{"id":"https://openalex.org/W2076349732","doi":"https://doi.org/10.1016/j.tetlet.2015.03.009","title":"Biosynthesis of the C15-acetogenin laurepoxide may involve bromine-induced skeletal rearrangement of a \u03944-oxocene precursor","display_name":"Biosynthesis of the C15-acetogenin laurepoxide may involve bromine-induced skeletal rearrangement of a \u03944-oxocene precursor","publication_year":2015,"publication_date":"2015-03-09","ids":{"openalex":"https://openalex.org/W2076349732","doi":"https://doi.org/10.1016/j.tetlet.2015.03.009","mag":"2076349732","pmid":"https://pubmed.ncbi.nlm.nih.gov/26146420","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/4489422"},"language":"en","primary_location":{"id":"doi:10.1016/j.tetlet.2015.03.009","doi":"https://doi.org/10.1016/j.tetlet.2015.03.009","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.tetlet.2015.03.009","pdf_url":null,"source":{"id":"https://openalex.org/S133942674","display_name":"Tetrahedron Letters","issn_l":"0040-4039","issn":["0040-4039","1873-3581"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Tetrahedron Letters","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://doi.org/10.1016/j.tetlet.2015.03.009","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5067034347","display_name":"Michael T. Taylor","orcid":"https://orcid.org/0000-0002-7655-7222","observed_orcids":["https://orcid.org/0000-0002-7655-7222"]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Michael T. Taylor","raw_affiliation_strings":["Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5034235550","display_name":"Joseph M. Fox","orcid":"https://orcid.org/0000-0002-8258-1640","observed_orcids":["https://orcid.org/0000-0002-8258-1640"]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Joseph M. Fox","raw_affiliation_strings":["Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5034235550"],"corresponding_institution_ids":["https://openalex.org/I86501945"],"apc_list":{"value":3610,"currency":"USD","value_usd":3610},"apc_paid":null,"fwci":0.5695,"has_fulltext":false,"cited_by_count":10,"citation_normalized_percentile":{"value":0.61538955,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"56","issue":"23","first_page":"3560","last_page":"3563"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.257099986076355,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.257099986076355,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11547","display_name":"Sesquiterpenes and Asteraceae Studies","score":0.1818999946117401,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12530","display_name":"Bioactive Natural Diterpenoids Research","score":0.12700000405311584,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/acetogenins","display_name":"acetogenins","score":0.9750000238418579},{"id":"https://openalex.org/keywords/biosynthesis","display_name":"biosynthesis","score":0.6700000166893005},{"id":"https://openalex.org/keywords/skeletal-rearrangement","display_name":"skeletal rearrangement","score":0.7120000123977661},{"id":"https://openalex.org/keywords/total-synthesis","display_name":"total synthesis","score":0.38100001215934753}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9692214727401733},{"id":"https://openalex.org/C2780988704","wikidata":"https://www.wikidata.org/wiki/Q3604300","display_name":"Acetogenin","level":3,"score":0.9617279767990112},{"id":"https://openalex.org/C517835270","wikidata":"https://www.wikidata.org/wiki/Q879","display_name":"Bromine","level":2,"score":0.7721099257469177},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.5722314715385437},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.200543612241745},{"id":"https://openalex.org/C2780303139","wikidata":"https://www.wikidata.org/wiki/Q220025","display_name":"Annonaceae","level":2,"score":0.05389466881752014},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C556039675","wikidata":"https://www.wikidata.org/wiki/Q771035","display_name":"Traditional medicine","level":1,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1016/j.tetlet.2015.03.009","doi":"https://doi.org/10.1016/j.tetlet.2015.03.009","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.tetlet.2015.03.009","pdf_url":null,"source":{"id":"https://openalex.org/S133942674","display_name":"Tetrahedron Letters","issn_l":"0040-4039","issn":["0040-4039","1873-3581"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Tetrahedron Letters","raw_type":"journal-article"},{"id":"pmid:26146420","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/26146420","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Tetrahedron