{"id":"https://openalex.org/W2076357440","doi":"https://doi.org/10.1063/1.4817418","title":"Probing local structure of pyrochlore lead zinc niobate with synchrotron x-ray absorption spectroscopy technique","display_name":"Probing local structure of pyrochlore lead zinc niobate with synchrotron x-ray absorption spectroscopy technique","publication_year":2013,"publication_date":"2013-08-09","ids":{"openalex":"https://openalex.org/W2076357440","doi":"https://doi.org/10.1063/1.4817418","mag":"2076357440"},"language":"en","primary_location":{"id":"doi:10.1063/1.4817418","doi":"https://doi.org/10.1063/1.4817418","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.4817418","pdf_url":null,"source":{"id":"https://openalex.org/S187991544","display_name":"Journal of Applied Physics","issn_l":"0021-8979","issn":["0021-8979","1089-7550","1520-8850"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Applied Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5022550102","display_name":"Kanokwan Kanchiang","orcid":"https://orcid.org/0009-0002-3653-4760","observed_orcids":["https://orcid.org/0009-0002-3653-4760"]},"institutions":[{"id":"https://openalex.org/I4210110022","display_name":"Thailand Center of Excellence in Physics","ror":"https://ror.org/01td4p294","country_code":"TH","type":"facility","lineage":["https://openalex.org/I4210110022"]},{"id":"https://openalex.org/I48076826","display_name":"Chiang Mai University","ror":"https://ror.org/05m2fqn25","country_code":"TH","type":"education","lineage":["https://openalex.org/I48076826"]}],"countries":["TH"],"is_corresponding":false,"raw_author_name":"Kanokwan Kanchiang","raw_affiliation_strings":["Department of Physics and Materials Science, Faculty of Science, Chiang Mai University 1 , Chiang Mai 50200, Thailand","Thailand Center of Excellence in Physics (ThEP), Commission on Higher Education 2 , Bangkok 10400, Thailand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics and Materials Science, Faculty of Science, Chiang Mai University 1 , Chiang Mai 50200, Thailand","institution_ids":["https://openalex.org/I48076826"]},{"raw_affiliation_string":"Thailand Center of Excellence in Physics (ThEP), Commission on Higher Education 2 , Bangkok 10400, Thailand","institution_ids":["https://openalex.org/I4210110022"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5047230485","display_name":"Sittichain Pramchu","orcid":"https://orcid.org/0000-0001-9302-8229","observed_orcids":["https://orcid.org/0000-0001-9302-8229"]},"institutions":[{"id":"https://openalex.org/I48076826","display_name":"Chiang Mai University","ror":"https://ror.org/05m2fqn25","country_code":"TH","type":"education","lineage":["https://openalex.org/I48076826"]}],"countries":["TH"],"is_corresponding":false,"raw_author_name":"Sittichain Pramchu","raw_affiliation_strings":["Department of Physics and Materials Science, Faculty of Science, Chiang Mai University 1 , Chiang Mai 50200, Thailand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics and Materials Science, Faculty of Science, Chiang Mai University 1 , Chiang Mai 50200, Thailand","institution_ids":["https://openalex.org/I48076826"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5040597209","display_name":"Rattikorn Yimnirun","orcid":"https://orcid.org/0000-0002-0297-7101","observed_orcids":["https://orcid.org/0000-0002-0297-7101"]},"institutions":[{"id":"https://openalex.org/I4210107674","display_name":"National Nanotechnology Center","ror":"https://ror.org/01neh8064","country_code":"TH","type":"facility","lineage":["https://openalex.org/I1332092204","https://openalex.org/I4210107674"]},{"id":"https://openalex.org/I82475049","display_name":"Suranaree University of Technology","ror":"https://ror.org/05sgb8g78","country_code":"TH","type":"education","lineage":["https://openalex.org/I82475049"]}],"countries":["TH"],"is_corresponding":false,"raw_author_name":"Rattikorn Yimnirun","raw_affiliation_strings":["School of Physics, Institute of Science, Suranaree University