{"id":"https://openalex.org/W2073409489","doi":"https://doi.org/10.1002/1522-2675(20010516)84:5<1157::aid-hlca1157>3.0.co;2-7","title":"Acetylene-Hydration Kinetics on Cadmium-Exchanged Clinoptilolite Catalyst, Preliminary Communication","display_name":"Acetylene-Hydration Kinetics on Cadmium-Exchanged Clinoptilolite Catalyst, Preliminary Communication","publication_year":2001,"publication_date":"2001-05-16","ids":{"openalex":"https://openalex.org/W2073409489","doi":"https://doi.org/10.1002/1522-2675(20010516)84:5<1157::aid-hlca1157>3.0.co;2-7","mag":"2073409489"},"language":"en","primary_location":{"id":"doi:10.1002/1522-2675(20010516)84:5<1157::aid-hlca1157>3.0.co;2-7","doi":"https://doi.org/10.1002/1522-2675(20010516)84:5<1157::aid-hlca1157>3.0.co;2-7","is_oa":false,"landing_page_url":"https://doi.org/10.1002/1522-2675(20010516)84:5<1157::aid-hlca1157>3.0.co;2-7","pdf_url":null,"source":{"id":"https://openalex.org/S181847678","display_name":"Helvetica Chimica Acta","issn_l":"0018-019X","issn":["0018-019X","1522-2675"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Helvetica Chimica Acta","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5001485205","display_name":"D. Kall\u00f3","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I7597260","display_name":"Hungarian Academy of Sciences","ror":"https://ror.org/02ks8qq67","country_code":"HU","type":"government","lineage":["https://openalex.org/I7597260"]},{"id":"https://openalex.org/I80251312","display_name":"HUN-REN Research Centre for Natural Sciences","ror":"https://ror.org/03zwxja46","country_code":"HU","type":"facility","lineage":["https://openalex.org/I4387152226","https://openalex.org/I80251312"]}],"countries":["HU"],"is_corresponding":true,"raw_author_name":"D\u00e9nes Kall\u00f3","raw_affiliation_strings":["Chemical Research Center, Institute of Chemistry, Hung. Acad. Sci., P.O. Box 17, H-1525 Budapest (phone: (36-1)325-7900/122; fax: (36-1)325-7554)","Chemical Research Center, Institute of Chemistry, Hung. Acad. Sci., P.O. Box 17, H-1525 Budapest (phone: (36-1)325-7900/122","fax: (36-1)325-7554)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemical Research Center, Institute of Chemistry, Hung. Acad. Sci., P.O. Box 17, H-1525 Budapest (phone: (36-1)325-7900/122; fax: (36-1)325-7554)","institution_ids":["https://openalex.org/I7597260","https://openalex.org/I80251312"]},{"raw_affiliation_string":"Chemical Research Center, Institute of Chemistry, Hung. Acad. Sci., P.O. Box 17, H-1525 Budapest (phone: (36-1)325-7900/122","institution_ids":["https://openalex.org/I7597260","https://openalex.org/I80251312"]},{"raw_affiliation_string":"fax: (36-1)325-7554)","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111677173","display_name":"Gy\u00f6rgy Onyesty\u00e1k","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I7597260","display_name":"Hungarian Academy of Sciences","ror":"https://ror.org/02ks8qq67","country_code":"HU","type":"government","lineage":["https://openalex.org/I7597260"]},{"id":"https://openalex.org/I80251312","display_name":"HUN-REN Research Centre for Natural Sciences","ror":"https://ror.org/03zwxja46","country_code":"HU","type":"facility","lineage":["https://openalex.org/I4387152226","https://openalex.org/I80251312"]}],"countries":["HU"],"is_corresponding":false,"raw_author_name":"Gy\u00f6rgy Onyesty\u00e1k","raw_affiliation_strings":["Chemical Research Center, Institute of Chemistry, Hung. Acad. Sci., P.O. Box 17, H-1525 Budapest (phone: (36-1)325-7900/122; fax: (36-1)325-7554)","Chemical Research Center, Institute of Chemistry, Hung. Acad. Sci., P.O. Box 17, H-1525 Budapest (phone: (36-1)325-7900/122","fax: (36-1)325-7554)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemical Research Center, Institute of Chemistry, Hung. Acad. Sci., P.O. Box 17, H-1525 Budapest (phone: (36-1)325-7900/122; fax: (36-1)325-7554)","institution_ids":["https://openalex.org/I7597260","https://openalex.org/I80251312"]},{"raw_affiliation_string":"Chemical Research Center, Institute of Chemistry, Hung. Acad. Sci., P.O. Box 17, H-1525 Budapest (phone: (36-1)325-7900/122","institution_ids":["https://openalex.org/I7597260","https://openalex.org/I80251312"]},{"raw_affiliation_string":"fax: (36-1)325-7554)","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5001485205"],"corresponding_institution_ids":["https://openalex.org/I7597260","https://openalex.org/I80251312"],"apc_list":{"value":4030,"currency":"USD","value_usd":4030},"apc_paid":null,"fwci":0.9929,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.70997375,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":97},"biblio":{"volume":"84","issue":"5","first_page":"1157","last_page":"1162"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10353","display_name":"Zeolite Catalysis and Synthesis","score":0.9589999914169312,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10353","display_name":"Zeolite Catalysis and Synthesis","score":0.9589999914169312,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.01940000057220459,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11825","display_name":"Catalysis and Oxidation Reactions","score":0.010400000028312206,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/acetylene-hydration","display_name":"acetylene