{"id":"https://openalex.org/W2091587795","doi":"https://doi.org/10.1021/ic800442y","title":"Rosamine-Based Fluorescent Chemosensor for Selective Detection of Silver(I) in an Aqueous Solution","display_name":"Rosamine-Based Fluorescent Chemosensor for Selective Detection of Silver(I) in an Aqueous Solution","publication_year":2008,"publication_date":"2008-04-24","ids":{"openalex":"https://openalex.org/W2091587795","doi":"https://doi.org/10.1021/ic800442y","mag":"2091587795","pmid":"https://pubmed.ncbi.nlm.nih.gov/18433117"},"language":"en","primary_location":{"id":"doi:10.1021/ic800442y","doi":"https://doi.org/10.1021/ic800442y","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic800442y","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5015171995","display_name":"Shohei Iyoshi","orcid":"https://orcid.org/0000-0003-4596-2177","observed_orcids":["https://orcid.org/0000-0003-4596-2177"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Shohei Iyoshi","raw_affiliation_strings":["Graduate School of Human & Environmental Studies and Graduate School of Global Environmental Studies, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Graduate School of Human & Environmental Studies and Graduate School of Global Environmental Studies, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5015933283","display_name":"Masayasu Taki","orcid":"https://orcid.org/0000-0003-2185-4593","observed_orcids":["https://orcid.org/0000-0003-2185-4593"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Masayasu Taki","raw_affiliation_strings":["Graduate School of Human & Environmental Studies and Graduate School of Global Environmental Studies, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Graduate School of Human & Environmental Studies and Graduate School of Global Environmental Studies, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5072470765","display_name":"Yukio Yamamoto","orcid":"https://orcid.org/0000-0002-8530-0701","observed_orcids":["https://orcid.org/0000-0002-8530-0701"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yukio Yamamoto","raw_affiliation_strings":["Graduate School of Human & Environmental Studies and Graduate School of Global Environmental Studies, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Graduate School of Human & Environmental Studies and Graduate School of Global Environmental Studies, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan","institution_ids":["https://openalex.org/I22299242"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5015933283"],"corresponding_institution_ids":["https://openalex.org/I22299242"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":4.854,"has_fulltext":false,"cited_by_count":107,"citation_normalized_percentile":{"value":0.96640015,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"47","issue":"10","first_page":"3946","last_page":"3948"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10532","display_name":"Molecular Sensors and Ion Detection","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10532","display_name":"Molecular Sensors and Ion Detection","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11240","display_name":"Luminescence and Fluorescent Materials","score":0.00139999995008111,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/fluorescent-sensors","display_name":"fluorescent sensors","score":0.9599999785423279},{"id":"https://openalex.org/keywords/silver-ion-sensing","display_name":"silver ion detection","score":0.8550000190734863},{"id":"https://openalex.org/keywords/aqueous-solutions","display_name":"aqueous solutions","score":0.8799999952316284},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5249999761581421},{"id":"https://openalex.org/keywords/trigonal-planar-geometry","display_name":"trigonal planar coordination","score":0.8289999961853027},{"id":"https://openalex.org/keywords/sulfur-ligands","display_name":"sulfur-containing ligands","score":0.527999997138977},{"id":"https://openalex.org/keywords/photoinduced-electron-transfer","display_name":"photoinduced electron transfer","score":0.9490000009536743},{"id":"https://openalex.org/keywords/fluorescence-enhancement","display_name":"fluorescence enhancement","score":0.8790000081062317},{"id":"https://openalex.org/keywords/coordination-chemistry","display_name":"coordination chemistry","score":0.3889999985694885}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9609214067459106},{"id":"https://openalex.org/C91881484","wikidata":"https://www.wikidata.org/wiki/Q191807","display_name":"Fluorescence","level":2,"score":0.8662014007568359},{"id":"https://openalex.org/C2776568683","wikidata":"https://www.wikidata.org/wiki/Q23005640","display_name":"Moiety","level":2,"score":0.752475917339325},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.7291240692138672},{"id":"https://openalex.org/C2779244968","wikidata":"https://www.wikidata.org/wiki/Q186414","display_name":"Aniline","level":2,"score":0.7163798809051514},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.70610511302948},{"id":"https://openalex.org/C2781018080","wikidata":"https://www.wikidata.org/wiki/Q7187813","display_name":"Photoinduced electron transfer","level":3,"score":0.6867987513542175},{"id":"https://openalex.org/C171001562","wikidata":"https://www.wikidata.org/wiki/Q2856048","display_name":"Quantum yield","level":3,"score":0.6483819484710693},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4818207323551178},{"id":"https://openalex.org/C197404232","wikidata":"https://www.wikidata.org/wiki/Q319827","display_name":"Chelation","level":2,"score":0.44868600368499756},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.43708282709121704},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.42596733570098877},{"id":"https://openalex.org/C199164860","wikidata":"https://www.wikidata.org/wiki/Q6822745","display_name":"Metal