{"id":"https://openalex.org/W2069272848","doi":"https://doi.org/10.1063/1.3168524","title":"Surface anchoring and dynamics of thiolated azobenzene molecules on Au(111)","display_name":"Surface anchoring and dynamics of thiolated azobenzene molecules on Au(111)","publication_year":2009,"publication_date":"2009-07-17","ids":{"openalex":"https://openalex.org/W2069272848","doi":"https://doi.org/10.1063/1.3168524","mag":"2069272848","pmid":"https://pubmed.ncbi.nlm.nih.gov/19624221"},"language":"en","primary_location":{"id":"doi:10.1063/1.3168524","doi":"https://doi.org/10.1063/1.3168524","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.3168524","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5018123468","display_name":"Jongweon Cho","orcid":"https://orcid.org/0000-0002-8956-5969","observed_orcids":["https://orcid.org/0000-0002-8956-5969"]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jongweon Cho","raw_affiliation_strings":["Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","University of California at Berkeley 1 Department of Physics, , Berkeley, California 94720-7300, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"University of California at Berkeley 1 Department of Physics, , Berkeley, California 94720-7300, USA","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5075834952","display_name":"Niv Levy","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Niv Levy","raw_affiliation_strings":["Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","University of California at Berkeley 1 Department of Physics, , Berkeley, California 94720-7300, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"University of California at Berkeley 1 Department of Physics, , Berkeley, California 94720-7300, USA","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5027216645","display_name":"\u0410. \u041a\u0438\u0440\u0430\u043a\u043e\u0441\u044f\u043d","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Armen Kirakosian","raw_affiliation_strings":["Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","University of California at Berkeley 1 Department of Physics, , Berkeley, California 94720-7300, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"University of California at Berkeley 1 Department of Physics, , Berkeley, California 94720-7300, USA","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5060310185","display_name":"Matthew Comstock","orcid":"https://orcid.org/0000-0002-6931-285X","observed_orcids":["https://orcid.org/0000-0002-6931-285X"]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Matthew J. Comstock","raw_affiliation_strings":["Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","University of California at Berkeley 1 Department of Physics, , Berkeley, California 94720-7300, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"University of California at Berkeley 1 Department of Physics, , Berkeley, California 94720-7300, USA","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043678948","display_name":"Frank Lauterwasser","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Frank Lauterwasser","raw_affiliation_strings":["Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","University of California 3 Department of Chemistry, , Berkeley, California 94720-1460, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"University of California 3 Department of Chemistry, , Berkeley, California 94720-1460, USA","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002152167","display_name":"Jean M. J. Fr\u00e9chet","orcid":"https://orcid.org/0000-0001-6419-0163","observed_orcids":["https://orcid.org/0000-0001-6419-0163"]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jean M. J. Fr\u00e9chet","raw_affiliation_strings":["Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","University of California 3 Department of Chemistry, , Berkeley, California 94720-1460, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"University of California 3 Department of Chemistry, , Berkeley, California 94720-1460, USA","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5033229285","display_name":"Michael F. Crommie","orcid":"https://orcid.org/0000-0001-8246-3444","observed_orcids":["https://orcid.org/0000-0001-8246-3444"]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Michael F. Crommie","raw_affiliation_strings":["Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","University of California at Berkeley 1 Department of Physics, , Berkeley, California 94720-7300, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Lawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"University of California at Berkeley 1 Department of Physics, , Berkeley, California 94720-7300, USA","institution_ids":["https://openalex.org/I95457486"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":0.9652,"has_fulltext":false,"cited_by_count":13,"citation_normalized_percentile":{"value":0.6870471,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":97},"biblio":{"volume":"131","issue":"3","first_page":"034707","last_page":"034707"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.9375,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.9375,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10913","display_name":"Molecular Junctions and Nanostructures","score":0.059300001710653305,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11708","display_name":"Photochromic and Fluorescence Chemistry","score":0.00139999995008111,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/au-111","display_name":"Au(111)","score":0.8460000157356262},{"id":"https://openalex.org/keywords/surface-anchoring","display_name":"surface anchoring","score":0.9089999794960022},{"id":"https://openalex.org/keywords/hindered-rotation","display_name":"hindered rotation","score":0.9309999942779541},{"id":"https://openalex.org/keywords/thermal-isomerization","display_name":"thermal isomerization","score":0.6759999990463257},{"id":"https://openalex.org/keywords/energy-barrier","display_name":"energy barrier","score":0.5879999995231628},{"id":"https://openalex.org/keywords/attempt-frequency","display_name":"attempt