{"id":"https://openalex.org/W2064913004","doi":"https://doi.org/10.1080/03067319.2015.1016015","title":"Preparation of standard VOC mixtures for climate monitoring","display_name":"Preparation of standard VOC mixtures for climate monitoring","publication_year":2015,"publication_date":"2015-03-09","ids":{"openalex":"https://openalex.org/W2064913004","doi":"https://doi.org/10.1080/03067319.2015.1016015","mag":"2064913004"},"language":"en","primary_location":{"id":"doi:10.1080/03067319.2015.1016015","doi":"https://doi.org/10.1080/03067319.2015.1016015","is_oa":false,"landing_page_url":"https://doi.org/10.1080/03067319.2015.1016015","pdf_url":null,"source":{"id":"https://openalex.org/S203371744","display_name":"International Journal of Environmental & Analytical Chemistry","issn_l":"0306-7319","issn":["0306-7319","1026-7468","1029-0397"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"International Journal of Environmental Analytical Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5041186597","display_name":"Guido Sassi","orcid":"https://orcid.org/0000-0002-6417-3467","observed_orcids":["https://orcid.org/0000-0002-6417-3467"]},"institutions":[{"id":"https://openalex.org/I177477856","display_name":"Politecnico di Torino","ror":"https://ror.org/00bgk9508","country_code":"IT","type":"education","lineage":["https://openalex.org/I177477856"]},{"id":"https://openalex.org/I4210136559","display_name":"Istituto Nazionale di Ricerca Metrologica","ror":"https://ror.org/03vn1bh77","country_code":"IT","type":"facility","lineage":["https://openalex.org/I4210104593","https://openalex.org/I4210136559","https://openalex.org/I4392021227"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Guido Sassi","raw_affiliation_strings":["Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy; Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Torino, Italy","Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Torino, Italy","Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy; Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Torino, Italy","institution_ids":["https://openalex.org/I177477856","https://openalex.org/I4210136559"]},{"raw_affiliation_string":"Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Torino, Italy","institution_ids":["https://openalex.org/I177477856"]},{"raw_affiliation_string":"Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy","institution_ids":["https://openalex.org/I4210136559"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010023538","display_name":"Alessia Demichelis","orcid":"https://orcid.org/0000-0002-7633-4125","observed_orcids":["https://orcid.org/0000-0002-7633-4125"]},"institutions":[{"id":"https://openalex.org/I4210136559","display_name":"Istituto Nazionale di Ricerca Metrologica","ror":"https://ror.org/03vn1bh77","country_code":"IT","type":"facility","lineage":["https://openalex.org/I4210104593","https://openalex.org/I4210136559","https://openalex.org/I4392021227"]}],"countries":["IT"],"is_corresponding":true,"raw_author_name":"Alessia Demichelis","raw_affiliation_strings":["Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy","institution_ids":["https://openalex.org/I4210136559"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038677499","display_name":"Maricarmen Lecuna","orcid":"https://orcid.org/0000-0001-5171-4319","observed_orcids":["https://orcid.org/0000-0001-5171-4319"]},"institutions":[{"id":"https://openalex.org/I177477856","display_name":"Politecnico di Torino","ror":"https://ror.org/00bgk9508","country_code":"IT","type":"education","lineage":["https://openalex.org/I177477856"]},{"id":"https://openalex.org/I4210136559","display_name":"Istituto Nazionale di Ricerca Metrologica","ror":"https://ror.org/03vn1bh77","country_code":"IT","type":"facility","lineage":["https://openalex.org/I4210104593","https://openalex.org/I4210136559","https://openalex.org/I4392021227"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Maricarmen Lecuna","raw_affiliation_strings":["Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy; Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Torino, Italy","Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Torino, Italy","Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy; Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Torino, Italy","institution_ids":["https://openalex.org/I177477856","https://openalex.org/I4210136559"]},{"raw_affiliation_string":"Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Torino, Italy","institution_ids":["https://openalex.org/I177477856"]},{"raw_affiliation_string":"Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy","institution_ids":["https://openalex.org/I4210136559"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5078583558","display_name":"Maria Paola Sassi","orcid":"https://orcid.org/0000-0002-6730-6544","observed_orcids":["https://orcid.org/0000-0002-6730-6544","https://orcid.org/0000-0002-6114-6826"]},"institutions":[{"id":"https://openalex.org/I4210136559","display_name":"Istituto Nazionale di Ricerca Metrologica","ror":"https://ror.org/03vn1bh77","country_code":"IT","type":"facility","lineage":["https://openalex.org/I4210104593","https://openalex.org/I4210136559","https://openalex.org/I4392021227"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Maria Paola