{"id":"https://openalex.org/W2091305743","doi":"https://doi.org/10.1021/ic2006265","title":"Monoanionic Molybdenum and Tungsten Tris(dithiolene) Complexes: A Multifrequency EPR Study","display_name":"Monoanionic Molybdenum and Tungsten Tris(dithiolene) Complexes: A Multifrequency EPR Study","publication_year":2011,"publication_date":"2011-06-23","ids":{"openalex":"https://openalex.org/W2091305743","doi":"https://doi.org/10.1021/ic2006265","mag":"2091305743","pmid":"https://pubmed.ncbi.nlm.nih.gov/21699192"},"language":"en","primary_location":{"id":"doi:10.1021/ic2006265","doi":"https://doi.org/10.1021/ic2006265","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic2006265","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5023609771","display_name":"Stephen A. Sproules","orcid":"https://orcid.org/0000-0003-3587-0375","observed_orcids":["https://orcid.org/0000-0003-3587-0375"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Stephen Sproules","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany","institution_ids":["https://openalex.org/I149899117"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5014941782","display_name":"Priyabrata Banerjee","orcid":"https://orcid.org/0000-0002-3009-5894","observed_orcids":["https://orcid.org/0000-0002-3009-5894"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I66760702","display_name":"Council of Scientific and Industrial Research","ror":"https://ror.org/021wm7p51","country_code":"IN","type":"government","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I66760702"]},{"id":"https://openalex.org/I70735523","display_name":"Central Mechanical Engineering Research Institute","ror":"https://ror.org/059h0ng81","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I4210134808","https://openalex.org/I66760702","https://openalex.org/I70735523"]}],"countries":["DE","IN"],"is_corresponding":false,"raw_author_name":"Priyabrata Banerjee","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany","CSIR - Central Mechanical Engineering Research Institute"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany","institution_ids":["https://openalex.org/I149899117"]},{"raw_affiliation_string":"CSIR - Central Mechanical Engineering Research Institute","institution_ids":["https://openalex.org/I66760702","https://openalex.org/I70735523"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020886062","display_name":"Thomas Weyherm\u00fcller","orcid":"https://orcid.org/0000-0002-0399-7999","observed_orcids":["https://orcid.org/0000-0002-0399-7999"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Thomas Weyherm\u00fcller","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany","institution_ids":["https://openalex.org/I149899117"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5073177245","display_name":"Yong Sheng Yan","orcid":"https://orcid.org/0000-0001-6361-0541","observed_orcids":["https://orcid.org/0000-0001-6361-0541"]},"institutions":[{"id":"https://openalex.org/I114832834","display_name":"Tulane University","ror":"https://ror.org/04vmvtb21","country_code":"US","type":"education","lineage":["https://openalex.org/I114832834"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Yong Yan","raw_affiliation_strings":["Department of Chemistry, Tulane University, 6400 Freret Street, New Orleans, Louisiana 70118-5698, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Tulane University, 6400 Freret Street, New Orleans, Louisiana 70118-5698, United States","institution_ids":["https://openalex.org/I114832834"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028429415","display_name":"James P. Donahue","orcid":"https://orcid.org/0000-0001-9768-4813","observed_orcids":["https://orcid.org/0000-0001-9768-4813"]},"institutions":[{"id":"https://openalex.org/I114832834","display_name":"Tulane University","ror":"https://ror.org/04vmvtb21","country_code":"US","type":"education","lineage":["https://openalex.org/I114832834"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"James P. Donahue","raw_affiliation_strings":["Department of Chemistry, Tulane University, 6400 Freret Street, New Orleans, Louisiana 70118-5698, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Tulane University, 