{"id":"https://openalex.org/W2069286153","doi":"https://doi.org/10.1039/tf9686401174","title":"Electron spin resonance spectra of carboxylic acid radical anions at 77\u00b0K","display_name":"Electron spin resonance spectra of carboxylic acid radical anions at 77\u00b0K","publication_year":1968,"publication_date":"1968-01-01","ids":{"openalex":"https://openalex.org/W2069286153","doi":"https://doi.org/10.1039/tf9686401174","mag":"2069286153"},"language":"en","primary_location":{"id":"doi:10.1039/tf9686401174","doi":"https://doi.org/10.1039/tf9686401174","is_oa":false,"landing_page_url":"https://doi.org/10.1039/tf9686401174","pdf_url":null,"source":{"id":"https://openalex.org/S164507617","display_name":"Transactions of the Faraday Society","issn_l":"0014-7672","issn":["0014-7672","2050-5647"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Trans. Faraday Soc.","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5075884909","display_name":"John E. Bennett","orcid":"https://orcid.org/0009-0008-1257-098X","observed_orcids":["https://orcid.org/0009-0008-1257-098X"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"J. E. Bennett","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5112969957","display_name":"L. H. Gale","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"L. H. Gale","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":4.8363,"has_fulltext":false,"cited_by_count":61,"citation_normalized_percentile":{"value":0.96521146,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":96},"biblio":{"volume":"64","issue":"0","first_page":"1174","last_page":"1187"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12381","display_name":"Electron Spin Resonance Studies","score":0.9940999746322632,"subfield":{"id":"https://openalex.org/subfields/1304","display_name":"Biophysics"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},"topics":[{"id":"https://openalex.org/T12381","display_name":"Electron Spin Resonance Studies","score":0.9940999746322632,"subfield":{"id":"https://openalex.org/subfields/1304","display_name":"Biophysics"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Chemical Reactions and Mechanisms","score":0.002899999963119626,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13013","display_name":"Free Radicals and Antioxidants","score":0.0008999999845400453,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/sodium-deposition","display_name":"sodium deposition","score":0.38600000739097595},{"id":"https://openalex.org/keywords/epr-spectra","display_name":"EPR spectra","score":0.656000018119812},{"id":"https://openalex.org/keywords/deuterated-acetic-acid","display_name":"deuterated acetic acid","score":0.9269999861717224},{"id":"https://openalex.org/keywords/hydrogen-abstraction","display_name":"hydrogen abstraction","score":0.7870000004768372},{"id":"https://openalex.org/keywords/secondary-radicals","display_name":"secondary radicals","score":0.8659999966621399},{"id":"https://openalex.org/keywords/isobutyric-acid","display_name":"isobutyric acid","score":0.8360000252723694}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9437167048454285},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.8051894903182983},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.7982162237167358},{"id":"https://openalex.org/C131538251","wikidata":"https://www.wikidata.org/wiki/Q1413102","display_name":"Hyperfine structure","level":2,"score":0.6381345987319946},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.5758097767829895},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4744231104850769},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.4466276466846466},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.41967514157295227},{"id":"https://openalex.org/C2779074116","wikidata":"https://www.wikidata.org/wiki/Q134856","display_name":"Carboxylic acid","level":2,"score":0.41473960876464844},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.41170600056648254},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.401054710149765},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.2679145932197571},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.13319233059883118},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.07531782984733582},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/tf9686401174","doi":"https://doi.org/10.1039/tf9686401174","is_oa":false,"landing_page_url":"https://doi.org/10.1039/tf9686401174","pdf_url":null,"source":{"id":"https://openalex.org/S164507617","display_name":"Transactions of the Faraday Society","issn_l":"0014-7672","issn":["0014-7672","2050-5647"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Trans. Faraday Soc.","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2008207425","https://openalex.org/W2033821333","https://openalex.org/W1968265312","https://openalex.org/W2170968845","https://openalex.org/W2021948744","https://openalex.org/W2039982735","https://openalex.org/W2026497500","https://openalex.org/W2034839119","https://openalex.org/W2077941213","https://openalex.org/W2045191548"],"abstract_inverted_index":{"Sodium":[0],"atoms":[1],"have":[2,95],"been":[3,96],"deposited":[4],"on":[5,156],"a":[6,118],"series":[7],"of":[8,66,86,104,153,159],"monocarboxylic":[9],"acids,":[10],"R\u2014COOH,":[11],"at":[12,70,144],"77\u00b0":[13,71,145],"K":[14,72,146],"in":[15,37,121,128,163,187],"the":[16,20,33,41,56,80,87,99,113,124,157,160,164,178,184,192],"rotating":[17],"cryostat":[18],"and":[19,73,83],"deposits":[21],"examined":[22],"by":[23,60],"electron":[24],"spin":[25],"resonance":[26],"(e.s.r.)":[27],"spectroscopy.":[28],"The":[29,48,90,109,132,151],"spectra":[30,49],"show":[31,111],"that":[32,76,112],"primary":[34,57,175],"paramagnetic":[35],"species":[36],"each":[38],"case":[39],"is":[40],"corresponding":[42,88],"radical":[43,81,100,133,179,193],"O\u2013":[44],"anion,":[45,101],"[graphic":[46,102],"omitted].":[47],"are":[50,79,135],"similar":[51],"to":[52,123,137,147,190],"those":[53],"observed":[54],"for":[55,98],"radicals":[58,78],"formed":[59],"X-,":[61],"\u03b2-":[62],"or":[63],"\u03b3-":[64],"irradiation":[65],"mono-or":[67],"di-carboxylic":[68],"acids":[69],"thus":[74],"confirm":[75],"these":[77],"anions,":[82],"not":[84],"cations,":[85],"acids.":[89],"carbon-13":[91],"hyperfine":[92],"coupling":[93],"constants":[94],"determined":[97],"omitted],":[103],"fully":[105],"deuterated":[106],"acetic":[107,170],"acid.":[108,165],"results":[110],"free":[114],"valence":[115],"centre":[116],"has":[117],"pyramidal":[119],"configuration,":[120],"contrast":[122],"planar":[125],"structure":[126],"found":[127],"many":[129],"alkyl":[130],"radicals.":[131,150],"anions":[134],"able":[136],"abstract":[138],"hydrogen":[139,186],"from":[140],"adjacent":[141],"neutral":[142],"molecules":[143],"give":[148,191],"secondary":[149],"extent":[152],"reaction":[154,167],"depends":[155],"strength":[158],"CH":[161],"bonds":[162],"Negligible":[166],"occurs":[168],"with":[169,183],"acid":[171,189],"which":[172],"possesses":[173],"only":[174],"hydrogens,":[176],"whereas":[177],"anion":[180],"reacts":[181],"completely":[182],"tertiary":[185],"isobutyric":[188],"(CH3)2CCOOH.":[194]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-07-30T17:31:21.811387","created_date":"2016-06-24T00:00:00"}