{"id":"https://openalex.org/W2075387635","doi":"https://doi.org/10.1021/om00138a035","title":"Kinetics and mechanism of carbon dioxide insertion into a metal-hydride bond. A large solvent effect and an inverse kinetic isotope effect","display_name":"Kinetics and mechanism of carbon dioxide insertion into a metal-hydride bond. A large solvent effect and an inverse kinetic isotope effect","publication_year":1986,"publication_date":"1986-07-01","ids":{"openalex":"https://openalex.org/W2075387635","doi":"https://doi.org/10.1021/om00138a035","mag":"2075387635"},"language":"en","primary_location":{"id":"doi:10.1021/om00138a035","doi":"https://doi.org/10.1021/om00138a035","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om00138a035","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5114973242","display_name":"B. Patrick Sullivan","orcid":"https://orcid.org/0000-0003-2838-9137","observed_orcids":["https://orcid.org/0000-0003-2838-9137"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"B. Patrick Sullivan","raw_affiliation_strings":["University of North Carolina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of North Carolina","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5089516413","display_name":"Thomas J. Meyer","orcid":"https://orcid.org/0000-0002-7006-2608","observed_orcids":["https://orcid.org/0000-0002-7006-2608"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Thomas J. Meyer","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.7813,"has_fulltext":false,"cited_by_count":150,"citation_normalized_percentile":{"value":0.89737183,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":94,"max":99},"biblio":{"volume":"5","issue":"7","first_page":"1500","last_page":"1502"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9125999808311462,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9125999808311462,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.04540000110864639,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.010900000110268593,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/carbon-dioxide-insertion","display_name":"carbon dioxide insertion","score":0.9810000061988831},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.8489999771118164},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.9959999918937683},{"id":"https://openalex.org/keywords/solvent-effects","display_name":"solvent effects","score":0.9269999861717224},{"id":"https://openalex.org/keywords/inverse-kinetic-isotope-effect","display_name":"inverse kinetic isotope effect","score":0.9629999995231628},{"id":"https://openalex.org/keywords/hydride-ligands","display_name":"hydride ligands","score":0.5059999823570251},{"id":"https://openalex.org/keywords/organometallic-chemistry","display_name":"organometallic chemistry","score":0.4860000014305115}],"concepts":[{"id":"https://openalex.org/C2777961443","wikidata":"https://www.wikidata.org/wiki/Q106520","display_name":"Hydride","level":3,"score":0.6434916257858276},{"id":"https://openalex.org/C207467116","wikidata":"https://www.wikidata.org/wiki/Q4385666","display_name":"Inverse","level":2,"score":0.5938448309898376},{"id":"https://openalex.org/C69928629","wikidata":"https://www.wikidata.org/wiki/Q1386472","display_name":"Kinetic isotope effect","level":3,"score":0.5933030247688293},{"id":"https://openalex.org/C2778805511","wikidata":"https://www.wikidata.org/wiki/Q1713","display_name":"Citation","level":2,"score":0.5405724048614502},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.47602584958076477},{"id":"https://openalex.org/C164304813","wikidata":"https://www.wikidata.org/wiki/Q25276","display_name":"Isotope","level":2,"score":0.4184996485710144},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.41631779074668884},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.39490535855293274},{"id":"https://openalex.org/C23123220","wikidata":"https://www.wikidata.org/wiki/Q816826","display_name":"Information retrieval","level":1,"score":0.3651743233203888},{"id":"https://openalex.org/C161191863","wikidata":"https://www.wikidata.org/wiki/Q199655","display_name":"Library science","level":1,"score":0.27061671018600464},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.24624541401863098},{"id":"https://openalex.org/C138885662","wikidata":"https://www.wikidata.org/wiki/Q5891","display_name":"Philosophy","level":0,"score":0.1688348650932312},{"id":"https://openalex.org/C185544564","wikidata":"https://www.wikidata.org/wiki/Q81197","display_name":"Nuclear