6400 Freret Street, New Orleans, Louisiana 70118-5698, United States","institution_ids":["https://openalex.org/I114832834"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5073896912","display_name":"Karl E. Wieghardt","orcid":"https://orcid.org/0000-0003-0600-7855","observed_orcids":["https://orcid.org/0000-0003-0600-7855"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Karl Wieghardt","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany","institution_ids":["https://openalex.org/I149899117"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5023609771","https://openalex.org/A5028429415","https://openalex.org/A5073896912"],"corresponding_institution_ids":["https://openalex.org/I114832834","https://openalex.org/I149899117"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.698,"has_fulltext":false,"cited_by_count":63,"citation_normalized_percentile":{"value":0.93887887,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"50","issue":"15","first_page":"7106","last_page":"7122"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11758","display_name":"Organic and Molecular Conductors Research","score":0.44040000438690186,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11758","display_name":"Organic and Molecular Conductors Research","score":0.44040000438690186,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.2985999882221222,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.11190000176429749,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/electron-spin-resonance","display_name":"electron spin resonance","score":0.671999990940094},{"id":"https://openalex.org/keywords/spin-hamiltonian-parameters","display_name":"spin Hamiltonian parameters","score":0.9599999785423279},{"id":"https://openalex.org/keywords/electronic-structure","display_name":"electronic structure","score":0.7570000290870667},{"id":"https://openalex.org/keywords/superhyperfine-coupling","display_name":"superhyperfine coupling","score":0.7310000061988831},{"id":"https://openalex.org/keywords/g-factor-anisotropy","display_name":"g-factor anisotropy","score":0.9419999718666077},{"id":"https://openalex.org/keywords/ligand-reduction","display_name":"ligand reduction","score":0.7730000019073486},{"id":"https://openalex.org/keywords/cyclic-voltammetry","display_name":"cyclic voltammetry","score":0.753000020980835}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9721230268478394},{"id":"https://openalex.org/C549387045","wikidata":"https://www.wikidata.org/wiki/Q1053","display_name":"Molybdenum","level":2,"score":0.9101514220237732},{"id":"https://openalex.org/C2781014771","wikidata":"https://www.wikidata.org/wiki/Q413961","display_name":"Tris","level":2,"score":0.861213207244873},{"id":"https://openalex.org/C542268612","wikidata":"https://www.wikidata.org/wiki/Q743","display_name":"Tungsten","level":2,"score":0.8532020449638367},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.7816040515899658},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4108211398124695},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4027281403541565},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.35638105869293213},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2055359184741974},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.15930244326591492},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[{"descriptor_ui":"D004563","descriptor_name":"Electrochemistry","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D004578","descriptor_name":"Electron Spin Resonance Spectroscopy","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":true},{"descriptor_ui":"D004583","descriptor_name":"Electrons","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008024","descriptor_name":"Ligands","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008958","descriptor_name":"Models, Molecular","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008968","descriptor_name":"Molecular Conformation","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008982","descriptor_name":"Molybdenum","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D009942","descriptor_name":"Organometallic