{"id":"https://openalex.org/W2085959629","doi":"https://doi.org/10.1039/b413334j","title":"Characteristics of methoxycarbonylation of aromatic diamine with dimethyl carbonate to dicarbamate using a zinc acetate catalyst","display_name":"Characteristics of methoxycarbonylation of aromatic diamine with dimethyl carbonate to dicarbamate using a zinc acetate catalyst","publication_year":2005,"publication_date":"2005-01-01","ids":{"openalex":"https://openalex.org/W2085959629","doi":"https://doi.org/10.1039/b413334j","mag":"2085959629"},"language":"en","primary_location":{"id":"doi:10.1039/b413334j","doi":"https://doi.org/10.1039/b413334j","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b413334j","pdf_url":null,"source":{"id":"https://openalex.org/S55009144","display_name":"Green Chemistry","issn_l":"1463-9262","issn":["1463-9262","1463-9270"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-3","ki-jl-1","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Green Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5102840333","display_name":"Toshihide Baba","orcid":"https://orcid.org/0000-0002-7565-6317","observed_orcids":["https://orcid.org/0000-0002-7565-6317"]},"institutions":[{"id":"https://openalex.org/I114531698","display_name":"Tokyo Institute of Technology","ror":"https://ror.org/0112mx960","country_code":"JP","type":"education","lineage":["https://openalex.org/I114531698","https://openalex.org/I4400009020"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Toshihide Baba","raw_affiliation_strings":["Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","institution_ids":["https://openalex.org/I114531698"]},{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan","institution_ids":["https://openalex.org/I114531698"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029057106","display_name":"Akane Kobayashi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I114531698","display_name":"Tokyo Institute of Technology","ror":"https://ror.org/0112mx960","country_code":"JP","type":"education","lineage":["https://openalex.org/I114531698","https://openalex.org/I4400009020"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Akane Kobayashi","raw_affiliation_strings":["Department of Chemical Engineering, Tokyo Institute of Technology, Ookayama 2-12-1, Meguro-ku, Tokyo, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering, Tokyo Institute of Technology, Ookayama 2-12-1, Meguro-ku, Tokyo, Japan","institution_ids":["https://openalex.org/I114531698"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110621858","display_name":"Yukio Kawanami","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I114531698","display_name":"Tokyo Institute of Technology","ror":"https://ror.org/0112mx960","country_code":"JP","type":"education","lineage":["https://openalex.org/I114531698","https://openalex.org/I4400009020"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yukio Kawanami","raw_affiliation_strings":["Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","institution_ids":["https://openalex.org/I114531698"]},{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan","institution_ids":["https://openalex.org/I114531698"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032583721","display_name":"Koji Inazu","orcid":"https://orcid.org/0009-0008-4003-2281","observed_orcids":["https://orcid.org/0009-0008-4003-2281"]},"institutions":[{"id":"https://openalex.org/I114531698","display_name":"Tokyo Institute of Technology","ror":"https://ror.org/0112mx960","country_code":"JP","type":"education","lineage":["https://openalex.org/I114531698","https://openalex.org/I4400009020"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Koji Inazu","raw_affiliation_strings":["Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","institution_ids":["https://openalex.org/I114531698"]},{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan","institution_ids":["https://openalex.org/I114531698"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5016062022","display_name":"Akio Ishikawa","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I114531698","display_name":"Tokyo Institute of Technology","ror":"https://ror.org/0112mx960","country_code":"JP","type":"education","lineage":["https://openalex.org/I114531698","https://openalex.org/I4400009020"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Akio Ishikawa","raw_affiliation_strings":["Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","institution_ids":["https://openalex.org/I114531698"]},{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan","institution_ids":["https://openalex.org/I114531698"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043007031","display_name":"Tsuneo Echizen","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I114531698","display_name":"Tokyo Institute of