of Technology, and NANOTEC-SUT Center of Excellence on Advanced Functional Nanomaterials 3 , Nakhon Ratchasima 30000, Thailand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Physics, Institute of Science, Suranaree University of Technology, and NANOTEC-SUT Center of Excellence on Advanced Functional Nanomaterials 3 , Nakhon Ratchasima 30000, Thailand","institution_ids":["https://openalex.org/I4210107674","https://openalex.org/I82475049"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112306357","display_name":"Phakkhananan Pakawanit","orcid":"https://orcid.org/0009-0000-1942-4733","observed_orcids":["https://orcid.org/0009-0000-1942-4733"]},"institutions":[{"id":"https://openalex.org/I48076826","display_name":"Chiang Mai University","ror":"https://ror.org/05m2fqn25","country_code":"TH","type":"education","lineage":["https://openalex.org/I48076826"]}],"countries":["TH"],"is_corresponding":false,"raw_author_name":"Phakkhananan Pakawanit","raw_affiliation_strings":["Department of Physics and Materials Science, Faculty of Science, Chiang Mai University 1 , Chiang Mai 50200, Thailand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics and Materials Science, Faculty of Science, Chiang Mai University 1 , Chiang Mai 50200, Thailand","institution_ids":["https://openalex.org/I48076826"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028465894","display_name":"Supon Ananta","orcid":"https://orcid.org/0000-0002-1478-3590","observed_orcids":["https://orcid.org/0000-0002-1478-3590"]},"institutions":[{"id":"https://openalex.org/I48076826","display_name":"Chiang Mai University","ror":"https://ror.org/05m2fqn25","country_code":"TH","type":"education","lineage":["https://openalex.org/I48076826"]}],"countries":["TH"],"is_corresponding":false,"raw_author_name":"Supon Ananta","raw_affiliation_strings":["Department of Physics and Materials Science, Faculty of Science, Chiang Mai University 1 , Chiang Mai 50200, Thailand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics and Materials Science, Faculty of Science, Chiang Mai University 1 , Chiang Mai 50200, Thailand","institution_ids":["https://openalex.org/I48076826"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5052173705","display_name":"Yongyut Laosiritaworn","orcid":"https://orcid.org/0000-0001-9813-8144","observed_orcids":["https://orcid.org/0000-0001-9813-8144"]},"institutions":[{"id":"https://openalex.org/I4210110022","display_name":"Thailand Center of Excellence in Physics","ror":"https://ror.org/01td4p294","country_code":"TH","type":"facility","lineage":["https://openalex.org/I4210110022"]},{"id":"https://openalex.org/I48076826","display_name":"Chiang Mai University","ror":"https://ror.org/05m2fqn25","country_code":"TH","type":"education","lineage":["https://openalex.org/I48076826"]}],"countries":["TH"],"is_corresponding":false,"raw_author_name":"Yongyut Laosiritaworn","raw_affiliation_strings":["Department of Physics and Materials Science, Faculty of Science, Chiang Mai University 1 , Chiang Mai 50200, Thailand","Thailand Center of Excellence in Physics (ThEP), Commission on Higher Education 2 , Bangkok 10400, Thailand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics and Materials Science, Faculty of Science, Chiang Mai University 1 , Chiang Mai 50200, Thailand","institution_ids":["https://openalex.org/I48076826"]},{"raw_affiliation_string":"Thailand Center of Excellence in Physics (ThEP), Commission on Higher Education 2 , Bangkok 10400, Thailand","institution_ids":["https://openalex.org/I4210110022"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":0.3954,"has_fulltext":false,"cited_by_count":7,"citation_normalized_percentile":{"value":0.52721051,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":"114","issue":"6","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10107","display_name":"Ferroelectric and Piezoelectric Materials","score":0.8574000000953674,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10107","display_name":"Ferroelectric