letters","raw_type":"Journal Article"},{"id":"pmh:oai:europepmc.org:3858708","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/4489422","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"Text"},{"id":"pmh:oai:pubmedcentral.nih.gov:4489422","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/4489422","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Tetrahedron Lett","raw_type":"Text"}],"best_oa_location":{"id":"doi:10.1016/j.tetlet.2015.03.009","doi":"https://doi.org/10.1016/j.tetlet.2015.03.009","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.tetlet.2015.03.009","pdf_url":null,"source":{"id":"https://openalex.org/S133942674","display_name":"Tetrahedron Letters","issn_l":"0040-4039","issn":["0040-4039","1873-3581"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Tetrahedron Letters","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1611799820","display_name":"Chiral Crown Catalysts for Selective Rh-Catalyzed Reactions","funder_award_id":"1300329","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G3703352996","display_name":"3D Structure of Membrane Proteins","funder_award_id":"R01GM068650","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G4188327313","display_name":"CRIF:MU  Cryprobe Upgrade of a NMR Spectrometer","funder_award_id":"0840401","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G5905849278","display_name":"Chemistry-Biology Interface (CBI) NIH T32 Training Grant","funder_award_id":"T32GM008550","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G6787174793","display_name":"SELECTIVE METHODS FOR SYNTHESIS WITH STRAINED MOLECULES AND CARBENOIDS","funder_award_id":"R01GM068640","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G7558382895","display_name":"High Performance Digital NMR Spectrometer","funder_award_id":"S10RR026962","funder_id":"https://openalex.org/F4320337375","funder_display_name":"National Center for Research Resources"},{"id":"https://openalex.org/G8612150275","display_name":"Molecular Design of Advanced Biomaterials","funder_award_id":"P30GM110758","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G886931444","display_name":"MRI: Acquisition of a High Resolution Mass Spectrometer for Small Molecule Analysis","funder_award_id":"1229234","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G93081233","display_name":"Q-Exactive Orbitrap LC-MC/MS System","funder_award_id":"1s10od016267-01","funder_id":"https://openalex.org/F4320332161","funder_display_name":"National Institutes of Health"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320332161","display_name":"National Institutes of Health","ror":"https://ror.org/01cwqze88"},{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"},{"id":"https://openalex.org/F4320337375","display_name":"National Center for Research Resources","ror":"https://ror.org/04pw6fb54"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":27,"referenced_works":["https://openalex.org/W98725330","https://openalex.org/W1978164707","https://openalex.org/W1996057323","https://openalex.org/W1996922791","https://openalex.org/W2004594176","https://openalex.org/W2008913163","https://openalex.org/W2009993008","https://openalex.org/W2018071097","https://openalex.org/W2020006967","https://openalex.org/W2025009653","https://openalex.org/W2071311579","https://openalex.org/W2072685955","https://openalex.org/W2088558628","https://openalex.org/W2091091242","https://openalex.org/W2102190823","https://openalex.org/W2111139603","https://openalex.org/W2129359245","https://openalex.org/W2157264889","https://openalex.org/W2168680551","https://openalex.org/W2319857799","https://openalex.org/W2320440392","https://openalex.org/W2320906368","https://openalex.org/W2334697756","https://openalex.org/W2949085851","https://openalex.org/W2949085867","https://openalex.org/W2949845637","https://openalex.org/W4211162522"],"related_works":["https://openalex.org/W2032180269","https://openalex.org/W2048848302","https://openalex.org/W2320906368","https://openalex.org/W2320440392","https://openalex.org/W2170620295","https://openalex.org/W2060196808","https://openalex.org/W2294655317","https://openalex.org/W2079933832","https://openalex.org/W2068161856","https://openalex.org/W2090491197"],"abstract_inverted_index":null,"counts_by_year":[{"year":2023,"cited_by_count":1},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":3},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":1}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}