Technology","ror":"https://ror.org/0112mx960","country_code":"JP","type":"education","lineage":["https://openalex.org/I114531698","https://openalex.org/I4400009020"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Tsuneo Echizenn","raw_affiliation_strings":["Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","institution_ids":["https://openalex.org/I114531698"]},{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan","institution_ids":["https://openalex.org/I114531698"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5083301980","display_name":"Kazuhito Murai","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I114531698","display_name":"Tokyo Institute of Technology","ror":"https://ror.org/0112mx960","country_code":"JP","type":"education","lineage":["https://openalex.org/I114531698","https://openalex.org/I4400009020"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Kazuhito Murai","raw_affiliation_strings":["Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan","institution_ids":["https://openalex.org/I114531698"]},{"raw_affiliation_string":"Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta,Midori-ku,Japan","institution_ids":["https://openalex.org/I114531698"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Shinji Aso","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Shinji Aso","raw_affiliation_strings":["Mistui Chemicals Inc., Sodegaura-shi, Nagaura 580-32, Chiba 299-0265, Japan","Mistui Chemicals Inc., Sodegaura-shi,Nagaura 580-32,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Mistui Chemicals Inc., Sodegaura-shi, Nagaura 580-32, Chiba 299-0265, Japan","institution_ids":[]},{"raw_affiliation_string":"Mistui Chemicals Inc., Sodegaura-shi,Nagaura 580-32,Japan","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5016119475","display_name":"Masamitsu Inomata","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Masamitsu Inomata","raw_affiliation_strings":["Mistui Chemicals Inc., Sodegaura-shi, Nagaura 580-32, Chiba 299-0265, Japan","Mistui Chemicals Inc., Sodegaura-shi,Nagaura 580-32,Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Mistui Chemicals Inc., Sodegaura-shi, Nagaura 580-32, Chiba 299-0265, Japan","institution_ids":[]},{"raw_affiliation_string":"Mistui Chemicals Inc., Sodegaura-shi,Nagaura 580-32,Japan","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5102840333"],"corresponding_institution_ids":["https://openalex.org/I114531698"],"apc_list":null,"apc_paid":null,"fwci":3.2007,"has_fulltext":false,"cited_by_count":73,"citation_normalized_percentile":{"value":0.88605287,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"7","issue":"3","first_page":"159","last_page":"159"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.9761000275611877,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.9761000275611877,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.019999999552965164,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13180","display_name":"Chemistry and Chemical Engineering","score":0.0010999999940395355,"subfield":{"id":"https://openalex.org/subfields/2304","display_name":"Environmental Chemistry"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/methoxycarbonylation","display_name":"methoxycarbonylation","score":0.9950000047683716},{"id":"https://openalex.org/keywords/aromatic-diamines","display_name":"aromatic diamines","score":0.9629999995231628},{"id":"https://openalex.org/keywords/dimethyl-carbonate","display_name":"dimethyl carbonate","score":0.9210000038146973},{"id":"https://openalex.org/keywords/zinc-acetate-catalyst","display_name":"zinc acetate catalyst","score":0.8989999890327454},{"id":"https://openalex.org/keywords/dicarbamates","display_name":"dicarbamates","score":0.7639999985694885},{"id":"https://openalex.org/keywords/induction-period","display_name":"induction period","score":0.8460000157356262},{"id":"https://openalex.org/keywords/amine-basicity","display_name":"amine basicity","score":0.8360000252723694},{"id":"https://openalex.org/keywords/aliphatic-amines","display_name":"aliphatic amines","score":0.8539999723434448}],"concepts":[{"id":"https://openalex.org/C2778197717","wikidata":"https://www.wikidata.org/wiki/Q416254","display_name":"Dimethyl carbonate","level":3,"score":0.9460771083831787},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.846190333366394},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.751094400882721},{"id":"https://openalex.org/C2779607525","wikidata":"https://www.wikidata.org/wiki/Q14982","display_name":"Methanol","level":2,"score":0.7312490940093994},{"id":"https://openalex.org/C2778142098","wikidata":"https://www.wikidata.org/wiki/Q15779","display_name":"Toluene","level":2,"score":0.699609637260437},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.6031205654144287},{"id":"https://openalex.org/C535196362","wikidata":"https://www.wikidata.org/wiki/Q758","display_name":"Zinc","level":2,"score":0.522443950176239},{"id":"https://openalex.org/C54175244","wikidata":"https://www.wikidata.org/wiki/Q17125762","display_name":"Induction