{"id":"https://openalex.org/W2071297787","doi":"https://doi.org/10.1039/b106486j","title":"Development of a new liquid chromatography method for the separation and speciation of organic and inorganic selenium compounds via particle beam-hollow cathode glow discharge-optical emission spectroscopy","display_name":"Development of a new liquid chromatography method for the separation and speciation of organic and inorganic selenium compounds via particle beam-hollow cathode glow discharge-optical emission spectroscopy","publication_year":2002,"publication_date":"2002-01-17","ids":{"openalex":"https://openalex.org/W2071297787","doi":"https://doi.org/10.1039/b106486j","mag":"2071297787"},"language":"en","primary_location":{"id":"doi:10.1039/b106486j","doi":"https://doi.org/10.1039/b106486j","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b106486j","pdf_url":null,"source":{"id":"https://openalex.org/S26602194","display_name":"Journal of Analytical Atomic Spectrometry","issn_l":"0267-9477","issn":["0267-9477","1364-5544"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Analytical Atomic Spectrometry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"W. Clay Davis","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I8078737","display_name":"Clemson University","ror":"https://ror.org/037s24f05","country_code":"US","type":"education","lineage":["https://openalex.org/I8078737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"W. Clay Davis","raw_affiliation_strings":["Department of Chemistry, Howard L. Hunter Laboratory, Clemson University, Clemson, SC 29634-1905, USA","Department of Chemistry, Howard L. Hunter Laboratory, Clemson University,Clemson,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Howard L. Hunter Laboratory, Clemson University, Clemson, SC 29634-1905, USA","institution_ids":["https://openalex.org/I8078737"]},{"raw_affiliation_string":"Department of Chemistry, Howard L. Hunter Laboratory, Clemson University,Clemson,USA","institution_ids":["https://openalex.org/I8078737"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058074370","display_name":"Fuxia Jin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I8078737","display_name":"Clemson University","ror":"https://ror.org/037s24f05","country_code":"US","type":"education","lineage":["https://openalex.org/I8078737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Fuxia Jin","raw_affiliation_strings":["Department of Chemistry, Howard L. Hunter Laboratory, Clemson University, Clemson, SC 29634-1905, USA","Department of Chemistry, Howard L. Hunter Laboratory, Clemson University,Clemson,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Howard L. Hunter Laboratory, Clemson University, Clemson, SC 29634-1905, USA","institution_ids":["https://openalex.org/I8078737"]},{"raw_affiliation_string":"Department of Chemistry, Howard L. Hunter Laboratory, Clemson University,Clemson,USA","institution_ids":["https://openalex.org/I8078737"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5044916107","display_name":"Melissa A. Dempster","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I8078737","display_name":"Clemson University","ror":"https://ror.org/037s24f05","country_code":"US","type":"education","lineage":["https://openalex.org/I8078737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Melissa A. Dempster","raw_affiliation_strings":["Department of Chemistry, Howard L. Hunter Laboratory, Clemson University, Clemson, SC 29634-1905, USA","Department of Chemistry, Howard L. Hunter Laboratory, Clemson University,Clemson,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Howard L. Hunter Laboratory, Clemson University, Clemson, SC 29634-1905, USA","institution_ids":["https://openalex.org/I8078737"]},{"raw_affiliation_string":"Department of Chemistry, Howard L. Hunter Laboratory, Clemson University,Clemson,USA","institution_ids":["https://openalex.org/I8078737"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5056688799","display_name":"Jennifer L. Robichaud","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I8078737","display_name":"Clemson University","ror":"https://ror.org/037s24f05","country_code":"US","type":"education","lineage":["https://openalex.org/I8078737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jennifer L. Robichaud","raw_affiliation_strings":["Department of Chemistry, Howard L. Hunter Laboratory, Clemson University, Clemson, SC 29634-1905, USA","Department of Chemistry, Howard L. Hunter Laboratory, Clemson University,Clemson,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Howard L. Hunter Laboratory, Clemson University, Clemson, SC 29634-1905, USA","institution_ids":["https://openalex.org/I8078737"]},{"raw_affiliation_string":"Department of Chemistry, Howard L. Hunter Laboratory, Clemson University,Clemson,USA","institution_ids":["https://openalex.org/I8078737"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5011021504","display_name":"Richard