ions in aqueous solution","level":3,"score":0.42282670736312866},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.3613658547401428},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3439113199710846},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.33038026094436646},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.1856641173362732},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.17607715725898743},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1503525972366333},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D000814","descriptor_name":"Aniline Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D005456","descriptor_name":"Fluorescent Dyes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008958","descriptor_name":"Models, Molecular","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012834","descriptor_name":"Silver","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D012996","descriptor_name":"Solutions","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D014966","descriptor_name":"Xanthenes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D015394","descriptor_name":"Molecular Structure","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1021/ic800442y","doi":"https://doi.org/10.1021/ic800442y","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic800442y","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:18433117","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/18433117","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320912","display_name":"Ministry of Education, Culture, Sports, Science and Technology","ror":"https://ror.org/048rj2z13"},{"id":"https://openalex.org/F4320334764","display_name":"Japan Society for the Promotion of Science","ror":"https://ror.org/00hhkn466"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":37,"referenced_works":["https://openalex.org/W204294393","https://openalex.org/W356225972","https://openalex.org/W633396529","https://openalex.org/W1547147585","https://openalex.org/W1601936385","https://openalex.org/W1978059664","https://openalex.org/W1981126082","https://openalex.org/W2002525163","https://openalex.org/W2004345351","https://openalex.org/W2005936128","https://openalex.org/W2006572561","https://openalex.org/W2012543803","https://openalex.org/W2016733868","https://openalex.org/W2025921028","https://openalex.org/W2043208802","https://openalex.org/W2043913075","https://openalex.org/W2049826930","https://openalex.org/W2051029649","https://openalex.org/W2062116598","https://openalex.org/W2062900498","https://openalex.org/W2065257131","https://openalex.org/W2079507386","https://openalex.org/W2086757937","https://openalex.org/W2086927986","https://openalex.org/W2089654888","https://openalex.org/W2093130867","https://openalex.org/W2094542849","https://openalex.org/W2105177764","https://openalex.org/W2115068264","https://openalex.org/W2118749301","https://openalex.org/W2132762533","https://openalex.org/W2163151727","https://openalex.org/W2176456641","https://openalex.org/W2479563444","https://openalex.org/W2951753738","https://openalex.org/W3123172076","https://openalex.org/W4241445517"],"related_works":["https://openalex.org/W1451233792","https://openalex.org/W1971151513","https://openalex.org/W2039358080","https://openalex.org/W3042223102","https://openalex.org/W1977495164","https://openalex.org/W2023496410","https://openalex.org/W1940012012","https://openalex.org/W2005807346","https://openalex.org/W2006848810","https://openalex.org/W1801733820"],"abstract_inverted_index":{"The":[0,50],"synthesis":[1],"and":[2,120],"photophysical":[3],"properties":[4],"of":[5,33,53,61,82,125],"a":[6,25,36,64,78],"rosamine-based":[7],"fluorescent":[8,22],"chemosensor,":[9],"RosAg,":[10],"for":[11],"detecting":[12],"Ag":[13],"ion":[14],"in":[15,30,39,68,87,108,122],"an":[16],"aqueous":[17],"solution":[18,110],"are":[19],"described.":[20],"This":[21,112],"sensor":[23],"has":[24],"negligible":[26],"quantum":[27],"yield":[28],"(<0.005)":[29],"the":[31,54,58,74,88,91,105,109,115,123],"absence":[32],"Ag(+),":[34],"whereas":[35],"significant":[37],"increase":[38],"fluorescence":[40],"is":[41,84,99],"observed":[42,86],"upon":[43],"complexation":[44],"with":[45,57,104],"Ag(+)":[46,106],"under":[47],"physiological":[48],"conditions.":[49],"crystal":[51,89],"structure":[52],"silver":[55],"complex":[56],"chelator":[59],"moiety":[60],"RosAg":[62],"reveals":[63],"trigonal-planar":[65],"coordination":[66],"geometry":[67],"which":[69],"three":[70],"S":[71],"atoms":[72],"occupy":[73],"metal":[75],"center.":[76],"Although":[77],"strong":[79],"coordinative":[80],"interaction":[81],"Ag-N":[83],"not":[85],"structure,":[90],"(1)H":[92],"NMR":[93],"experiments":[94],"suggest":[95],"that":[96],"aniline":[97],"nitrogen":[98],"likely":[100],"to":[101],"be":[102],"associated":[103],"center":[107],"state.":[111],"may":[113],"inhibit":[114],"photoinduced":[116],"electron":[117],"transfer":[118],"process":[119],"result":[121],"enhancement":[124],"fluorescence.":[126]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":4},{"year":2018,"cited_by_count":5},{"year":2017,"cited_by_count":6},{"year":2016,"cited_by_count":5},{"year":2015,"cited_by_count":6},{"year":2014,"cited_by_count":6},{"year":2013,"cited_by_count":9},{"year":2012,"cited_by_count":13}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}