frequency","score":0.9779999852180481},{"id":"https://openalex.org/keywords/single-molecule-dynamics","display_name":"single-molecule dynamics","score":0.7609999775886536},{"id":"https://openalex.org/keywords/temperature-dependence","display_name":"temperature dependence","score":0.5289999842643738},{"id":"https://openalex.org/keywords/surface-morphology","display_name":"surface morphology","score":0.6669999957084656}],"concepts":[{"id":"https://openalex.org/C2778150588","wikidata":"https://www.wikidata.org/wiki/Q8884513","display_name":"Azobenzene","level":3,"score":0.9697575569152832},{"id":"https://openalex.org/C18483071","wikidata":"https://www.wikidata.org/wiki/Q168432","display_name":"Anchoring","level":2,"score":0.8101929426193237},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.530641496181488},{"id":"https://openalex.org/C2776799497","wikidata":"https://www.wikidata.org/wiki/Q484298","display_name":"Surface (topology)","level":2,"score":0.4859980046749115},{"id":"https://openalex.org/C145912823","wikidata":"https://www.wikidata.org/wiki/Q113558","display_name":"Dynamics (music)","level":2,"score":0.45742830634117126},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4041769206523895},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.372725248336792},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3375791907310486},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.32615113258361816},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.14549481868743896},{"id":"https://openalex.org/C15744967","wikidata":"https://www.wikidata.org/wiki/Q9418","display_name":"Psychology","level":0,"score":0.11185815930366516},{"id":"https://openalex.org/C188147891","wikidata":"https://www.wikidata.org/wiki/Q147638","display_name":"Cognitive science","level":1,"score":0.09903442859649658},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.07727649807929993},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.05146178603172302},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.049399763345718384},{"id":"https://openalex.org/C24890656","wikidata":"https://www.wikidata.org/wiki/Q82811","display_name":"Acoustics","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D001391","descriptor_name":"Azo Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D006046","descriptor_name":"Gold","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D010316","descriptor_name":"Particle Size","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D013438","descriptor_name":"Sulfhydryl Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D013499","descriptor_name":"Surface Properties","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D013816","descriptor_name":"Thermodynamics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1063/1.3168524","doi":"https://doi.org/10.1063/1.3168524","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.3168524","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},{"id":"pmid:19624221","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/19624221","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of chemical physics","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320332359","display_name":"Office of Science","ror":"https://ror.org/00mmn6b08"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":26,"referenced_works":["https://openalex.org/W1480193527","https://openalex.org/W1974436039","https://openalex.org/W1981170157","https://openalex.org/W1987347836","https://openalex.org/W1988028763","https://openalex.org/W1996625569","https://openalex.org/W1996782241","https://openalex.org/W2004412281","https://openalex.org/W2009835690","https://openalex.org/W2012499551","https://openalex.org/W2026440318","https://openalex.org/W2035794494","https://openalex.org/W2038100642","https://openalex.org/W2038203596","https://openalex.org/W2045725637","https://openalex.org/W2048631643","https://openalex.org/W2053925793","https://openalex.org/W2054217978","https://openalex.org/W2059828431","https://openalex.org/W2067197439","https://openalex.org/W2087623017","https://openalex.org/W2121234655","https://openalex.org/W2133899617","https://openalex.org/W2144087168","https://openalex.org/W2154395440","https://openalex.org/W2166806803"],"related_works":["https://openalex.org/W2059828431","https://openalex.org/W3179254565","https://openalex.org/W2034779476","https://openalex.org/W2568505369","https://openalex.org/W1894164564","https://openalex.org/W2147806413","https://openalex.org/W2161180582","https://openalex.org/W3131729177","https://openalex.org/W2006026023","https://openalex.org/W2434520454"],"abstract_inverted_index":{"We":[0],"have":[1],"investigated":[2],"the":[3,68,88],"temperature-dependent":[4],"behavior":[5],"of":[6,18,31,70,76],"thiolated":[7],"azobenzene":[8,24,33,38],"molecules":[9,25,34,56,72],"on":[10],"Au(111)":[11],"using":[12,79],"scanning":[13],"tunneling":[14],"microscopy.":[15],"The":[16],"addition":[17],"a":[19,74,80],"thiol":[20],"functional":[21],"group":[22],"to":[23,27,35,59,86,99],"leads":[26],"increased":[28],"surface":[29,41],"anchoring":[30],"single":[32],"gold.":[36],"Thiolated":[37],"shows":[39],"diverse":[40],"morphology":[42],"and":[43,78,91,103],"does":[44],"not":[45],"form":[46],"well-ordered":[47],"structures":[48],"at":[49],"low":[50],"coverage.":[51],"At":[52],"elevated":[53],"temperatures,":[54],"anchored":[55],"are":[57,84],"observed":[58],"spin":[60],"in":[61],"place":[62],"via":[63],"hindered":[64,97],"rotation.":[65],"By":[66],"measuring":[67],"number":[69],"rotating":[71],"as":[73],"function":[75],"temperature":[77],"simple":[81],"model,":[82],"we":[83],"able":[85],"estimate":[87],"energy":[89],"barrier":[90],"attempt":[92],"frequency":[93],"for":[94],"thermally":[95],"induced":[96],"rotation":[98],"be":[100],"102+/-3":[101],"meV":[102],"110+/-2":[104],"GHz,":[105],"respectively.":[106]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2017,"cited_by_count":1},{"year":2015,"cited_by_count":2}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}