{"id":"https://openalex.org/W2069734407","doi":"https://doi.org/10.1002/ange.19760881303","title":"Mechanistische Aspekte der Olefin\u2010Metathese","display_name":"Mechanistische Aspekte der Olefin\u2010Metathese","publication_year":1976,"publication_date":"1976-07-01","ids":{"openalex":"https://openalex.org/W2069734407","doi":"https://doi.org/10.1002/ange.19760881303","mag":"2069734407"},"language":"de","primary_location":{"id":"doi:10.1002/ange.19760881303","doi":"https://doi.org/10.1002/ange.19760881303","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.19760881303","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5049072099","display_name":"Nissim Calderon","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210143271","display_name":"Goodyear (United States)","ror":"https://ror.org/03bfyaa19","country_code":"US","type":"company","lineage":["https://openalex.org/I4210143271"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nissim Calderon","raw_affiliation_strings":["The Goodyear Tire & Rubber Co., Research Division Akron, Ohio 44316 (USA) 551. Mitteilung"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Goodyear Tire & Rubber Co., Research Division Akron, Ohio 44316 (USA) 551. Mitteilung","institution_ids":["https://openalex.org/I4210143271"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067991170","display_name":"Eilert A. Ofstead","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210143271","display_name":"Goodyear (United States)","ror":"https://ror.org/03bfyaa19","country_code":"US","type":"company","lineage":["https://openalex.org/I4210143271"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"E. A. Ofstead","raw_affiliation_strings":["The Goodyear Tire & Rubber Co., Research Division Akron, Ohio 44316 (USA) 551. Mitteilung"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Goodyear Tire & Rubber Co., Research Division Akron, Ohio 44316 (USA) 551. Mitteilung","institution_ids":["https://openalex.org/I4210143271"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5053285070","display_name":"W. Allen Judy","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210143271","display_name":"Goodyear (United States)","ror":"https://ror.org/03bfyaa19","country_code":"US","type":"company","lineage":["https://openalex.org/I4210143271"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"W. A. Judy","raw_affiliation_strings":["The Goodyear Tire & Rubber Co., Research Division Akron, Ohio 44316 (USA) 551. Mitteilung"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Goodyear Tire & Rubber Co., Research Division Akron, Ohio 44316 (USA) 551. Mitteilung","institution_ids":["https://openalex.org/I4210143271"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I4210143271"],"apc_list":{"value":5790,"currency":"USD","value_usd":5790},"apc_paid":null,"fwci":6.9986,"has_fulltext":false,"cited_by_count":46,"citation_normalized_percentile":{"value":0.98303411,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":95},"biblio":{"volume":"88","issue":"13","first_page":"433","last_page":"442"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11549","display_name":"Synthetic Organic Chemistry Methods","score":0.8935999870300293,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11549","display_name":"Synthetic Organic Chemistry Methods","score":0.8935999870300293,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.09570000320672989,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.001500000013038516,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/olefin-metathesis","display_name":"olefin metathesis","score":0.9990000128746033},{"id":"https://openalex.org/keywords/transition-state","display_name":"transition state","score":0.8169999718666077},{"id":"https://openalex.org/keywords/chain-reaction-mechanism","display_name":"chain reaction mechanism","score":0.5879999995231628},{"id":"https://openalex.org/keywords/carbenes","display_name":"carbenes","score":0.8700000047683716},{"id":"https://openalex.org/keywords/metallacycles","display_name":"metallacycles","score":0.9229999780654907},{"id":"https://openalex.org/keywords/terminal-olefins","display_name":"terminal