Compounds","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":false},{"descriptor_ui":"D009942","descriptor_name":"Organometallic Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D013379","descriptor_name":"Substrate Specificity","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D013438","descriptor_name":"Sulfhydryl Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D014414","descriptor_name":"Tungsten","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D018360","descriptor_name":"Crystallography, X-Ray","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":4,"locations":[{"id":"doi:10.1021/ic2006265","doi":"https://doi.org/10.1021/ic2006265","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic2006265","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:21699192","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/21699192","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:edoc.mpg.de:577889","doi":null,"is_oa":false,"landing_page_url":"http://edoc.mpg.de/577889","pdf_url":null,"source":{"id":"https://openalex.org/S4406922265","display_name":"Max Planck Institute for Plasma Physics","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Inorganic Chemistry, v.50, 7106-7122 (2011)","raw_type":"Article"},{"id":"pmh:oai:eprints.gla.ac.uk:94349","doi":null,"is_oa":false,"landing_page_url":"http://eprints.gla.ac.uk/94349/","pdf_url":null,"source":{"id":"https://openalex.org/S4210235606","display_name":"ENLIGHTEN (Jurnal Bimbingan dan Konseling Islam)","issn_l":"2622-8912","issn":["2622-8912","2622-8920"],"is_oa":false,"is_in_doaj":true,"is_core":false,"listed_in":["doaj"],"host_organization":"https://openalex.org/I4405259220","host_organization_name":"Institut Agama Islam Negeri Langsa","host_organization_lineage":["https://openalex.org/I4405259220"],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Articles"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":76,"referenced_works":["https://openalex.org/W165400752","https://openalex.org/W1490393732","https://openalex.org/W1582727934","https://openalex.org/W1708984004","https://openalex.org/W1749277125","https://openalex.org/W1918494586","https://openalex.org/W1965194719","https://openalex.org/W1966667217","https://openalex.org/W1967660707","https://openalex.org/W1969078948","https://openalex.org/W1979211564","https://openalex.org/W1985639336","https://openalex.org/W1987777444","https://openalex.org/W1988091937","https://openalex.org/W1988557359","https://openalex.org/W2001699920","https://openalex.org/W2002031955","https://openalex.org/W2008014856","https://openalex.org/W2009401460","https://openalex.org/W2010200254","https://openalex.org/W2013183108","https://openalex.org/W2017242725","https://openalex.org/W2021108534","https://openalex.org/W2023271753","https://openalex.org/W2028498874","https://openalex.org/W2029895267","https://openalex.org/W2042054507","https://openalex.org/W2044955954","https://openalex.org/W2045386814","https://openalex.org/W2045462665","https://openalex.org/W2045645700","https://openalex.org/W2046738998","https://openalex.org/W2048642998","https://openalex.org/W2051188308","https://openalex.org/W2055445037","https://openalex.org/W2055770627","https://openalex.org/W2055874817","https://openalex.org/W2055940300","https://openalex.org/W2056606144","https://openalex.org/W2057747483","https://openalex.org/W2058317823","https://openalex.org/W2058351048","https://openalex.org/W2060148931","https://openalex.org/W2060962014","https://openalex.org/W2071380348","https://openalex.org/W2072365604","https://openalex.org/W2073276776","https://openalex.org/W2074331108","https://openalex.org/W2074768592","https://openalex.org/W2075114792","https://openalex.org/W2076868875","https://openalex.org/W2079124090","https://openalex.org/W2084095879","https://openalex.org/W2084402676","https://openalex.org/W2090309515","https://openalex.org/W2102409677","https://openalex.org/W2113084681","https://openalex.org/W2126864213","https://openalex.org/W2129482946","https://openalex.org/W2135261637","https://openalex.org/W2143981217","https://openalex.org/W2155616091","https://openalex.org/W2315445416","https://openalex.org/W2324389639","https://openalex.org/W2329077548","https://openalex.