{"id":"https://openalex.org/W2064801469","doi":"https://doi.org/10.1080/00958979608028171","title":"TRANSITION METAL COMPLEXES WITH THIOSEMICARBAZIDE-BASED LIGANDS. PART 28. SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF THE FIRST PHOSPHORUS-BONDED THIOSEMICARBAZIDE COMPLEX: [2-(DIPHENYLPHOSPHINO) BENZALDEHYDE THIOSEMICARBAZONATO(1-)] PYRIDINENICKEL(II)-NITRATE","display_name":"TRANSITION METAL COMPLEXES WITH THIOSEMICARBAZIDE-BASED LIGANDS. PART 28. SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF THE FIRST PHOSPHORUS-BONDED THIOSEMICARBAZIDE COMPLEX: [2-(DIPHENYLPHOSPHINO) BENZALDEHYDE THIOSEMICARBAZONATO(1-)] PYRIDINENICKEL(II)-NITRATE","publication_year":1996,"publication_date":"1996-07-01","ids":{"openalex":"https://openalex.org/W2064801469","doi":"https://doi.org/10.1080/00958979608028171","mag":"2064801469"},"language":"en","primary_location":{"id":"doi:10.1080/00958979608028171","doi":"https://doi.org/10.1080/00958979608028171","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00958979608028171","pdf_url":null,"source":{"id":"https://openalex.org/S161439912","display_name":"Journal of Coordination Chemistry","issn_l":"0095-8972","issn":["0095-8972","1026-7441","1029-0389"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Coordination Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5063698459","display_name":"Vukadin M. Leovac","orcid":"https://orcid.org/0000-0003-3551-6034","observed_orcids":["https://orcid.org/0000-0003-3551-6034"]},"institutions":[{"id":"https://openalex.org/I170726198","display_name":"University of Novi Sad","ror":"https://ror.org/00xa57a59","country_code":"RS","type":"education","lineage":["https://openalex.org/I170726198"]}],"countries":["RS"],"is_corresponding":false,"raw_author_name":"Vukadin M. Leovac","raw_affiliation_strings":["Faculty of Sciences, Trg. D. Obradovica, 3, 21000, Novi Sad, Yugoslavia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Sciences, Trg. D. Obradovica, 3, 21000, Novi Sad, Yugoslavia","institution_ids":["https://openalex.org/I170726198"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5083596418","display_name":"\u0392. Rib\u00e1r","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I170726198","display_name":"University of Novi Sad","ror":"https://ror.org/00xa57a59","country_code":"RS","type":"education","lineage":["https://openalex.org/I170726198"]}],"countries":["RS"],"is_corresponding":false,"raw_author_name":"B\u00e9la Rib\u00e1r","raw_affiliation_strings":["Faculty of Sciences, Trg. D. Obradovica, 3, 21000, Novi Sad, Yugoslavia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Sciences, Trg. D. Obradovica, 3, 21000, Novi Sad, Yugoslavia","institution_ids":["https://openalex.org/I170726198"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038676526","display_name":"Gyula Argay","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I7597260","display_name":"Hungarian Academy of Sciences","ror":"https://ror.org/02ks8qq67","country_code":"HU","type":"government","lineage":["https://openalex.org/I7597260"]}],"countries":["HU"],"is_corresponding":false,"raw_author_name":"Gyula Argay","raw_affiliation_strings":["Central Research Institute of Chemistry, Hungarian Academy of Sciences, Budapest-114, P.O. Box 17, H-1525, Hungary"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Central Research Institute of Chemistry, Hungarian Academy of Sciences, Budapest-114, P.O. Box 17, H-1525, Hungary","institution_ids":["https://openalex.org/I7597260"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110157040","display_name":"Alajos K\u00e1lm\u00e1n","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I7597260","display_name":"Hungarian Academy of Sciences","ror":"https://ror.org/02ks8qq67","country_code":"HU","type":"government","lineage":["https://openalex.org/I7597260"]}],"countries":["HU"],"is_corresponding":false,"raw_author_name":"Alajos