olefins","score":0.7269999980926514},{"id":"https://openalex.org/keywords/internal-olefins","display_name":"internal olefins","score":0.7919999957084656},{"id":"https://openalex.org/keywords/regioselectivity","display_name":"regioselectivity","score":0.7369999885559082},{"id":"https://openalex.org/keywords/steric-effects","display_name":"steric effects","score":0.7110000252723694},{"id":"https://openalex.org/keywords/metathesis-catalysts","display_name":"metathesis catalysts","score":0.7850000262260437}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8364059925079346}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.19760881303","doi":"https://doi.org/10.1002/ange.19760881303","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.19760881303","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":33,"referenced_works":["https://openalex.org/W562458176","https://openalex.org/W647911431","https://openalex.org/W1553334906","https://openalex.org/W1621500924","https://openalex.org/W1762603737","https://openalex.org/W1970071140","https://openalex.org/W1981379193","https://openalex.org/W1983695899","https://openalex.org/W1986955969","https://openalex.org/W1989832431","https://openalex.org/W2003212312","https://openalex.org/W2009624417","https://openalex.org/W2013588355","https://openalex.org/W2022549457","https://openalex.org/W2022918531","https://openalex.org/W2024088493","https://openalex.org/W2028346240","https://openalex.org/W2078397956","https://openalex.org/W2082031419","https://openalex.org/W2083025048","https://openalex.org/W2083401454","https://openalex.org/W2238328241","https://openalex.org/W2315713925","https://openalex.org/W2319878859","https://openalex.org/W2320407534","https://openalex.org/W2329193800","https://openalex.org/W2498634116","https://openalex.org/W2950460969","https://openalex.org/W2951176318","https://openalex.org/W2952584124","https://openalex.org/W2952704516","https://openalex.org/W2952893644","https://openalex.org/W2953375457"],"related_works":["https://openalex.org/W2061541352","https://openalex.org/W1996069382","https://openalex.org/W4241528169","https://openalex.org/W2950460969","https://openalex.org/W1970071140","https://openalex.org/W2033223628","https://openalex.org/W2008008366","https://openalex.org/W4231159419","https://openalex.org/W2144660143","https://openalex.org/W3005266902"],"abstract_inverted_index":{"Abstract":[0],"In":[1],"diesem":[2],"Aufsatz":[3],"werden":[4],"Anschauungen":[5],"\u00fcber":[6],"die":[7,39,47,54,97],"Art":[8],"des":[9],"\u00dcbergangszustands":[10],"bei":[11,37,55],"der":[12],"Olefin\u2010Metathese":[13],"diskutiert.":[14],"Die":[15],"fr\u00fcher":[16],"angenommene":[17],"paarweise":[18],"Umordnung":[19],"ist":[20],"k\u00fcrzlich":[21],"angezweifelt":[22],"worden.":[23],"Metathese\u2010Studien":[24],"sowohl":[25],"an":[26,30,101],"acyclischen":[27],"als":[28],"auch":[29],"cyclischen":[31],"Olefinen":[32,57,68,70],"legen":[33],"einen":[34,44],"Kettenmechanismus":[35],"nahe,":[36],"dem":[38],"Umwandlung":[40],"eines":[41],"Carbens":[42],"in":[43,64],"Metallocyclus":[45],"f\u00fcr":[46,108],"Umalkylidenierung":[48],"verantwortlich":[49],"sein":[50],"k\u00f6nnte.":[51],"Einige":[52,91],"Katalysator\u2010Systeme,":[53],"terminalen":[56,67],"nur":[58],"eine":[59],"niedrige":[60],"Metathese\u2010Aktivit\u00e4t":[61],"zeigen,":[62,81],"f\u00fchren":[63],"Mischungen":[65],"von":[66],"und":[69],"mit":[71],"innenst\u00e4ndiger":[72],"Doppelbindung":[73],"dagegen":[74],"selektiv":[75],"zu":[76],"gekreuzten":[77],"Produkten.":[78],"Kritische":[79],"Experimente":[80],"da\u00df":[82,96],"terminale":[83],"Olefine":[84],"bevorzugt":[85],"einer":[86],"schnellen":[87],"regenerativen":[88],"Metathese":[89],"unterliegen.":[90],"Ergebnisse":[92],"deuten":[93],"darauf":[94],"hin,":[95],"strengsten":[98],"sterischen":[99],"Anforderungen":[100],"das":[102],"\u03b2\u2010C\u2010Atom":[103],"gestellt":[104],"werden;":[105],"einleuchtende":[106],"Gr\u00fcnde":[107],"diese":[109],"sterische":[110],"Forderung":[111],"gibt":[112],"es":[113],"jedoch":[114],"nicht.":[115]},"counts_by_year":[{"year":2012,"cited_by_count":2}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}