physics","level":1,"score":0.1618501842021942},{"id":"https://openalex.org/C58364064","wikidata":"https://www.wikidata.org/wiki/Q102296","display_name":"Deuterium","level":2,"score":0.11685866117477417},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.09134486317634583},{"id":"https://openalex.org/C41895202","wikidata":"https://www.wikidata.org/wiki/Q8162","display_name":"Linguistics","level":1,"score":0.09013035893440247}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/om00138a035","doi":"https://doi.org/10.1021/om00138a035","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om00138a035","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2876641039","https://openalex.org/W4399846068","https://openalex.org/W4402507320","https://openalex.org/W2950295031","https://openalex.org/W1576641219","https://openalex.org/W4210855118","https://openalex.org/W1984840186","https://openalex.org/W2002703485","https://openalex.org/W2027182901","https://openalex.org/W2061129477"],"abstract_inverted_index":{"ADVERTISEMENT":[0],"RETURN":[1],"TO":[2],"ISSUEPREVArticleNEXTKinetics":[3],"and":[4,18,26,71,76,105,149,166,182,184],"mechanism":[5],"of":[6,61,96,122],"carbon":[7],"dioxide":[8],"insertion":[9],"into":[10],"a":[11,119,126,139],"metal-hydride":[12],"bond.":[13],"A":[14],"large":[15],"solvent":[16],"effect":[17],"an":[19],"inverse":[20],"kinetic":[21],"isotope":[22],"effectB.":[23],"Patrick":[24],"Sullivan":[25],"Thomas":[27],"J.":[28],"MeyerCite":[29],"this:":[30],"Organometallics":[31],"1986,":[32],"5,":[33],"7,":[34],"1500\u20131502Publication":[35],"Date":[36],"(Print):July":[37],"1,":[38],"1986Publication":[39],"History":[40],"Published":[41],"online1":[42],"May":[43],"2002Published":[44],"inissue":[45],"1":[46],"July":[47],"1986https://pubs.acs.org/doi/10.1021/om00138a035https://doi.org/10.1021/om00138a035research-articleACS":[48],"PublicationsRequest":[49],"reuse":[50],"permissionsArticle":[51],"Views1602Altmetric-Citations137LEARN":[52],"ABOUT":[53],"THESE":[54],"METRICSArticle":[55],"Views":[56],"are":[57,80,93],"the":[58,89,94,123,134,147,150,155,162,168],"COUNTER-compliant":[59],"sum":[60],"full":[62],"text":[63],"article":[64,128],"downloads":[65],"since":[66],"November":[67],"2008":[68],"(both":[69],"PDF":[70],"HTML)":[72],"across":[73],"all":[74],"institutions":[75],"individuals.":[77],"These":[78],"metrics":[79],"regularly":[81],"updated":[82,106],"to":[83,88],"reflect":[84],"usage":[85],"leading":[86],"up":[87],"last":[90],"few":[91],"days.Citations":[92],"number":[95],"other":[97],"articles":[98],"citing":[99],"this":[100],"article,":[101],"calculated":[102],"by":[103],"Crossref":[104,112],"daily.":[107],"Find":[108,158],"more":[109,159],"information":[110,160],"about":[111,146],"citation":[113],"counts.The":[114],"Altmetric":[115,163],"Attention":[116,164],"Score":[117,165],"is":[118,170],"quantitative":[120],"measure":[121],"attention":[124],"that":[125],"research":[127],"has":[129],"received":[130],"online.":[131],"Clicking":[132],"on":[133,161],"donut":[135],"icon":[136],"will":[137],"load":[138],"page":[140],"at":[141],"altmetric.com":[142],"with":[143,178],"additional":[144],"details":[145],"score":[148,169],"social":[151],"media":[152],"presence":[153],"for":[154],"given":[156],"article.":[157],"how":[167],"calculated.":[171],"Share":[172,187],"Add":[173],"toView":[174],"InAdd":[175],"Full":[176],"Text":[177],"ReferenceAdd":[179],"Description":[180],"ExportRISCitationCitation":[181],"abstractCitation":[183],"referencesMore":[185],"Options":[186],"onFacebookTwitterWechatLinked":[188],"InRedditEmail":[189],"Other":[190],"access":[191],"optionsGet":[192],"e-Alertsclose":[193],"Get":[194],"e-Alerts":[195]},"counts_by_year":[{"year":2025,"cited_by_count":5},{"year":2024,"cited_by_count":6},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":5},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":6},{"year":2018,"cited_by_count":8},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":6},{"year":2015,"cited_by_count":5},{"year":2014,"cited_by_count":4},{"year":2013,"cited_by_count":10},{"year":2012,"cited_by_count":4}],"updated_date":"2026-10-08T09:06:37.294493","created_date":"2016-06-24T00:00:00"}