Kenneth Marcus","orcid":"https://orcid.org/0000-0003-4276-5805","observed_orcids":["https://orcid.org/0000-0003-4276-5805"]},"institutions":[{"id":"https://openalex.org/I8078737","display_name":"Clemson University","ror":"https://ror.org/037s24f05","country_code":"US","type":"education","lineage":["https://openalex.org/I8078737"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"R. Kenneth Marcus","raw_affiliation_strings":["Department of Chemistry, Howard L. Hunter Laboratory, Clemson University, Clemson, SC 29634-1905, USA","Department of Chemistry, Howard L. Hunter Laboratory, Clemson University,Clemson,USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Howard L. Hunter Laboratory, Clemson University, Clemson, SC 29634-1905, USA","institution_ids":["https://openalex.org/I8078737"]},{"raw_affiliation_string":"Department of Chemistry, Howard L. Hunter Laboratory, Clemson University,Clemson,USA","institution_ids":["https://openalex.org/I8078737"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5011021504"],"corresponding_institution_ids":["https://openalex.org/I8078737"],"apc_list":null,"apc_paid":null,"fwci":3.3571,"has_fulltext":false,"cited_by_count":21,"citation_normalized_percentile":{"value":0.91109495,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":97},"biblio":{"volume":"17","issue":"2","first_page":"99","last_page":"103"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11854","display_name":"Laser-induced spectroscopy and plasma","score":0.5791000127792358,"subfield":{"id":"https://openalex.org/subfields/2211","display_name":"Mechanics of Materials"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11854","display_name":"Laser-induced spectroscopy and plasma","score":0.5791000127792358,"subfield":{"id":"https://openalex.org/subfields/2211","display_name":"Mechanics of Materials"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10180","display_name":"Analytical chemistry methods development","score":0.21619999408721924,"subfield":{"id":"https://openalex.org/subfields/1602","display_name":"Analytical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10908","display_name":"Analytical Chemistry and Chromatography","score":0.10599999874830246,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/selenium-speciation","display_name":"selenium speciation","score":0.9610000252723694},{"id":"https://openalex.org/keywords/organoselenium-compounds","display_name":"organoselenium compounds","score":0.8920000195503235},{"id":"https://openalex.org/keywords/liquid-chromatography","display_name":"liquid chromatography","score":0.5210000276565552},{"id":"https://openalex.org/keywords/ion-pair-chromatography","display_name":"ion-pair chromatography","score":0.890999972820282},{"id":"https://openalex.org/keywords/selenocystine","display_name":"selenocystine","score":0.828000009059906},{"id":"https://openalex.org/keywords/selenomethionine","display_name":"selenomethionine","score":0.9990000128746033},{"id":"https://openalex.org/keywords/sodium-selenate","display_name":"sodium selenate","score":0.9449999928474426},{"id":"https://openalex.org/keywords/sodium-selenite","display_name":"sodium selenite","score":0.9990000128746033},{"id":"https://openalex.org/keywords/flow-injection","display_name":"flow injection","score":0.4580000042915344},{"id":"https://openalex.org/keywords/desolvation","display_name":"desolvation","score":0.5429999828338623}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7439125180244446},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.6817664504051208},{"id":"https://openalex.org/C553756173","wikidata":"https://www.wikidata.org/wiki/Q876","display_name":"Selenium","level":2,"score":0.6572742462158203},{"id":"https://openalex.org/C98015330","wikidata":"https://www.wikidata.org/wiki/Q907315","display_name":"Absorbance","level":2,"score":0.5837568044662476},{"id":"https://openalex.org/C10390740","wikidata":"https://www.wikidata.org/wiki/Q2282401","display_name":"Analyte","level":2,"score":0.549883246421814},{"id":"https://openalex.org/C119128265","wikidata":"https://www.wikidata.org/wiki/Q900165","display_name":"Detection limit","level":2,"score":0.5496528744697571},{"id":"https://openalex.org/C2776595061","wikidata":"https://www.wikidata.org/wiki/Q1427934","display_name":"Glow discharge","level":3,"score":0.5186538100242615},{"id":"https://openalex.org/C118495887","wikidata":"https://www.wikidata.org/wiki/Q186548","display_name":"Atomic emission spectroscopy","level":4,"score":0.4819497764110565},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.45112577080726624},{"id":"https://openalex.org/C95974651","wikidata":"https://www.wikidata.org/wiki/Q2454436","display_name":"Inductively coupled