{"id":"https://openalex.org/W2092014431","doi":"https://doi.org/10.1021/ja800876k","title":"A Group 13/Group 17 Analogue of CO and N2: Coordinative Trapping of the GaI Molecule","display_name":"A Group 13/Group 17 Analogue of CO and N2: Coordinative Trapping of the GaI Molecule","publication_year":2008,"publication_date":"2008-04-01","ids":{"openalex":"https://openalex.org/W2092014431","doi":"https://doi.org/10.1021/ja800876k","mag":"2092014431","pmid":"https://pubmed.ncbi.nlm.nih.gov/18376829"},"language":"en","primary_location":{"id":"doi:10.1021/ja800876k","doi":"https://doi.org/10.1021/ja800876k","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja800876k","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","datacite","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://doi.org/10.25405/ncl.34638927","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5014256554","display_name":"N.D. Coombs","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]},{"id":"https://openalex.org/I84884186","display_name":"Newcastle University","ror":"https://ror.org/01kj2bm70","country_code":"GB","type":"education","lineage":["https://openalex.org/I84884186"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Natalie D. Coombs","raw_affiliation_strings":["Inorganic Chemistry, University of Oxford, South Parks Road, Oxford, U.K. OX1 3QR; Cardiff School of Chemistry, Main Building, Park Place, Cardiff, U.K. CF10 3AT, and School of Natural Sciences (Chemistry), Bedson Building, Newcastle University, Newcastle upon Tyne, U.K. NE1 7RU"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Inorganic Chemistry, University of Oxford, South Parks Road, Oxford, U.K. OX1 3QR; Cardiff School of Chemistry, Main Building, Park Place, Cardiff, U.K. CF10 3AT, and School of Natural Sciences (Chemistry), Bedson Building, Newcastle University, Newcastle upon Tyne, U.K. NE1 7RU","institution_ids":["https://openalex.org/I40120149","https://openalex.org/I84884186"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5065082245","display_name":"W. Clegg","orcid":"https://orcid.org/0000-0003-1643-5298","observed_orcids":["https://orcid.org/0000-0003-1643-5298"]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]},{"id":"https://openalex.org/I84884186","display_name":"Newcastle University","ror":"https://ror.org/01kj2bm70","country_code":"GB","type":"education","lineage":["https://openalex.org/I84884186"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"William Clegg","raw_affiliation_strings":["Inorganic Chemistry, University of Oxford, South Parks Road, Oxford, U.K. OX1 3QR; Cardiff School of Chemistry, Main Building, Park Place, Cardiff, U.K. CF10 3AT, and School of Natural Sciences (Chemistry), Bedson Building, Newcastle University, Newcastle upon Tyne, U.K. NE1 7RU"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Inorganic Chemistry, University of Oxford, South Parks Road, Oxford, U.K. OX1 3QR; Cardiff School of Chemistry, Main Building, Park Place, Cardiff, U.K. CF10 3AT, and School of Natural Sciences (Chemistry), Bedson Building, Newcastle University, Newcastle upon Tyne, U.K. NE1 7RU","institution_ids":["https://openalex.org/I40120149","https://openalex.org/I84884186"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087369600","display_name":"Amber L. Thompson","orcid":"https://orcid.org/0000-0001-8258-860X","observed_orcids":["https://orcid.org/0000-0001-8258-860X"]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]},{"id":"https://openalex.org/I84884186","display_name":"Newcastle University","ror":"https://ror.org/01kj2bm70","country_code":"GB","type":"education","lineage":["https://openalex.org/I84884186"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Amber L. Thompson","raw_affiliation_strings":["Inorganic Chemistry, University of Oxford, South Parks Road, Oxford, U.K. OX1 3QR; Cardiff School of Chemistry, Main Building, Park Place, Cardiff, U.K. CF10 3AT, and School of Natural Sciences (Chemistry), Bedson Building, Newcastle University, Newcastle upon Tyne, U.K. NE1 7RU"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Inorganic Chemistry, University of Oxford, South Parks Road, Oxford, U.K. OX1 3QR; Cardiff School of Chemistry, Main Building, Park Place, Cardiff, U.K. CF10 3AT, and School of Natural Sciences (Chemistry), Bedson Building, Newcastle University, Newcastle upon Tyne, U.K. NE1 7RU","institution_ids":["https://openalex.org/I40120149","https://openalex.org/I84884186"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009469968","display_name":"David J. Willock","orcid":"https://orcid.org/0000-0002-8893-1090","observed_orcids":["https://orcid.org/0000-0002-8893-1090"]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]},{"id":"https://openalex.org/I84884186","display_name":"Newcastle