divis\u00e9e, CNRS - Universit\u00e9 d\u2019Orl\u00e9ans, 1b rue de la F\u00e9rollerie, 45071 Orl\u00e9ans Cedex 02, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre de Recherche sur la Mati\u00e8re Divis\u00e9e, CNRS - Universit\u00e9 d\u2019Orl\u00e9ans, 1b rue de la F\u00e9rollerie, 45071 Orl\u00e9ans Cedex 02, France","institution_ids":["https://openalex.org/I12449238","https://openalex.org/I1294671590","https://openalex.org/I4210090075"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5069093170","display_name":"Alfred Delville","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I12449238","display_name":"Universit\u00e9 d'Orl\u00e9ans","ror":"https://ror.org/014zrew76","country_code":"FR","type":"education","lineage":["https://openalex.org/I12449238"]},{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210090075","display_name":"Interfaces, Confinement, Mat\u00e9riaux et Nanostructures","ror":"https://ror.org/008h1f725","country_code":"FR","type":"education","lineage":["https://openalex.org/I12449238","https://openalex.org/I1294671590","https://openalex.org/I4210090075","https://openalex.org/I4210098836","https://openalex.org/I4210113334","https://openalex.org/I4210139971"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Alfred Delville","raw_affiliation_strings":["Centre de Recherche sur la Mati\u00e8re Divis\u00e9e, CNRS - Universit\u00e9 d\u2019Orl\u00e9ans, 1b rue de la F\u00e9rollerie, 45071 Orl\u00e9ans Cedex 02, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre de Recherche sur la Mati\u00e8re Divis\u00e9e, CNRS - Universit\u00e9 d\u2019Orl\u00e9ans, 1b rue de la F\u00e9rollerie, 45071 Orl\u00e9ans Cedex 02, France","institution_ids":["https://openalex.org/I12449238","https://openalex.org/I1294671590","https://openalex.org/I4210090075"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5069093170","https://openalex.org/A5106469701"],"corresponding_institution_ids":["https://openalex.org/I12449238","https://openalex.org/I1294671590","https://openalex.org/I4210090075"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.4822,"has_fulltext":false,"cited_by_count":18,"citation_normalized_percentile":{"value":0.52246445,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"113","issue":"24","first_page":"10580","last_page":"10597"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12603","display_name":"NMR spectroscopy and applications","score":0.8964999914169312,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12603","display_name":"NMR spectroscopy and applications","score":0.8964999914169312,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11809","display_name":"Advanced NMR Techniques and Applications","score":0.08980000019073486,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":0.00279999990016222,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/7li-nmr","display_name":"7Li NMR","score":0.8339999914169312},{"id":"https://openalex.org/keywords/lithium-counterion","display_name":"lithium counterion","score":0.8130000233650208},{"id":"https://openalex.org/keywords/clay-nanoplatelets","display_name":"clay nanoplatelets","score":0.6909999847412109},{"id":"https://openalex.org/keywords/ion-dynamics","display_name":"ion dynamics","score":0.6209999918937683},{"id":"https://openalex.org/keywords/quadrupolar-relaxation","display_name":"quadrupolar relaxation","score":0.8360000252723694},{"id":"https://openalex.org/keywords/dipole-relaxation","display_name":"dipolar relaxation","score":0.7210000157356262},{"id":"https://openalex.org/keywords/power-spectrum","display_name":"power spectrum","score":0.6710000038146973},{"id":"https://openalex.org/keywords/multiscale-modeling","display_name":"multiscale modeling","score":0.75},{"id":"https://openalex.org/keywords/lithium-ion-diffusion","display_name":"lithium ion diffusion","score":0.7350000143051147}],"concepts":[{"id":"https://openalex.org/C2776029896","wikidata":"https://www.wikidata.org/wiki/Q3935810","display_name":"Relaxation (psychology)","level":2,"score":0.712165355682373},{"id":"https://openalex.org/C34814092","wikidata":"https://www.wikidata.org/wiki/Q2268418","display_name":"Counterion","level":3,"score":0.6004457473754883},{"id":"https://openalex.org/C2778541603","wikidata":"https://www.wikidata.org/wiki/Q152763","display_name":"Lithium (medication)","level":2,"score":0.5655752420425415},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.5144524574279785},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.5071427822113037},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.45769673585891724},{"id":"https://openalex.org/C177562468","wikidata":"https://www.wikidata.org/wiki/Q182893","display_name":"Dispersion (optics)","level":2,"score":0.4490004777908325},{"id":"https://openalex.org/C69357855","wikidata":"https://www.wikidata.org/wiki/Q163214","display_name":"Diffusion","level":2,"score":0.43579035997390747},{"id":"https://openalex.org/C85725439","wikidata":"https://www.wikidata.org/wiki/Q466686","display_name":"Anisotropy","level":2,"score":0.42977476119995117},{"id":"https://openalex.org/C131584629","wikidata":"https://www.wikidata.org/wiki/Q4308705","display_name":"Coupling (piping)","level":2,"score":0.42587897181510925},{"id":"https://openalex.org/C2778046766","wikidata":"https://www.wikidata.org/wiki/Q17052393","display_name":"Dynamical heterogeneity","level":4,"score":0.41718313097953796},{"id":"https://openalex.org/C41999313","wikidata":"https://www.wikidata.org/wiki/Q489328","display_name":"Molecular