period","level":3,"score":0.5143023729324341},{"id":"https://openalex.org/C2780659211","wikidata":"https://www.wikidata.org/wiki/Q181699","display_name":"Carbonate","level":2,"score":0.5136796832084656},{"id":"https://openalex.org/C2780871995","wikidata":"https://www.wikidata.org/wiki/Q2500485","display_name":"Diamine","level":2,"score":0.4915400445461273},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.47139909863471985},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.39086222648620605},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.37223753333091736},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.03884309530258179},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1039/b413334j","doi":"https://doi.org/10.1039/b413334j","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b413334j","pdf_url":null,"source":{"id":"https://openalex.org/S55009144","display_name":"Green Chemistry","issn_l":"1463-9262","issn":["1463-9262","1463-9270"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-3","ki-jl-1","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Green Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:irdb.nii.ac.jp:00897:0003989428","doi":null,"is_oa":false,"landing_page_url":"http://t2r2.star.titech.ac.jp/cgi-bin/publicationinfo.cgi?q_publication_content_number=CTT100398846","pdf_url":null,"source":{"id":"https://openalex.org/S7407056385","display_name":"Institutional Repositories DataBase (IRDB)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I184597095","host_organization_name":"National Institute of Informatics","host_organization_lineage":["https://openalex.org/I184597095"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Green Chem.","raw_type":"journal article"},{"id":"pmh:oai:t2r2.star.titech.ac.jp:00209115","doi":null,"is_oa":false,"landing_page_url":"http://t2r2.star.titech.ac.jp/cgi-bin/publicationinfo.cgi?q_publication_content_number=CTT100398846","pdf_url":null,"source":{"id":"https://openalex.org/S4377196385","display_name":"Tokyo Tech Research Repository (Tokyo Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I114531698","host_organization_name":"Tokyo Institute of Technology","host_organization_lineage":["https://openalex.org/I114531698"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":10,"referenced_works":["https://openalex.org/W181191598","https://openalex.org/W1825124165","https://openalex.org/W1964480440","https://openalex.org/W1969144192","https://openalex.org/W1991208765","https://openalex.org/W2024185860","https://openalex.org/W2092338806","https://openalex.org/W2114757626","https://openalex.org/W2127336290","https://openalex.org/W2952985614"],"related_works":["https://openalex.org/W181191598","https://openalex.org/W1554462297","https://openalex.org/W7039855635","https://openalex.org/W2043448331","https://openalex.org/W7145556856","https://openalex.org/W2608139208","https://openalex.org/W2376050572","https://openalex.org/W2350893793","https://openalex.org/W2045669880","https://openalex.org/W1963627778"],"abstract_inverted_index":{"The":[0,74],"methoxycarbonylation":[1,105],"of":[2,23,29,54,76,99,113],"aromatic":[3,55,100],"diamines":[4],"such":[5],"as":[6,14],"2,4-toluene":[7],"diamine":[8],"with":[9,57,72],"dimethyl":[10,58,89],"carbonate":[11,90],"using":[12],"Zn(OAc)2\u00b72H2O":[13],"a":[15,86],"catalyst":[16,71],"is":[17,49,64,78,92],"examined":[18],"to":[19,108],"determine":[20],"the":[21,27,52,70,97,111],"influence":[22],"reaction":[24,53],"variables":[25],"on":[26,81],"yields":[28],"mono-":[30],"and":[31,85,101],"di-carbamates.":[32],"These":[33],"reactions":[34],"yield":[35,39],"dimethyltoluene-2,4-dicarbamate":[36],"in":[37,51,110,116],"98%":[38],"over":[40],"2":[41],"h":[42],"at":[43],"453":[44],"K.":[45],"An":[46],"induction":[47,62],"period":[48,63],"observed":[50],"amines":[56,103],"carbonate,":[59],"but":[60],"this":[61],"almost":[65],"completely":[66],"eliminated":[67],"by":[68],"pretreating":[69],"methanol.":[73],"role":[75],"methanol":[77],"investigated":[79],"based":[80],"infrared":[82],"absorption":[83],"measurements,":[84],"mechanism":[87],"for":[88,104],"activation":[91],"proposed.":[93],"Observed":[94],"differences":[95,109],"between":[96],"reactivities":[98],"aliphatic":[102],"are":[106],"attributed":[107],"basicities":[112],"NH2":[114],"groups":[115],"these":[117],"amines.":[118]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":5},{"year":2018,"cited_by_count":7},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":6},{"year":2014,"cited_by_count":6},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}