{"id":"https://openalex.org/W2090494102","doi":"https://doi.org/10.1002/chin.199408250","title":"ChemInform Abstract: Rate\u2010Determining Carbonyl Hydration in the Intramolecular Hydrolysis of Phenacyl Phosphonate Esters: Isotopic Probes and Activation Parameters.","display_name":"ChemInform Abstract: Rate\u2010Determining Carbonyl Hydration in the Intramolecular Hydrolysis of Phenacyl Phosphonate Esters: Isotopic Probes and Activation Parameters.","publication_year":1994,"publication_date":"1994-02-22","ids":{"openalex":"https://openalex.org/W2090494102","doi":"https://doi.org/10.1002/chin.199408250","mag":"2090494102"},"language":"en","primary_location":{"id":"doi:10.1002/chin.199408250","doi":"https://doi.org/10.1002/chin.199408250","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chin.199408250","pdf_url":null,"source":{"id":"https://openalex.org/S41354064","display_name":"ChemInform","issn_l":"0009-2975","issn":["0009-2975","0931-7597","1431-5890","1522-2667","2199-2924"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemInform","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5053162331","display_name":"Ildiko M. Kovach","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I84470341","display_name":"Catholic University of America","ror":"https://ror.org/047yk3s18","country_code":"US","type":"education","lineage":["https://openalex.org/I84470341"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"I. M. KOVACH","raw_affiliation_strings":["Dep. Chem., Cathol. Univ. Am., Washington, DC 20064, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Cathol. Univ. Am., Washington, DC 20064, USA","institution_ids":["https://openalex.org/I84470341"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Q. ZHAO","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I84470341","display_name":"Catholic University of America","ror":"https://ror.org/047yk3s18","country_code":"US","type":"education","lineage":["https://openalex.org/I84470341"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Q. ZHAO","raw_affiliation_strings":["Dep. Chem., Cathol. Univ. Am., Washington, DC 20064, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Cathol. Univ. Am., Washington, DC 20064, USA","institution_ids":["https://openalex.org/I84470341"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002624105","display_name":"Matthew Keane","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I84470341","display_name":"Catholic University of America","ror":"https://ror.org/047yk3s18","country_code":"US","type":"education","lineage":["https://openalex.org/I84470341"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"M. KEANE","raw_affiliation_strings":["Dep. Chem., Cathol. Univ. Am., Washington, DC 20064, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Cathol. Univ. Am., Washington, DC 20064, USA","institution_ids":["https://openalex.org/I84470341"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5091853791","display_name":"Rachel Reyes","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I84470341","display_name":"Catholic University of America","ror":"https://ror.org/047yk3s18","country_code":"US","type":"education","lineage":["https://openalex.org/I84470341"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"R. REYES","raw_affiliation_strings":["Dep. Chem., Cathol. Univ. Am., Washington, DC 20064, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Dep. Chem., Cathol. Univ. Am., Washington, DC 20064, USA","institution_ids":["https://openalex.org/I84470341"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I84470341"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.20487411,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"25","issue":"8","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.0017999999690800905,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12358","display_name":"Thermal and Kinetic Analysis","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/carbonyl-hydration","display_name":"carbonyl hydration","score":0.9570000171661377},{"id":"https://openalex.org/keywords/rate-limiting-step","display_name":"rate-determining step","score":0.8880000114440918},{"id":"https://openalex.org/keywords/isotopic-labeling","display_name":"isotopic labeling","score":0.7760000228881836},{"id":"https://openalex.org/keywords/activation-parameters","display_name":"activation parameters","score":0.9620000123977661},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.45500001311302185}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9736126065254211},{"id":"https://openalex.org/C2777626080","wikidata":"https://www.wikidata.org/wiki/Q422733","display_name":"Phosphonate","level":2,"score":0.8848099708557129},{"id":"https://openalex.org/C75079739","wikidata":"https://www.wikidata.org/wiki/Q1571801","display_name":"Intramolecular force","level":2,"score":0.7577047348022461},{"id":"https://openalex.org/C2780570554","wikidata":"https://www.wikidata.org/wiki/Q2419401","display_name":"Phenacyl","level":2,"score":0.7392420768737793},{"id":"https://openalex.org/C94412978","wikidata":"https://www.wikidata.org/wiki/Q103135","display_name":"Hydrolysis","level":2,"score":0.5791261196136475},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.425295889377594},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3182026743888855},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.27909398078918457},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2711331248283386}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/chin.199408250","doi":"https://doi.org/10.1002/chin.199408250","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chin.199408250","pdf_url":null,"source":{"id":"https://openalex.org/S41354064","display_name":"ChemInform","issn_l":"0009-2975","issn":["0009-2975","0931-7597","1431-5890","1522-2667","2199-2924"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemInform","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":1,"referenced_works":["https://openalex.org/W2952781543"],"related_works":["https://openalex.org/W2952781543","https://openalex.org/W2328618727","https://openalex.org/W2951095750","https://openalex.org/W2070873877","https://openalex.org/W2024004531","https://openalex.org/W2035703589","https://openalex.org/W2066983784","https://openalex.org/W2053025160","https://openalex.org/W2607345921","https://openalex.org/W2951619306"],"abstract_inverted_index":{"Abstract":[0,25],"ChemInform":[1,24],"is":[2,42],"a":[3,11,23,35],"weekly":[4],"Abstracting":[5],"Service,":[6],"delivering":[7],"concise":[8],"information":[9],"at":[10],"glance":[12],"that":[13],"was":[14,30],"extracted":[15],"from":[16],"about":[17],"100":[18],"leading":[19],"journals.":[20],"To":[21],"access":[22],"of":[26],"an":[27],"article":[28,41],"which":[29],"published":[31],"elsewhere,":[32],"please":[33],"select":[34],"\u201cFull":[36],"Text\u201d":[37],"option.":[38,47],"The":[39],"original":[40],"trackable":[43],"via":[44],"the":[45],"\u201cReferences\u201d":[46]},"counts_by_year":[],"updated_date":"2026-09-27T08:07:27.782135","created_date":"2016-06-24T00:00:00"}