{"id":"https://openalex.org/W2087724906","doi":"https://doi.org/10.1002/(sici)1521-3773(19980216)37:3<338::aid-anie338>3.0.co;2-5","title":"Triphenylphosphonioacetylide: A Species Isoelectronic with Isocyanides","display_name":"Triphenylphosphonioacetylide: A Species Isoelectronic with Isocyanides","publication_year":1998,"publication_date":"1998-02-16","ids":{"openalex":"https://openalex.org/W2087724906","doi":"https://doi.org/10.1002/(sici)1521-3773(19980216)37:3<338::aid-anie338>3.0.co;2-5","mag":"2087724906","pmid":"https://pubmed.ncbi.nlm.nih.gov/29711265"},"language":"en","primary_location":{"id":"doi:10.1002/(sici)1521-3773(19980216)37:3<338::aid-anie338>3.0.co;2-5","doi":"https://doi.org/10.1002/(sici)1521-3773(19980216)37:3<338::aid-anie338>3.0.co;2-5","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1521-3773(19980216)37:3<338::aid-anie338>3.0.co;2-5","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5109074550","display_name":"Hans J\u00fcrgen Bestmann","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Hans J\u00fcrgen Bestmann","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864","institution_ids":["https://openalex.org/I181369854"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Wilhelm Frank","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Wilhelm Frank","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864","institution_ids":["https://openalex.org/I181369854"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5015272238","display_name":"Claus Moll","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Claus Moll","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864","institution_ids":["https://openalex.org/I181369854"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5078586870","display_name":"Andreas Pohlschmidt","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Andreas Pohlschmidt","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864","institution_ids":["https://openalex.org/I181369854"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017203543","display_name":"Timothy Clark","orcid":"https://orcid.org/0000-0001-7931-4659","observed_orcids":["https://orcid.org/0000-0001-7931-4659"]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Timothy Clark","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864","institution_ids":["https://openalex.org/I181369854"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5067864075","display_name":"Andreas H. G\u00f6ller","orcid":"https://orcid.org/0000-0003-4343-4063","observed_orcids":["https://orcid.org/0000-0003-4343-4063"]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Andreas G\u00f6ller","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen-N\u00fcrnberg, Henkestrasse 42, D-91054 Erlangen (Germany), Fax: Int. code+(49)\u20099131\u200985-6864","institution_ids":["https://openalex.org/I181369854"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I181369854"],"apc_list":{"value":5510,"currency":"USD","value_usd":5510},"apc_paid":null,"fwci":0.6041,"has_fulltext":false,"cited_by_count":13,"citation_normalized_percentile":{"value":0.63168479,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"37","issue":"3","first_page":"338","last_page":"342"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13239","display_name":"Phosphorus compounds and reactions","score":0.8148999810218811,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13239","display_name":"Phosphorus compounds and reactions","score":0.8148999810218811,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.10029999911785126,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.037700001150369644,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/triphenylphosphine","display_name":"triphenylphosphine","score":0.7950000166893005},{"id":"https://openalex.org/keywords/acetylide-anions","display_name":"acetylide anions","score":0.6050000190734863},{"id":"https://openalex.org/keywords/homo","display_name":"Homo","score":0.5820000171661377},{"id":"https://openalex.org/keywords/molecular-geometry","display_name":"molecular geometry","score":0.5889999866485596},{"id":"https://openalex.org/keywords/charge-distribution","display_name":"charge distribution","score":0.9390000104904175},{"id":"https://openalex.org/keywords/passerini-reaction","display_name":"Passerini reaction","score":0.8569999933242798},{"id":"https://openalex.org/keywords/organophosphorus-synthesis","display_name":"organophosphorus synthesis","score":0.5730000138282776},{"id":"https://openalex.org/keywords/nmr-spectra","display_name":"NMR spectra","score":0.6480000019073486}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6616953611373901},{"id":"https://openalex.org/C163638829","wikidata":"https://www.wikidata.org/wiki/Q900337","display_name":"Lewis acids and bases","level":3,"score":0.5239900946617126},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.5171448588371277},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.5034331679344177},{"id":"https://openalex.org/C188082385","wikidata":"https://www.wikidata.org/wiki/Q73792","display_name":"Charge (physics)","level":2,"score":0.4657137393951416},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.43869900703430176},{"id":"https://openalex.org/C67787023","wikidata":"https://www.wikidata.org/wiki/Q6954755","display_name":"NMR spectra database","level":3,"score":0.4307313859462738},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1373235583305359},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.13475489616394043},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.11683207750320435},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/(sici)1521-3773(19980216)37:3<338::aid-anie338>3.0.co;2-5","doi":"https://doi.org/10.1002/(sici)1521-3773(19980216)37:3<338::aid-anie338>3.0.co;2-5","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1521-3773(19980216)37:3<338::aid-anie338>3.0.co;2-5","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"pmid:29711265","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/29711265","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2088930755","https://openalex.org/W2095437056","https://openalex.org/W2005431465","https://openalex.org/W2129705854","https://openalex.org/W2075778471","https://openalex.org/W2044112649","https://openalex.org/W2157167781","https://openalex.org/W1977541389","https://openalex.org/W2950966625","https://openalex.org/W2501832084"],"abstract_inverted_index":{"Stabilized":[0],"only":[1],"by":[2],"triphenylphosphane,":[3],"the":[4,20,35,47],"title":[5],"compound":[6],"1":[7,16,42,51],"was":[8],"synthesized":[9],"and":[10,24,37],"investigated":[11],"theoretically":[12],"(the":[13],"HOMO":[14],"of":[15,46],"is":[17],"depicted":[18],"on":[19],"right).":[21],"Both":[22],"calculations":[23],"experimental":[25],"NMR":[26],"spectra":[27],"show":[28],"that":[29],"no":[30],"Lewis":[31],"structure":[32],"can":[33],"describe":[34],"geometry":[36],"charge":[38],"distribution":[39],"accurately.":[40],"Compound":[41],"undergoes":[43],"an":[44],"equivalent":[45],"Passerini":[48],"reaction.":[49],"Ph3P+\u2212C\u2261C\u2212:":[50]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2013,"cited_by_count":3}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}