physics","level":1,"score":0.4045131802558899},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3741464614868164},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3414720594882965},{"id":"https://openalex.org/C26873012","wikidata":"https://www.wikidata.org/wiki/Q214781","display_name":"Condensed matter physics","level":1,"score":0.3394535183906555},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.3273719549179077},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.28686583042144775},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.23200839757919312},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.1343185007572174},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.12767067551612854},{"id":"https://openalex.org/C15744967","wikidata":"https://www.wikidata.org/wiki/Q9418","display_name":"Psychology","level":0,"score":0.0},{"id":"https://openalex.org/C122865956","wikidata":"https://www.wikidata.org/wiki/Q825643","display_name":"Glass transition","level":3,"score":0.0},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C134018914","wikidata":"https://www.wikidata.org/wiki/Q162606","display_name":"Endocrinology","level":1,"score":0.0},{"id":"https://openalex.org/C77805123","wikidata":"https://www.wikidata.org/wiki/Q161272","display_name":"Social psychology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/jp9007625","doi":"https://doi.org/10.1021/jp9007625","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp9007625","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":61,"referenced_works":["https://openalex.org/W110285710","https://openalex.org/W293687779","https://openalex.org/W1589163079","https://openalex.org/W1594487206","https://openalex.org/W1966270961","https://openalex.org/W1969786581","https://openalex.org/W1973584397","https://openalex.org/W1975342432","https://openalex.org/W1977218081","https://openalex.org/W1979071915","https://openalex.org/W1987414906","https://openalex.org/W1987648587","https://openalex.org/W1993536537","https://openalex.org/W1999217993","https://openalex.org/W2000991704","https://openalex.org/W2001929205","https://openalex.org/W2002544902","https://openalex.org/W2002823447","https://openalex.org/W2007773308","https://openalex.org/W2011418450","https://openalex.org/W2015792496","https://openalex.org/W2020596226","https://openalex.org/W2022580207","https://openalex.org/W2022754257","https://openalex.org/W2024712990","https://openalex.org/W2025344250","https://openalex.org/W2027863625","https://openalex.org/W2027998089","https://openalex.org/W2033234421","https://openalex.org/W2034404018","https://openalex.org/W2035236239","https://openalex.org/W2036856777","https://openalex.org/W2039213393","https://openalex.org/W2041902442","https://openalex.org/W2041949618","https://openalex.org/W2049580917","https://openalex.org/W2052297107","https://openalex.org/W2053226681","https://openalex.org/W2055671247","https://openalex.org/W2063785360","https://openalex.org/W2064496705","https://openalex.org/W2066762419","https://openalex.org/W2068937960","https://openalex.org/W2072132753","https://openalex.org/W2073055013","https://openalex.org/W2075068750","https://openalex.org/W2084194234","https://openalex.org/W2085087109","https://openalex.org/W2085951228","https://openalex.org/W2090081099","https://openalex.org/W2092580280","https://openalex.org/W2093556881","https://openalex.org/W2098386530","https://openalex.org/W2136721036","https://openalex.org/W2137722071","https://openalex.org/W2143226810","https://openalex.org/W2147002086","https://openalex.org/W2148393427","https://openalex.org/W2152809699","https://openalex.org/W2503576964","https://openalex.org/W4234735672"],"related_works":["https://openalex.org/W2073055013","https://openalex.org/W2036856777","https://openalex.org/W192391954","https://openalex.org/W2007773308","https://openalex.org/W2050444194","https://openalex.org/W2026822531","https://openalex.org/W1993536537","https://openalex.org/W2768337126","https://openalex.org/W2159626109","https://openalex.org/W2087777579"],"abstract_inverted_index":{"7":[0],"Li":[1],"NMR":[2],"relaxation":[3,35,42,64,94,114],"measurements":[4,95],"under":[5,44],"spin-locking":[6,47,93],"conditions":[7],"are":[8],"used":[9],"to":[10,39,52,67,88],"probe":[11,136],"the":[12,16,29,45,55,58,61,68,71,77,110,119,123,127,130,138,142,145],"dynamical":[13,86],"properties":[14],"of":[15,22,100,109,122,129,137,144],"lithium":[17,79,111],"counterions":[18],"within":[19,115],"dense":[20],"dispersions":[21],"charged":[23],"anisotropic":[24],"nanoplatelets.":[25],"By":[26],"simultaneously":[27],"measuring":[28],"T":[30,33],"1\u03c1":[31],"and":[32,60,113,141],"2\u03c1":[34],"times":[36,43],"in":[37],"addition":[38],"triple-quantum":[40],"filtered":[41],"same":[46],"conditions,":[48],"it":[49],"is":[50,133],"possible":[51],"separately":[53],"quantify":[54],"contributions":[56],"from":[57,70],"quadrupolar":[59,73,131],"heterogeneous":[62,117],"dipolar":[63],"mechanisms.":[65],"Thanks":[66],"contribution":[69],"residual":[72],"coupling":[74,132],"felt":[75],"by":[76,91,105],"condensed":[78],"counterions,":[80],"that":[81],"procedure":[82],"allows":[83],"a":[84,97,106,134],"broad":[85],"range":[87],"be":[89],"probed":[90],"performing":[92],"using":[96],"limited":[98],"number":[99],"irradiation":[101],"powers.":[102],"As":[103],"illustrated":[104],"multiscale":[107],"modeling":[108],"diffusion":[112],"such":[116],"system,":[118],"frequency":[120],"variation":[121],"spectral":[124],"densities":[125],"characterizing":[126],"decorrelation":[128],"sensitive":[135],"ionic":[139],"mobility":[140],"structure":[143],"colloidal":[146],"dispersion.":[147]},"counts_by_year":[{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":2}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}