Sassi","raw_affiliation_strings":["Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Istituto Nazionale di Ricerca Metrologica INRIM, Torino, Italy","institution_ids":["https://openalex.org/I4210136559"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5010023538"],"corresponding_institution_ids":["https://openalex.org/I4210136559"],"apc_list":null,"apc_paid":null,"fwci":1.5181,"has_fulltext":false,"cited_by_count":9,"citation_normalized_percentile":{"value":0.86088489,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"95","issue":"13","first_page":"1195","last_page":"1207"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11890","display_name":"Scientific Measurement and Uncertainty Evaluation","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/1804","display_name":"Statistics, Probability and Uncertainty"},"field":{"id":"https://openalex.org/fields/18","display_name":"Decision Sciences"},"domain":{"id":"https://openalex.org/domains/2","display_name":"Social Sciences"}},"topics":[{"id":"https://openalex.org/T11890","display_name":"Scientific Measurement and Uncertainty Evaluation","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/1804","display_name":"Statistics, Probability and Uncertainty"},"field":{"id":"https://openalex.org/fields/18","display_name":"Decision Sciences"},"domain":{"id":"https://openalex.org/domains/2","display_name":"Social Sciences"}},{"id":"https://openalex.org/T11588","display_name":"Atmospheric and Environmental Gas Dynamics","score":0.004600000102072954,"subfield":{"id":"https://openalex.org/subfields/2306","display_name":"Global and Planetary Change"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10075","display_name":"Atmospheric chemistry and aerosols","score":0.0020000000949949026,"subfield":{"id":"https://openalex.org/subfields/1902","display_name":"Atmospheric Science"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/volatile-organic-compounds","display_name":"volatile organic compounds","score":0.9929999709129333},{"id":"https://openalex.org/keywords/traceable-standards","display_name":"traceable standards","score":0.44200000166893005},{"id":"https://openalex.org/keywords/global-atmosphere-watch","display_name":"Global Atmosphere Watch","score":0.7910000085830688},{"id":"https://openalex.org/keywords/dynamic-dilution","display_name":"dynamic dilution","score":0.5830000042915344},{"id":"https://openalex.org/keywords/diffusion-method","display_name":"diffusion method","score":0.7350000143051147},{"id":"https://openalex.org/keywords/uncertainty-budget","display_name":"uncertainty budget","score":0.6880000233650208},{"id":"https://openalex.org/keywords/wall-interaction","display_name":"wall interaction","score":0.671999990940094},{"id":"https://openalex.org/keywords/leak-testing","display_name":"leak testing","score":0.7310000061988831},{"id":"https://openalex.org/keywords/oxygenated-vocs","display_name":"oxygenated VOCs","score":0.8399999737739563},{"id":"https://openalex.org/keywords/climate-monitoring","display_name":"climate monitoring","score":0.593999981880188},{"id":"https://openalex.org/keywords/air-quality","display_name":"air quality","score":0.5559999942779541}],"concepts":[{"id":"https://openalex.org/C39432304","wikidata":"https://www.wikidata.org/wiki/Q188847","display_name":"Environmental science","level":0,"score":0.6157627105712891},{"id":"https://openalex.org/C2778150766","wikidata":"https://www.wikidata.org/wiki/Q910267","display_name":"Volatile organic compound","level":2,"score":0.5842945575714111},{"id":"https://openalex.org/C149629883","wikidata":"https://www.wikidata.org/wiki/Q660926","display_name":"Fraction (chemistry)","level":2,"score":0.5542890429496765},{"id":"https://openalex.org/C96618451","wikidata":"https://www.wikidata.org/wiki/Q3028008","display_name":"Dilution","level":2,"score":0.48948419094085693},{"id":"https://openalex.org/C69357855","wikidata":"https://www.wikidata.org/wiki/Q163214","display_name":"Diffusion","level":2,"score":0.46861323714256287},{"id":"https://openalex.org/C2781213060","wikidata":"https://www.wikidata.org/wiki/Q49546","display_name":"Acetone","level":2,"score":0.44844937324523926},{"id":"https://openalex.org/C21880701","wikidata":"https://www.wikidata.org/wiki/Q2144042","display_name":"Process engineering","level":1,"score":0.356522798538208},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.28676068782806396},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.15926644206047058},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.09304723143577576},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1080/03067319.2015.1016015","doi":"https://doi.org/10.1080/03067319.2015.1016015","is_oa":false,"landing_page_url":"https://doi.org/10.1080/03067319.2015.1016015","pdf_url":null,"source":{"id":"https://openalex.org/S203371744","display_name":"International Journal of Environmental & Analytical Chemistry","issn_l":"0306-7319","issn":["0306-7319","1026-7468","1029-0397"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"International Journal of Environmental Analytical Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:iris.inrim.it:11696/30288","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/11696/30288","pdf_url":null,"source":{"id":"https://openalex.org/S4306400708","display_name":"CINECA IRIS Institutional