{"id":"https://openalex.org/W2089452279","doi":"https://doi.org/10.1021/ja00264a026","title":"Control of the reactivity and coordination number of a 16-electron complex by .pi.-donating thiolate ligands","display_name":"Control of the reactivity and coordination number of a 16-electron complex by .pi.-donating thiolate ligands","publication_year":1986,"publication_date":"1986-02-01","ids":{"openalex":"https://openalex.org/W2089452279","doi":"https://doi.org/10.1021/ja00264a026","mag":"2089452279"},"language":"en","primary_location":{"id":"doi:10.1021/ja00264a026","doi":"https://doi.org/10.1021/ja00264a026","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00264a026","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5086031829","display_name":"Michael T. Ashby","orcid":"https://orcid.org/0000-0003-1875-4823","observed_orcids":["https://orcid.org/0000-0003-1875-4823"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Michael T. Ashby","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5018957391","display_name":"John H. Enemark","orcid":"https://orcid.org/0000-0002-5272-3652","observed_orcids":["https://orcid.org/0000-0002-5272-3652"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"John H. Enemark","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.8014,"has_fulltext":false,"cited_by_count":48,"citation_normalized_percentile":{"value":0.8994232,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":90,"max":94},"biblio":{"volume":"108","issue":"4","first_page":"730","last_page":"733"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9067000150680542,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9067000150680542,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.06319999694824219,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.013399999588727951,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/16-electron-complexes","display_name":"16-electron complexes","score":0.9100000262260437},{"id":"https://openalex.org/keywords/thiolate-ligands","display_name":"thiolate ligands","score":0.8980000019073486},{"id":"https://openalex.org/keywords/pi-donor-ligands","display_name":"\u03c0-donor ligands","score":0.8360000252723694},{"id":"https://openalex.org/keywords/reactivity-control","display_name":"reactivity control","score":0.8379999995231628},{"id":"https://openalex.org/keywords/coordination-compounds","display_name":"metal complexes","score":0.39800000190734863},{"id":"https://openalex.org/keywords/ligand-exchange","display_name":"ligand exchange","score":0.47699999809265137}],"concepts":[{"id":"https://openalex.org/C2778805511","wikidata":"https://www.wikidata.org/wiki/Q1713","display_name":"Citation","level":2,"score":0.7409090995788574},{"id":"https://openalex.org/C2778447006","wikidata":"https://www.wikidata.org/wiki/Q1156474","display_name":"Icon","level":2,"score":0.6692894697189331},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.6082620620727539},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.5848584771156311},{"id":"https://openalex.org/C23123220","wikidata":"https://www.wikidata.org/wiki/Q816826","display_name":"Information retrieval","level":1,"score":0.4615369737148285},{"id":"https://openalex.org/C2778407487","wikidata":"https://www.wikidata.org/wiki/Q14565201","display_name":"Altmetrics","level":2,"score":0.4594183564186096},{"id":"https://openalex.org/C518677369","wikidata":"https://www.wikidata.org/wiki/Q202833","display_name":"Social media","level":2,"score":0.41837409138679504},{"id":"https://openalex.org/C136764020","wikidata":"https://www.wikidata.org/wiki/Q466","display_name":"World Wide Web","level":1,"score":0.3288434147834778},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.16506707668304443},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ja00264a026","doi":"https://doi.org/10.1021/ja00264a026","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00264a026","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320332161","display_name":"National Institutes of Health","ror":"https://ror.org/01cwqze88"},{"id":"https://openalex.org/F4320337361","display_name":"National Institute of Environmental Health Sciences","ror":"https://ror.org/00j4k1h63"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W3005162010","https://openalex.org/W3158583431","https://openalex.org/W4389781107","https://openalex.org/W2956160153","https://openalex.org/W2027399773","https://openalex.org/W2966794409","https://openalex.org/W2038982477","https://openalex.org/W2042547173","https://openalex.org/W2406810168","https://openalex.org/W2015242737"],"abstract_inverted_index":{"ADVERTISEMENT":[0],"RETURN":[1],"TO":[2],"ISSUEPREVArticleNEXTControl":[3],"of":[4,10,58,93,119],"the":[5,55,86,91,120,131,144,147,152,159,165],"reactivity":[6],"and":[7,20,68,73,102,146,163,179,181],"coordination":[8],"number":[9,92],"a":[11,116,123,136],"16-electron":[12],"complex":[13],"by":[14,100],".pi.-donating":[15],"thiolate":[16],"ligandsMichael":[17],"T.":[18],"Ashby":[19],"John":[21],"H.":[22],"EnemarkCite":[23],"this:":[24],"J.":[25],"Am.":[26],"Chem.":[27],"Soc.":[28],"1986,":[29],"108,":[30],"4,":[31],"730\u2013733Publication":[32],"Date":[33],"(Print):February":[34],"1,":[35],"1986Publication":[36],"History":[37],"Published":[38],"online1":[39],"May":[40],"2002Published":[41],"inissue":[42],"1":[43],"February":[44],"1986https://pubs.acs.org/doi/10.1021/ja00264a026https://doi.org/10.1021/ja00264a026research-articleACS":[45],"PublicationsRequest":[46],"reuse":[47],"permissionsArticle":[48],"Views151Altmetric-Citations42LEARN":[49],"ABOUT":[50],"THESE":[51],"METRICSArticle":[52],"Views":[53],"are":[54,77,90],"COUNTER-compliant":[56],"sum":[57],"full":[59],"text":[60],"article":[61,125],"downloads":[62],"since":[63],"November":[64],"2008":[65],"(both":[66],"PDF":[67],"HTML)":[69],"across":[70],"all":[71],"institutions":[72],"individuals.":[74],"These":[75],"metrics":[76],"regularly":[78],"updated":[79,103],"to":[80,85],"reflect":[81],"usage":[82],"leading":[83],"up":[84],"last":[87],"few":[88],"days.Citations":[89],"other":[94],"articles":[95],"citing":[96],"this":[97],"article,":[98],"calculated":[99],"Crossref":[101,109],"daily.":[104],"Find":[105,155],"more":[106,156],"information":[107,157],"about":[108,143],"citation":[110],"counts.The":[111],"Altmetric":[112,160],"Attention":[113,161],"Score":[114,162],"is":[115,167],"quantitative":[117],"measure":[118],"attention":[121],"that":[122],"research":[124],"has":[126],"received":[127],"online.":[128],"Clicking":[129],"on":[130,158],"donut":[132],"icon":[133],"will":[134],"load":[135],"page":[137],"at":[138],"altmetric.com":[139],"with":[140,175],"additional":[141],"details":[142],"score":[145,166],"social":[148],"media":[149],"presence":[150],"for":[151],"given":[153],"article.":[154],"how":[164],"calculated.":[168],"Share":[169,184],"Add":[170],"toView":[171],"InAdd":[172],"Full":[173],"Text":[174],"ReferenceAdd":[176],"Description":[177],"ExportRISCitationCitation":[178],"abstractCitation":[180],"referencesMore":[182],"Options":[183],"onFacebookTwitterWechatLinked":[185],"InRedditEmail":[186],"Other":[187],"access":[188],"optionsGet":[189],"e-AlertscloseSupporting":[190],"Info":[191],"(1)\u00bbSupporting":[192],"Information":[193,195],"Supporting":[194],"Get":[196],"e-Alerts":[197]},"counts_by_year":[{"year":2025,"cited_by_count":1}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}