University","ror":"https://ror.org/01kj2bm70","country_code":"GB","type":"education","lineage":["https://openalex.org/I84884186"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"David J. Willock","raw_affiliation_strings":["Inorganic Chemistry, University of Oxford, South Parks Road, Oxford, U.K. OX1 3QR; Cardiff School of Chemistry, Main Building, Park Place, Cardiff, U.K. CF10 3AT, and School of Natural Sciences (Chemistry), Bedson Building, Newcastle University, Newcastle upon Tyne, U.K. NE1 7RU"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Inorganic Chemistry, University of Oxford, South Parks Road, Oxford, U.K. OX1 3QR; Cardiff School of Chemistry, Main Building, Park Place, Cardiff, U.K. CF10 3AT, and School of Natural Sciences (Chemistry), Bedson Building, Newcastle University, Newcastle upon Tyne, U.K. NE1 7RU","institution_ids":["https://openalex.org/I40120149","https://openalex.org/I84884186"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5007266295","display_name":"Simon Aldridge","orcid":"https://orcid.org/0000-0001-9998-9434","observed_orcids":["https://orcid.org/0000-0001-9998-9434"]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]},{"id":"https://openalex.org/I84884186","display_name":"Newcastle University","ror":"https://ror.org/01kj2bm70","country_code":"GB","type":"education","lineage":["https://openalex.org/I84884186"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Simon Aldridge","raw_affiliation_strings":["Inorganic Chemistry, University of Oxford, South Parks Road, Oxford, U.K. OX1 3QR; Cardiff School of Chemistry, Main Building, Park Place, Cardiff, U.K. CF10 3AT, and School of Natural Sciences (Chemistry), Bedson Building, Newcastle University, Newcastle upon Tyne, U.K. NE1 7RU"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Inorganic Chemistry, University of Oxford, South Parks Road, Oxford, U.K. OX1 3QR; Cardiff School of Chemistry, Main Building, Park Place, Cardiff, U.K. CF10 3AT, and School of Natural Sciences (Chemistry), Bedson Building, Newcastle University, Newcastle upon Tyne, U.K. NE1 7RU","institution_ids":["https://openalex.org/I40120149","https://openalex.org/I84884186"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":6.3633,"has_fulltext":false,"cited_by_count":62,"citation_normalized_percentile":{"value":0.9738046,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":98},"biblio":{"volume":"130","issue":"16","first_page":"5449","last_page":"5451"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.9843999743461609,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.9843999743461609,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.012199999764561653,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.0010999999940395355,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/gai","display_name":"GAI","score":0.7260000109672546},{"id":"https://openalex.org/keywords/isoelectronic-molecules","display_name":"isoelectronic molecules","score":0.781000018119812},{"id":"https://openalex.org/keywords/metal-ligand-bonding","display_name":"metal-ligand bonding","score":0.7279999852180481}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9689937829971313},{"id":"https://openalex.org/C2781311116","wikidata":"https://www.wikidata.org/wiki/Q83306","display_name":"Group (periodic table)","level":2,"score":0.841493546962738},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.6801894307136536},{"id":"https://openalex.org/C2777924906","wikidata":"https://www.wikidata.org/wiki/Q34168","display_name":"Trapping","level":2,"score":0.6778687238693237},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.40171417593955994},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17512068152427673},{"id":"https://openalex.org/C86803240","wikidata":"https://www.wikidata.org/wiki/Q420","display_name":"Biology","level":0,"score":0.0},{"id":"https://openalex.org/C18903297","wikidata":"https://www.wikidata.org/wiki/Q7150","display_name":"Ecology","level":1,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1021/ja800876k","doi":"https://doi.org/10.1021/ja800876k","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja800876k","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:18376829","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/18376829","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"},{"id":"doi:10.25405/ncl.34638927","doi":"https://doi.org/10.25405/ncl.34638927","is_oa":true,"landing_page_url":"https://doi.org/10.25405/ncl.34638927","pdf_url":null,"source":{"id":"https://openalex.org/S4306402485","display_name":"Newcastle University ePrints (Newcastle Univesity)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I84884186","host_organization_name":"Newcastle