Research Information System (IRIS Istituto Nazionale di Ricerca Metrologica)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I27837315","host_organization_name":"University of Michigan","host_organization_lineage":["https://openalex.org/I27837315"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},{"id":"pmh:oai:iris.polito.it:11583/2644868","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/11583/2644868","pdf_url":null,"source":{"id":"https://openalex.org/S7407055329","display_name":"PORTO@Iris","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:porto.polito.it:2644868","doi":null,"is_oa":false,"landing_page_url":"http://porto.polito.it/2644868/","pdf_url":null,"source":{"id":"https://openalex.org/S4306402038","display_name":"PORTO Publications Open Repository TOrino (Politecnico di Torino)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I177477856","host_organization_name":"Politecnico di Torino","host_organization_lineage":["https://openalex.org/I177477856"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"ISSN:0306-7319","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":11,"referenced_works":["https://openalex.org/W1968141400","https://openalex.org/W1972861871","https://openalex.org/W1992800008","https://openalex.org/W2006528774","https://openalex.org/W2008140327","https://openalex.org/W2030097177","https://openalex.org/W2062465803","https://openalex.org/W2074101569","https://openalex.org/W2163031356","https://openalex.org/W2954688669","https://openalex.org/W6601009120"],"related_works":["https://openalex.org/W2554116253","https://openalex.org/W2395608011","https://openalex.org/W1560208380","https://openalex.org/W1966881731","https://openalex.org/W2062465803","https://openalex.org/W2771662354","https://openalex.org/W4406787924","https://openalex.org/W851712841","https://openalex.org/W2052198557","https://openalex.org/W2893247729"],"abstract_inverted_index":{"The":[0,173],"growing":[1],"need":[2],"for":[3,13,36,74,111,233,270,275],"global":[4],"volatile":[5],"organic":[6],"compounds":[7],"(VOC)":[8],"data":[9,63],"at":[10,77,107],"trace":[11],"level":[12],"industrial":[14],"applications,":[15],"domestic":[16],"and":[17,22,33,105,137,150,183,190,209,239,245,259,272],"working":[18],"health,":[19],"air":[20,139],"quality":[21,64],"climate":[23],"change":[24],"is":[25,206],"driving":[26],"research":[27],"towards":[28],"the":[29,37,130,158,170,176,255],"preparation":[30],"of":[31,40,79,103,126,129,143,157,161,175,203],"traceable":[32],"accurate":[34,278],"standards":[35],"VOC":[38,54,75,145,159,177,204,234],"amount":[39,78,125,160],"substance":[41,80,127,162],"fraction":[42,128,163],"in":[43,91,166],"gas":[44,94,167],"phase.The":[45],"World":[46],"Meteorological":[47],"Organization":[48],"(WMO)":[49],"has":[50,193],"implemented":[51],"a":[52,123,191,200,212,215],"worldwide":[53],"monitoring":[55],"programme,":[56],"named":[57],"Global":[58],"Atmosphere":[59],"Watch":[60],"(GAW),":[61],"which":[62,276],"objectives":[65],"refer":[66],"to":[67,121,148,179,211,229,237,287,292],"an":[68,119,221],"expanded":[69],"uncertainty":[70,182,225,232],"lower":[71,82],"than":[72,83],"10%":[73],"measurement":[76],"fractions":[81],"100":[84],"nmol\u2219mol\u22121.Currently,":[85],"gaseous":[86],"standard":[87,180],"atmospheres":[88],"are":[89,116,187,280],"prepared":[90,165,228],"high":[92],"pressure":[93],"cylinders,":[95],"but":[96],"they":[97],"do":[98],"not":[99,194,264,268],"fulfil":[100],"GAW":[101],"requirements":[102],"accuracy":[104],"stability":[106],"ppb":[108],"level,":[109],"especially":[110],"oxygenated":[112],"VOCs.":[113],"Dynamic":[114],"methods":[115],"proposed":[117],"as":[118,154],"alternative":[120],"provide":[122],"stable":[124],"mixture":[131],"over":[132],"time.":[133],"Diffusion":[134],"rate,":[135],"dilution":[136],"carrier":[138],"flow":[140],"rates,":[141],"purity":[142],"air,":[144],"losses":[146,178,205,235],"due":[147,236],"wall-interactions":[149],"leakages":[151,238],"were":[152,263],"considered":[153],"influence":[155],"quantities":[156],"dynamically":[164],"phase":[168],"by":[169],"diffusion":[171],"method.":[172],"contribution":[174,291],"mixtures":[181],"their":[184],"sampling":[185],"procedure":[186],"under":[188],"study":[189],"solution":[192],"yet":[195],"been":[196],"proposed.In":[197],"this":[198],"paper,":[199],"conservative":[201],"quantification":[202],"proposed,":[207],"discussed":[208],"applied":[210],"case":[213],"study:":[214],"single":[216],"stage":[217],"dynamic":[218],"dilutor":[219],"with":[220],"acetone":[222],"generation.":[223],"An":[224],"budget":[226],"was":[227,257,267,285],"calculate":[230],"target":[231],"VOC\u2013wall":[240],"interactions":[241],"on":[242],"Teflon\u00ae,":[243],"Pyrex\u00ae":[244],"stainless":[246,273],"steel":[247,274],"tubing.":[248],"Teflon\u00ae":[249],"showed":[250],"negligible":[251,269,289],"interaction":[252],"effects":[253,262],"when":[254],"pipe":[256],"clean":[258],"long":[260],"term":[261],"considered.":[265],"Uncertainty":[266],"glass":[271],"more":[277],"analyses":[279],"necessary.":[281],"A":[282],"leakage":[283,290],"test":[284],"developed":[286],"assure":[288],"uncertainty.":[293]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":1}],"updated_date":"2026-10-06T10:28:23.643775","created_date":"2016-06-24T00:00:00"}