K\u00e1lm\u00e1n","raw_affiliation_strings":["Central Research Institute of Chemistry, Hungarian Academy of Sciences, Budapest-114, P.O. Box 17, H-1525, Hungary"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Central Research Institute of Chemistry, Hungarian Academy of Sciences, Budapest-114, P.O. Box 17, H-1525, Hungary","institution_ids":["https://openalex.org/I7597260"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5049216753","display_name":"Ilija Br\u010deski","orcid":"https://orcid.org/0000-0001-6537-6840","observed_orcids":["https://orcid.org/0000-0001-6537-6840"]},"institutions":[{"id":"https://openalex.org/I4068193","display_name":"University of Belgrade","ror":"https://ror.org/02qsmb048","country_code":"RS","type":"education","lineage":["https://openalex.org/I4068193"]}],"countries":["RS"],"is_corresponding":false,"raw_author_name":"Ilija Br\u010deski","raw_affiliation_strings":["Faculty of Chemistry, University of Belgrade, Studenski Trg. 16, P.O. Box, 550, Belgrade, Yugoslavia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, University of Belgrade, Studenski Trg. 16, P.O. Box, 550, Belgrade, Yugoslavia","institution_ids":["https://openalex.org/I4068193"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":16,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":95},"biblio":{"volume":"39","issue":"1","first_page":"11","last_page":"19"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.9814000129699707,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.9814000129699707,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.004699999932199717,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.0024999999441206455,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/nickel-ii-complexes","display_name":"nickel(II) complexes","score":0.9100000262260437},{"id":"https://openalex.org/keywords/thiosemicarbazide-ligands","display_name":"thiosemicarbazide ligands","score":0.9589999914169312},{"id":"https://openalex.org/keywords/thiosemicarbazones","display_name":"thiosemicarbazones","score":0.7760000228881836},{"id":"https://openalex.org/keywords/phosphorus-nitrogen-double-bond","display_name":"phosphorus-nitrogen double bond","score":0.5559999942779541},{"id":"https://openalex.org/keywords/tridentate-coordination","display_name":"tridentate coordination","score":0.7960000038146973},{"id":"https://openalex.org/keywords/pyridine-ligands","display_name":"pyridine ligands","score":0.7310000061988831},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.8500000238418579},{"id":"https://openalex.org/keywords/coordination-geometry","display_name":"coordination geometry","score":0.42100000381469727}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9476767778396606},{"id":"https://openalex.org/C2779692420","wikidata":"https://www.wikidata.org/wiki/Q372524","display_name":"Benzaldehyde","level":3,"score":0.8708046078681946},{"id":"https://openalex.org/C83591994","wikidata":"https://www.wikidata.org/wiki/Q416105","display_name":"Semicarbazone","level":2,"score":0.7958608269691467},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6816951036453247},{"id":"https://openalex.org/C118629725","wikidata":"https://www.wikidata.org/wiki/Q2686738","display_name":"Deprotonation","level":3,"score":0.6782041788101196},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5822033882141113},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.549614429473877},{"id":"https://openalex.org/C2779485729","wikidata":"https://www.wikidata.org/wiki/Q210385","display_name":"Pyridine","level":2,"score":0.4944894313812256},{"id":"https://openalex.org/C158842870","wikidata":"https://www.wikidata.org/wiki/Q6125309","display_name":"Pentagonal bipyramidal molecular