and Piezoelectric Materials","score":0.8574000000953674,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11733","display_name":"X-ray Spectroscopy and Fluorescence Analysis","score":0.04490000009536743,"subfield":{"id":"https://openalex.org/subfields/3108","display_name":"Radiation"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11878","display_name":"Solid-state spectroscopy and crystallography","score":0.008700000122189522,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/lead-zinc-niobate","display_name":"lead zinc niobate","score":0.9539999961853027},{"id":"https://openalex.org/keywords/pyrochlore-phase","display_name":"pyrochlore phase","score":0.9629999995231628},{"id":"https://openalex.org/keywords/local-structure","display_name":"local structure","score":0.8299999833106995},{"id":"https://openalex.org/keywords/zinc-substitution","display_name":"zinc substitution","score":0.5740000009536743},{"id":"https://openalex.org/keywords/formation-energy","display_name":"formation energy","score":0.6299999952316284},{"id":"https://openalex.org/keywords/steric-hindrance","display_name":"steric hindrance","score":0.7850000262260437},{"id":"https://openalex.org/keywords/xanes-simulation","display_name":"XANES simulation","score":0.6389999985694885},{"id":"https://openalex.org/keywords/exafs","display_name":"EXAFS","score":0.996999979019165}],"concepts":[{"id":"https://openalex.org/C2779303976","wikidata":"https://www.wikidata.org/wiki/Q417202","display_name":"Pyrochlore","level":3,"score":0.8468705415725708},{"id":"https://openalex.org/C110715899","wikidata":"https://www.wikidata.org/wiki/Q3570341","display_name":"XANES","level":3,"score":0.8373372554779053},{"id":"https://openalex.org/C107861141","wikidata":"https://www.wikidata.org/wiki/Q908783","display_name":"Extended X-ray absorption fine structure","level":3,"score":0.8319715261459351},{"id":"https://openalex.org/C62284982","wikidata":"https://www.wikidata.org/wiki/Q903103","display_name":"X-ray absorption spectroscopy","level":3,"score":0.7395734190940857},{"id":"https://openalex.org/C46000676","wikidata":"https://www.wikidata.org/wiki/Q804644","display_name":"Lone pair","level":3,"score":0.6428028345108032},{"id":"https://openalex.org/C155011858","wikidata":"https://www.wikidata.org/wiki/Q3036449","display_name":"Perovskite (structure)","level":2,"score":0.5714403390884399},{"id":"https://openalex.org/C155860418","wikidata":"https://www.wikidata.org/wiki/Q863695","display_name":"Bond length","level":3,"score":0.523262619972229},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4969330132007599},{"id":"https://openalex.org/C119824511","wikidata":"https://www.wikidata.org/wiki/Q13553575","display_name":"Absorption spectroscopy","level":2,"score":0.4926948845386505},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.45916658639907837},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.4248640239238739},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.41227295994758606},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.34147655963897705},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.2874850630760193},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.07812908291816711},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.06149435043334961},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1063/1.4817418","doi":"https://doi.org/10.1063/1.4817418","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.4817418","pdf_url":null,"source":{"id":"https://openalex.org/S187991544","display_name":"Journal of Applied