org/W2332355425","https://openalex.org/W2334036400","https://openalex.org/W2949605658","https://openalex.org/W2950208888","https://openalex.org/W2952062431","https://openalex.org/W2952190752","https://openalex.org/W3137276436","https://openalex.org/W3137552403","https://openalex.org/W4229620782","https://openalex.org/W4234928581","https://openalex.org/W4244498511"],"related_works":["https://openalex.org/W2025927160","https://openalex.org/W2027503062","https://openalex.org/W2015149658","https://openalex.org/W1965277400","https://openalex.org/W2030026097","https://openalex.org/W1979211564","https://openalex.org/W2337950862","https://openalex.org/W1932485314","https://openalex.org/W2143833391","https://openalex.org/W2118857809"],"abstract_inverted_index":{"Numerous":[0],"Mo":[1,53],"and":[2,13,62,70,83,89,109,168,174,198,229],"W":[3,56],"tris(dithiolene)":[4,118,166],"complexes":[5,119,264],"in":[6,59,213],"varying":[7],"redox":[8],"states":[9],"have":[10,120],"been":[11,121],"prepared":[12],"representative":[14],"examples":[15],"characterized":[16,170],"crystallographically:":[17],"[M(S(2)C(2)R(2))(3)](z)":[18],"[M":[19],"=":[20,23,26,33,36,39,46,49,52,153,186],"Mo,":[21],"R":[22,35,45],"Ph,":[24,37],"z":[25,38,48],"0":[27,40],"(1)":[28],"or":[29,42,55],"1-":[30,43],"(2);":[31],"M":[32,51],"W,":[34],"(4)":[41],"(5);":[44],"CN,":[47],"2-,":[50],"(3)":[54],"(6)].":[57],"Changes":[58],"dithiolene":[60,84],"C-S":[61],"C-C":[63],"bond":[64],"lengths":[65],"for":[66,92,136,268],"1":[67],"versus":[68,72,94,97],"2":[69,93],"4":[71],"5":[73,96],"are":[74],"indicative":[75],"of":[76,115,142,227,238],"ligand":[77],"reduction.":[78],"Trigonal":[79],"twist":[80],"angles":[81,86],"(\u0398)":[82],"fold":[85],"(\u03b1)":[87],"increase":[88],"decrease,":[90],"respectively,":[91],"1,":[95],"4.":[98],"Cyclic":[99],"voltammetry":[100],"reveals":[101],"generally":[102],"two":[103,143,252],"reversible":[104],"couples":[105],"corresponding":[106,262],"to":[107,164,225],"0/1-":[108],"1-/2-":[110],"reductions.":[111],"The":[112,148,179,206,218,235,258],"electronic":[113,145,207,215,246],"structures":[114],"monoanionic":[116],"molybdenum":[117,176],"analyzed":[122],"by":[123,133,171,194,251],"multifrequency":[124],"(S-,":[125],"X-,":[126],"Q-band)":[127],"EPR":[128,236],"spectroscopy.":[129],"Spin-Hamiltonian":[130],"parameters":[131,223,242],"afforded":[132],"spectral":[134],"simulation":[135],"each":[137],"complex":[138],"demonstrate":[139],"the":[140,160,165,203,261],"existence":[141],"distinctive":[144],"structure":[146,208,247],"types.":[147],"first":[149],"is":[150,169,181,210,231,248],"[Mo(IV)((A)L(3)(5-\u2022))](1-)":[151,263],"((A)L":[152],"olefinic":[154],"dithiolene,":[155,188],"type":[156,189],"A),":[157],"which":[158],"has":[159],"unpaired":[161],"electron":[162],"restricted":[163],"unit":[167],"isotropic":[172],"g-values":[173],"small":[175],"superhyperfine":[177],"coupling.":[178],"second":[180],"formulated":[182,232],"as":[183,233],"[Mo(V)((B)L(3)(6-))](1-)":[184],"((B)L":[185],"aromatic":[187],"B)":[190],"with":[191,202,260],"spectra":[192,237],"distinguished":[193],"a":[195],"prominent":[196],"g-anisotropy":[197],"hyperfine":[199],"coupling":[200],"consistent":[201],"(d(z(2)))(1)":[204],"paramagnet.":[205],"disparity":[209],"also":[211],"manifested":[212],"their":[214,245],"absorption":[216],"spectra.":[217],"compound":[219],"[W(bdt)(3)](1-)":[220],"exhibits":[221],"spin-Hamiltonian":[222,241],"similar":[224],"those":[226],"[Mo(bdt)(3)](1-)":[228],"thus":[230],"[W(V)((B)L(3)(6-))](1-).":[234],"[W((A)L(3))](1-)":[239],"display":[240],"that":[243],"suggest":[244],"best":[249],"represented":[250],"resonance":[253],"forms":[254],"{[W(IV)((A)L(3)(5-\u2022))](1-)":[255],"\u2194":[256],"[W(V)((A)L(3)(6-))](1-)}.":[257],"contrast":[259],"highlights":[265],"tungsten's":[266],"preference":[267],"higher":[269],"oxidation":[270],"states.":[271]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":5},{"year":2017,"cited_by_count":5},{"year":2016,"cited_by_count":5},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":8},{"year":2013,"cited_by_count":9},{"year":2012,"cited_by_count":8}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}