geometry","level":3,"score":0.4151662588119507},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.36677733063697815},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3592912554740906},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.33272361755371094},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.16900300979614258},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08410066366195679},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.06177237629890442},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1080/00958979608028171","doi":"https://doi.org/10.1080/00958979608028171","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00958979608028171","pdf_url":null,"source":{"id":"https://openalex.org/S161439912","display_name":"Journal of Coordination Chemistry","issn_l":"0095-8972","issn":["0095-8972","1026-7441","1029-0389"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Coordination Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:cherry.chem.bg.ac.rs:123456789/2245","doi":null,"is_oa":false,"landing_page_url":"https://cherry.chem.bg.ac.rs/handle/123456789/2245","pdf_url":null,"source":{"id":"https://openalex.org/S4306402516","display_name":"Cherry (Univesrity of Belgrade, Faculty of Chemistry)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210101313","host_organization_name":"University Hospital Center Dr Dragi\u0161a Mi\u0161ovi\u0107","host_organization_lineage":["https://openalex.org/I4210101313"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of Coordination Chemistry","raw_type":"article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":14,"referenced_works":["https://openalex.org/W1897085524","https://openalex.org/W1984611145","https://openalex.org/W1998722626","https://openalex.org/W2041934180","https://openalex.org/W2046208515","https://openalex.org/W2056245309","https://openalex.org/W2078123855","https://openalex.org/W2078931912","https://openalex.org/W2087754183","https://openalex.org/W2101748147","https://openalex.org/W2114105486","https://openalex.org/W2148066840","https://openalex.org/W2236469781","https://openalex.org/W4229925216"],"related_works":["https://openalex.org/W2078931912","https://openalex.org/W2090991354","https://openalex.org/W1994034580","https://openalex.org/W2035878853","https://openalex.org/W2733940541","https://openalex.org/W4200340172","https://openalex.org/W2011723031","https://openalex.org/W2075201082","https://openalex.org/W1024668842","https://openalex.org/W1976084689"],"abstract_inverted_index":{"The":[0,24,73,95,107],"synthesis":[1],"and":[2,103],"crystal":[3],"structure":[4],"analysis":[5],"of":[6,15,75,98,124],"the":[7,13,16,28,57,76,99,115,121,125],"diamagnetic":[8],"complex":[9,25],"[Ni(L)Py]NO3":[10],"(L":[11],"=":[12,36,39,42,46,49],"monoanion":[14],"newly":[17],"synthesized":[18],"ligand":[19,60],"2-(diphenylphosphino)benzaldehyde":[20,58],"thiosemicarbazone)":[21],"are":[22,111],"reported.":[23],"crystallizes":[26],"in":[27],"space":[29],"group":[30],"P21/n":[31],"(No.":[32],"14)":[33],"with":[34],"a":[35,66,81,92],"8.533(1),":[37],"b":[38],"29.123(3),":[40],"c":[41],"10.627(a)":[43],"\u00c5,":[44],"\u03b2":[45],"100.36(1)\u00b0,":[47],"V":[48],"2597.8(5)":[50],"\u00c53.":[51],"As":[52],"revealed":[53],"by":[54,88,91],"X-ray":[55],"analysis,":[56],"thiosemicarbazone":[59],"deprotonated":[61],"at":[62],"N(3)":[63],"acts":[64],"as":[65],"monoanionic":[67],"tridentate":[68],"donor,":[69],"coordinating":[70],"through":[71],"SNP.":[72],"core":[74],"bulky":[77],"{Ni[(C6H5)2P-(C6H4CH=N-N=CS-NH2)\u00b7]}+":[78],"cation":[79],"is":[80,105],"slightly":[82],"puckered":[83],"quadrangle":[84],"formed":[85],"around":[86],"Ni2+":[87],"SNP":[89],"accompanied":[90],"pyridine":[93],"nitrogen.":[94],"dihedral":[96],"angle":[97],"atomic":[100],"triangles":[101],"S/N(4)/N(41)":[102],"P(2)/N(4)/N(41)":[104],"18.0(4)\u00b0.":[106],"NO3":[108],"\u2212":[109],"anions":[110],"well":[112],"separated":[113],"from":[114],"cations":[116],"which":[117],"may":[118],"account":[119],"for":[120],"observed":[122],"disorder":[123],"oxygen":[126],"atoms.":[127]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}