Physics","issn_l":"0021-8979","issn":["0021-8979","1089-7550","1520-8850"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Applied Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":35,"referenced_works":["https://openalex.org/W1416920827","https://openalex.org/W1567056218","https://openalex.org/W1969111064","https://openalex.org/W1969926317","https://openalex.org/W1970669068","https://openalex.org/W1970939899","https://openalex.org/W1982368408","https://openalex.org/W1986139795","https://openalex.org/W1991516230","https://openalex.org/W1996330429","https://openalex.org/W2010472073","https://openalex.org/W2014115207","https://openalex.org/W2016960382","https://openalex.org/W2018222553","https://openalex.org/W2029176691","https://openalex.org/W2035223648","https://openalex.org/W2041784314","https://openalex.org/W2045562184","https://openalex.org/W2051805648","https://openalex.org/W2053822398","https://openalex.org/W2060340975","https://openalex.org/W2063014940","https://openalex.org/W2070227796","https://openalex.org/W2074762273","https://openalex.org/W2082867420","https://openalex.org/W2092991141","https://openalex.org/W2096741432","https://openalex.org/W2117373859","https://openalex.org/W2138003353","https://openalex.org/W2156605351","https://openalex.org/W2163293749","https://openalex.org/W2165768408","https://openalex.org/W2167590372","https://openalex.org/W2230728100","https://openalex.org/W4252588424"],"related_works":["https://openalex.org/W2247149764","https://openalex.org/W2736849838","https://openalex.org/W2510562721","https://openalex.org/W1416920827","https://openalex.org/W1869828554","https://openalex.org/W2285685453","https://openalex.org/W2608174049","https://openalex.org/W2324512619","https://openalex.org/W3036310613","https://openalex.org/W1530640396"],"abstract_inverted_index":{"Local":[0],"structure":[1,30,62,212],"of":[2,115,145,154,164,185,202,205,217,227],"lead":[3,206],"zinc":[4,207],"niobate":[5,208],"(PZN)":[6],"ceramic,":[7],"synthesized":[8],"via":[9],"B-site":[10],"oxide":[11],"precursor":[12],"route":[13],"in":[14,47,90,105,209,222],"atmospheric":[15],"pressure,":[16],"was":[17,33,65,94],"investigated":[18],"using":[19,131],"synchrotron":[20],"x-ray":[21,27,59],"absorption":[22,28,60],"spectroscopy":[23],"(XAS)":[24],"technique.":[25],"The":[26,37,137],"near-edge":[29],"(XANES)":[31],"simulation":[32,39],"first":[34],"carried":[35],"out.":[36],"XANES":[38],"results":[40,139],"indicate":[41],"that":[42,141,153],"the":[43,57,69,80,83,91,100,106,111,119,123,132,142,146,155,162,170,182,190,203,210,215],"PZN":[44],"ceramic":[45],"is":[46,149,159],"pyrochlore":[48,92,156,229],"phase":[49,93,148,172],"having":[50],"Zn2+":[51,74,87,175,198],"substituted":[52],"on":[53],"Nb5+":[54],"site.":[55],"Afterwards,":[56],"extended":[58],"fine":[61],"(EXAFS)":[63],"analysis":[64,221],"performed":[66],"to":[67,96,176],"extract":[68],"bond":[70,84,103],"length":[71,85,104],"information":[72,114],"between":[73,86,193],"and":[75,88,125,189,197,213,219],"its":[76],"neighboring":[77,117],"atoms.":[78],"From":[79],"EXAFS":[81],"fitting,":[82],"Pb2+":[89,166,177,186,194],"found":[95],"be":[97],"longer":[98],"than":[99,152],"previously":[101],"reported":[102],"perovskite":[107,147,171,211],"phase.":[108],"Further,":[109],"with":[110],"radial":[112],"distribution":[113],"Zn2+'s":[116],"atoms,":[118],"formation":[120,143],"energies":[121],"along":[122],"precursor-to-pyrochlore":[124],"precursor-to-perovskite":[126],"reaction":[127],"paths":[128],"were":[129],"calculated":[130,138],"density":[133],"functional":[134],"theory":[135],"(DFT).":[136],"show":[140],"energy":[144],"noticeably":[150],"higher":[151],"phase,":[157],"which":[158],"influenced":[160],"by":[161],"presence":[163],"energetic":[165],"lone":[167,187,195],"pair,":[168],"as":[169],"has":[173],"shorter":[174],"bonding.":[178],"This":[179],"therefore":[180],"suggests":[181],"steric":[183],"hindrance":[184],"pair":[188,196],"mutual":[191],"interactions":[192],"are":[199],"main":[200],"causes":[201],"instability":[204],"confirm":[214],"efficacy":[216],"XAS":[218],"DFT":[220],"revealing":[223],"local":[224],"structural":[225],"details":[226],"complex":[228],"materials.":[230]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2020,"cited_by_count":2},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":1}],"updated_date":"2026-05-21T06:26:12.895304","created_date":"2016-06-24T00:00:00"}