University","host_organization_lineage":["https://openalex.org/I84884186"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"JournalArticle"},{"id":"doi:10.25405/ncl.34638927.v1","doi":"https://doi.org/10.25405/ncl.34638927.v1","is_oa":true,"landing_page_url":"https://doi.org/10.25405/ncl.34638927.v1","pdf_url":null,"source":{"id":"https://openalex.org/S4306402485","display_name":"Newcastle University ePrints (Newcastle Univesity)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I84884186","host_organization_name":"Newcastle University","host_organization_lineage":["https://openalex.org/I84884186"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"JournalArticle"}],"best_oa_location":{"id":"doi:10.25405/ncl.34638927","doi":"https://doi.org/10.25405/ncl.34638927","is_oa":true,"landing_page_url":"https://doi.org/10.25405/ncl.34638927","pdf_url":null,"source":{"id":"https://openalex.org/S4306402485","display_name":"Newcastle University ePrints (Newcastle Univesity)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I84884186","host_organization_name":"Newcastle University","host_organization_lineage":["https://openalex.org/I84884186"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"JournalArticle"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3894483326","display_name":"National Crystallography Service 2006 Renewal","funder_award_id":"EP/D07746X/1","funder_id":"https://openalex.org/F4320334627","funder_display_name":"Engineering and Physical Sciences Research Council"}],"funders":[{"id":"https://openalex.org/F4320334627","display_name":"Engineering and Physical Sciences Research Council","ror":"https://ror.org/0439y7842"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":24,"referenced_works":["https://openalex.org/W1591139189","https://openalex.org/W1973159442","https://openalex.org/W1981612165","https://openalex.org/W1982470009","https://openalex.org/W1994935625","https://openalex.org/W2007522509","https://openalex.org/W2012812868","https://openalex.org/W2015229350","https://openalex.org/W2022964808","https://openalex.org/W2032008443","https://openalex.org/W2037528428","https://openalex.org/W2040082220","https://openalex.org/W2043693767","https://openalex.org/W2061632557","https://openalex.org/W2069329659","https://openalex.org/W2080506484","https://openalex.org/W2087919641","https://openalex.org/W2107708272","https://openalex.org/W2119870101","https://openalex.org/W2126809809","https://openalex.org/W2129393813","https://openalex.org/W2132217712","https://openalex.org/W2153368439","https://openalex.org/W2222564956"],"related_works":["https://openalex.org/W2000840592","https://openalex.org/W2146658792","https://openalex.org/W1964830010","https://openalex.org/W3034268710","https://openalex.org/W1999579378","https://openalex.org/W2950733631","https://openalex.org/W2074177204","https://openalex.org/W2085651471","https://openalex.org/W2043693767","https://openalex.org/W1925442928"],"abstract_inverted_index":{"The":[0],"first":[1],"row":[2],"diatomic":[3],"molecules":[4,34],"N2":[5],"and":[6,19,95,100,104],"CO":[7],"have":[8,25,46],"played":[9],"central":[10],"roles":[11],"in":[12,114],"developing":[13],"fundamental":[14],"models":[15],"of":[16],"electronic":[17],"structure,":[18],"their":[20],"interactions":[21],"with":[22],"transition":[23],"metals":[24],"been":[26],"widely":[27],"investigated.":[28],"By":[29],"contrast,":[30],"the":[31,56,74],"valence":[32],"isoelectronic":[33],"EX":[35],"(E":[36],"=":[37,42],"group":[38,43],"13":[39],"element,":[40],"X":[41],"17":[44],"element)":[45],"yet":[47],"to":[48,116],"be":[49],"isolated":[50],"under":[51],"ambient":[52],"conditions,":[53],"either":[54],"as":[55,60],"\"free\"":[57],"molecule":[58],"or":[59],"a":[61,80,87,108],"simple":[62],"metal":[63],"complex.":[64],"Here,":[65],"we":[66],"find":[67],"that":[68,117],"iodide":[69],"abstraction":[70],"from":[71],"Cp*Fe(dppe)(GaI2)":[72],"yields":[73],"stable":[75],"complex":[76],"[Cp*Fe(dppe)(GaI)]+":[77],"which":[78],"features":[79],"terminally":[81],"bound":[82],"GaI":[83],"ligand,":[84],"characterized":[85],"by":[86,96],"near":[88],"linear":[89],"(but":[90],"readily":[91],"deformed)":[92],"Fe-Ga-I":[93],"geometry":[94],"very":[97],"short":[98],"Fe-Ga":[99],"Ga-I":[101],"distances.":[102],"Chemical":[103],"computational":[105],"evidence":[106],"reveal":[107],"relatively":[109],"weak":[110],"metal-ligand":[111],"bond":[112],"similar":[113],"strength":[115],"found":[118],"for":[119],"dinitrogen":[120],"analogues.":[121]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":3},{"year":2018,"cited_by_count":1},{"year":2015,"cited_by_count":2},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":5},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-03T10:50:19.383937","created_date":"2016-06-24T00:00:00"}