hydration","score":0.9879999756813049},{"id":"https://openalex.org/keywords/zeolite-catalysts","display_name":"zeolite catalysts","score":0.8450000286102295},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.7369999885559082},{"id":"https://openalex.org/keywords/langmuir-hinshelwood-kinetics","display_name":"Langmuir-Hinshelwood kinetics","score":0.9769999980926514},{"id":"https://openalex.org/keywords/acetaldehyde","display_name":"acetaldehyde","score":0.8040000200271606},{"id":"https://openalex.org/keywords/acetylene-adsorption","display_name":"acetylene adsorption","score":0.7049999833106995},{"id":"https://openalex.org/keywords/water-adsorption","display_name":"water adsorption","score":0.7799999713897705},{"id":"https://openalex.org/keywords/rate-limiting-step","display_name":"rate-determining step","score":0.7559999823570251},{"id":"https://openalex.org/keywords/catalyst-deactivation","display_name":"catalyst deactivation","score":0.6660000085830688}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9595186114311218},{"id":"https://openalex.org/C2777517455","wikidata":"https://www.wikidata.org/wiki/Q133145","display_name":"Acetylene","level":2,"score":0.912375807762146},{"id":"https://openalex.org/C2778020220","wikidata":"https://www.wikidata.org/wiki/Q277046","display_name":"Clinoptilolite","level":4,"score":0.801120400428772},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7232838869094849},{"id":"https://openalex.org/C2777595113","wikidata":"https://www.wikidata.org/wiki/Q61457","display_name":"Acetaldehyde","level":3,"score":0.6946970224380493},{"id":"https://openalex.org/C162711632","wikidata":"https://www.wikidata.org/wiki/Q905514","display_name":"Desorption","level":3,"score":0.6005734205245972},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.5883113145828247},{"id":"https://openalex.org/C8171440","wikidata":"https://www.wikidata.org/wiki/Q903414","display_name":"Steady state (chemistry)","level":2,"score":0.559705376625061},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.5591739416122437},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4527015686035156},{"id":"https://openalex.org/C111163200","wikidata":"https://www.wikidata.org/wiki/Q904041","display_name":"Rate equation","level":3,"score":0.4426647424697876},{"id":"https://openalex.org/C85800342","wikidata":"https://www.wikidata.org/wiki/Q7300284","display_name":"Reactions on surfaces","level":3,"score":0.4424426555633545},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3343421518802643},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2511812448501587},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2240276038646698},{"id":"https://openalex.org/C2778077586","wikidata":"https://www.wikidata.org/wiki/Q181332","display_name":"Zeolite","level":3,"score":0.13143491744995117},{"id":"https://openalex.org/C2780161600","wikidata":"https://www.wikidata.org/wiki/Q153","display_name":"Ethanol","level":2,"score":0.06089895963668823},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/1522-2675(20010516)84:5<1157::aid-hlca1157>3.0.co;2-7","doi":"https://doi.org/10.1002/1522-2675(20010516)84:5<1157::aid-hlca1157>3.0.co;2-7","is_oa":false,"landing_page_url":"https://doi.org/10.1002/1522-2675(20010516)84:5<1157::aid-hlca1157>3.0.co;2-7","pdf_url":null,"source":{"id":"https://openalex.org/S181847678","display_name":"Helvetica Chimica Acta","issn_l":"0018-019X","issn":["0018-019X","1522-2675"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Helvetica Chimica Acta","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2052888030","https://openalex.org/W2027569300","https://openalex.org/W2152053981","https://openalex.org/W2090055535","https://openalex.org/W2046599250","https://openalex.org/W420313317","https://openalex.org/W2026108987","https://openalex.org/W2952969320","https://openalex.org/W3081599766","https://openalex.org/W4297910389"],"abstract_inverted_index":{"Hydration":[0],"of":[1,17,30,82],"acetylene":[2,56],"under":[3,23],"steady-state":[4,24],"conditions":[5,25],"around":[6],"450":[7],"K":[8],"proceeds":[9],"on":[10,61],"Cd-clinoptilolite":[11],"without":[12],"catalyst":[13],"deactivation":[14],"and":[15,33,57,64],"formation":[16],"by-products.":[18],"Reaction":[19],"rates":[20],"were":[21,46],"determined":[22],"at":[26],"different":[27,43],"partial":[28],"pressures":[29],"acetylene,":[31],"water,":[32],"acetaldehyde.":[34,85],"In":[35],"relation":[36],"with":[37],"the":[38,65,69,73,83],"results,":[39],"rate":[40],"equations":[41],"for":[42],"kinetic":[44],"models":[45],"evaluated.":[47],"Langmuir-Hinshelwood":[48],"kinetics":[49],"was":[50],"established.":[51],"According":[52],"to":[53],"this":[54],"model,":[55],"water":[58],"must":[59],"adsorb":[60],"similar":[62],"sites,":[63],"surface":[66],"reaction":[67],"between":[68],"adsorbed":[70],"reactants":[71],"is":[72,77],"rate-determining":[74],"step,":[75],"which":[76],"followed":[78],"by":[79],"equilibrated":[80],"desorption":[81],"produced":[84]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2022,"cited_by_count":4},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":3},{"year":2012,"cited_by_count":1}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}