plasma","level":3,"score":0.18066191673278809},{"id":"https://openalex.org/C82706917","wikidata":"https://www.wikidata.org/wiki/Q10251","display_name":"Plasma","level":2,"score":0.17356643080711365},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/b106486j","doi":"https://doi.org/10.1039/b106486j","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b106486j","pdf_url":null,"source":{"id":"https://openalex.org/S26602194","display_name":"Journal of Analytical Atomic Spectrometry","issn_l":"0267-9477","issn":["0267-9477","1364-5544"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Analytical Atomic Spectrometry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"display_name":"Clean water and sanitation","id":"https://metadata.un.org/sdg/6","score":0.5699999928474426}],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320309106","display_name":"Clemson University","ror":"https://ror.org/037s24f05"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":23,"referenced_works":["https://openalex.org/W32757006","https://openalex.org/W1967103052","https://openalex.org/W1967130502","https://openalex.org/W1971851800","https://openalex.org/W1975999077","https://openalex.org/W1978635793","https://openalex.org/W1979304254","https://openalex.org/W2001279678","https://openalex.org/W2004311521","https://openalex.org/W2005811740","https://openalex.org/W2030144233","https://openalex.org/W2034075088","https://openalex.org/W2050282682","https://openalex.org/W2056516718","https://openalex.org/W2060754735","https://openalex.org/W2064912729","https://openalex.org/W2066024461","https://openalex.org/W2074080961","https://openalex.org/W2078364646","https://openalex.org/W2085146255","https://openalex.org/W2088325900","https://openalex.org/W2094314614","https://openalex.org/W2108610115"],"related_works":["https://openalex.org/W2073969114","https://openalex.org/W2085146255","https://openalex.org/W2012726497","https://openalex.org/W1981715951","https://openalex.org/W1972409126","https://openalex.org/W2056516718","https://openalex.org/W2141622849","https://openalex.org/W2000142002","https://openalex.org/W1983389191","https://openalex.org/W2025115878"],"abstract_inverted_index":{"A":[0,99],"system":[1,235],"for":[2,47,145,178,241],"the":[3,82,86,136,140,146,150,191,204,207,212,216,226,230,233],"separation":[4],"and":[5,9,49,79,96,114,152],"detection":[6,165,220],"of":[7,61,148,167,184,190,206,215,221,225,232],"inorganic":[8,153],"organic":[10,113,151],"selenium":[11,147],"compounds":[12,88,111,154,228],"utilizing":[13],"particle":[14],"beam-hollow":[15],"cathode":[16],"glow":[17],"discharge-optical":[18],"emission":[19,129,219],"spectroscopy":[20],"(PB-HC-OES)":[21],"as":[22,236],"a":[23,33,38,42,50,68,182,237],"selenium-specific":[24,239],"detector":[25,240],"has":[26],"been":[27],"investigated.":[28],"The":[29,58,123,187],"PB":[30,208],"interface":[31,209],"includes":[32],"thermoconcentric":[34],"nebulizer":[35],"to":[36,107,197,210],"generate":[37],"finely":[39],"dispersed":[40],"aerosol,":[41],"heated":[43,69],"metal":[44],"spray":[45],"chamber":[46],"desolvation,":[48],"two-stage":[51],"momentum":[52],"separator,":[53],"which":[54],"removes":[55],"solvent":[56],"vapor.":[57],"resulting":[59],"beam":[60],"dry":[62],"analyte":[63,193],"particles":[64],"are":[65,76,195],"introduced":[66],"into":[67],"(\u223c250":[70],"\u00b0C)":[71],"hollow":[72],"cathode,":[73],"where":[74],"they":[75],"vaporized,":[77],"atomized":[78],"excited":[80],"within":[81],"plasma.":[83],"Using":[84],"LC-PB-HC-OES":[85],"following":[87],"were":[89],"examined:":[90],"selenocystine,":[91],"selenomethionine,":[92],"selenoethionine,":[93],"sodium":[94,97],"selenate,":[95],"selenite.":[98],"reverse":[100],"phase":[101],"ion-pairing":[102],"chromatography":[103],"method":[104],"was":[105,131],"developed":[106],"separate":[108],"these":[109],"five":[110,192],"(both":[112],"inorganic),":[115],"with":[116,139,172],"UV":[117,201],"absorbance":[118],"monitored":[119,133],"at":[120],"210":[121],"nm.":[122],"Se":[124],"I":[125],"204.0":[126],"nm":[127],"atomic":[128],"intensity":[130],"then":[132],"by":[134,200],"coupling":[135],"LC":[137],"column":[138],"PB-HC-OES":[141,234],"system.":[142],"Emission":[143],"responses":[144],"both":[149],"in":[155],"flow":[156],"injection":[157,162],"mode":[158],"using":[159],"200":[160],"\u00b5L":[161],"volumes":[163],"indicate":[164],"limits":[166],"\u223c200":[168],"ppb":[169],"(100":[170],"ng)":[171],"less":[173],"than":[174],"10%":[175],"RSD":[176],"variability":[177],"triplicate":[179],"injections":[180],"over":[181],"range":[183],"200\u20131960":[185],"ng.":[186],"retention":[188],"times":[189],"peaks":[194],"similar":[196],"those":[198],"detected":[199],"absorbance,":[202],"demonstrating":[203],"ability":[205],"preserve":[211],"chromatographic":[213,223],"integrity":[214],"separation.":[217],"Optical":[218],"liquid":[222,242],"separations":[224],"selenium-containing":[227],"demonstrates":[229],"feasibility":[231],"simple":[238],"chromatography.":[243]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2014,"cited_by_count":1}],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}