{"id":"https://openalex.org/W2061689331","doi":"https://doi.org/10.1021/jo300963m","title":"meso-Arylporpholactones and their Reduction Products","display_name":"meso-Arylporpholactones and their Reduction Products","publication_year":2012,"publication_date":"2012-06-27","ids":{"openalex":"https://openalex.org/W2061689331","doi":"https://doi.org/10.1021/jo300963m","mag":"2061689331","pmid":"https://pubmed.ncbi.nlm.nih.gov/22734444","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/3411881"},"language":"en","primary_location":{"id":"doi:10.1021/jo300963m","doi":"https://doi.org/10.1021/jo300963m","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo300963m","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"http://europepmc.org/articles/PMC3411881","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5089718436","display_name":"Christian Br\u00fcckner","orcid":"https://orcid.org/0000-0002-1560-7345","observed_orcids":["https://orcid.org/0000-0002-1560-7345"]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Christian Br\u00fcckner","raw_affiliation_strings":["Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States","institution_ids":["https://openalex.org/I140172145"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5059604144","display_name":"Junichi Ogikubo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Junichi Ogikubo","raw_affiliation_strings":["Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States","institution_ids":["https://openalex.org/I140172145"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005270186","display_name":"Jason R. McCarthy","orcid":"https://orcid.org/0000-0002-5302-2030","observed_orcids":["https://orcid.org/0000-0002-5302-2030"]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jason R. McCarthy","raw_affiliation_strings":["Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States","institution_ids":["https://openalex.org/I140172145"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020991195","display_name":"Joshua O. Akhigbe","orcid":"https://orcid.org/0000-0002-6805-8810","observed_orcids":["https://orcid.org/0000-0002-6805-8810"]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Joshua Akhigbe","raw_affiliation_strings":["Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States","institution_ids":["https://openalex.org/I140172145"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068709754","display_name":"Michael A. Hyland","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Michael A. Hyland","raw_affiliation_strings":["Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States","institution_ids":["https://openalex.org/I140172145"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071640366","display_name":"Pedro Daddario","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Pedro Daddario","raw_affiliation_strings":["Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States","institution_ids":["https://openalex.org/I140172145"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5048933984","display_name":"Jill L. Worlinsky","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jill L. Worlinsky","raw_affiliation_strings":["Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States","institution_ids":["https://openalex.org/I140172145"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025944326","display_name":"Mat\u00adthias Zeller","orcid":"https://orcid.org/0000-0002-3305-852X","observed_orcids":["https://orcid.org/0000-0002-3305-852X"]},"institutions":[{"id":"https://openalex.org/I161203489","display_name":"Youngstown State University","ror":"https://ror.org/038zf2n28","country_code":"US","type":"education","lineage":["https://openalex.org/I161203489"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Matthias Zeller","raw_affiliation_strings":["Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, Ohio 44555-3663, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, Ohio 44555-3663, United States","institution_ids":["https://openalex.org/I161203489"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5083096773","display_name":"James T. Engle","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I110152177","display_name":"University of Akron","ror":"https://ror.org/02kyckx55","country_code":"US","type":"education","lineage":["https://openalex.org/I110152177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James T. Engle","raw_affiliation_strings":["Department of Chemistry, University of Akron, Akron, Ohio 44325-3601, United\rStates","Department of Chemistry, University of Akron, Akron, Ohio 44325-3601, United#R#States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Akron, Akron, Ohio 44325-3601, United\rStates","institution_ids":["https://openalex.org/I110152177"]},{"raw_affiliation_string":"Department of Chemistry, University of Akron, Akron, Ohio 44325-3601, United#R#States","institution_ids":["https://openalex.org/I110152177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020817205","display_name":"Christopher J. Ziegler","orcid":"https://orcid.org/0000-0002-0142-5161","observed_orcids":["https://orcid.org/0000-0002-0142-5161"]},"institutions":[{"id":"https://openalex.org/I110152177","display_name":"University of Akron","ror":"https://ror.org/02kyckx55","country_code":"US","type":"education","lineage":["https://openalex.org/I110152177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Christopher J. Ziegler","raw_affiliation_strings":["Department of Chemistry, University of Akron, Akron, Ohio 44325-3601, United\rStates","Department of Chemistry, University of Akron, Akron, Ohio 44325-3601, United#R#States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Akron, Akron, Ohio 44325-3601, United\rStates","institution_ids":["https://openalex.org/I110152177"]},{"raw_affiliation_string":"Department of Chemistry, University of Akron, Akron, Ohio 44325-3601, United#R#States","institution_ids":["https://openalex.org/I110152177"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5091036930","display_name":"Matthew J. Ranaghan","orcid":"https://orcid.org/0000-0003-3572-5127","observed_orcids":["https://orcid.org/0000-0003-3572-5127"]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Matthew J. Ranaghan","raw_affiliation_strings":["Department\rof Molecular and\rCell Biology, University of Connecticut, Storrs, Connecticut 06269-3125, United States","Department#R#of Molecular and#R#Cell Biology, University of Connecticut, Storrs, Connecticut 06269-3125, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Molecular and\rCell Biology, University of Connecticut, Storrs, Connecticut 06269-3125, United States","institution_ids":["https://openalex.org/I140172145"]},{"raw_affiliation_string":"Department#R#of Molecular and#R#Cell Biology, University of Connecticut, Storrs, Connecticut 06269-3125, United States","institution_ids":["https://openalex.org/I140172145"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5063484657","display_name":"Megan N. Sandberg","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Megan N. Sandberg","raw_affiliation_strings":["Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States","institution_ids":["https://openalex.org/I140172145"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5110429982","display_name":"Robert R. Birge","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Robert R. Birge","raw_affiliation_strings":["Department\rof Molecular and\rCell Biology, University of Connecticut, Storrs, Connecticut 06269-3125, United States","Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060,\rUnited States","Department#R#of Molecular and#R#Cell Biology, University of Connecticut, Storrs, Connecticut 06269-3125, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Molecular and\rCell Biology, University of Connecticut, Storrs, Connecticut 06269-3125, United States","institution_ids":["https://openalex.org/I140172145"]},{"raw_affiliation_string":"Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060,\rUnited States","institution_ids":["https://openalex.org/I140172145"]},{"raw_affiliation_string":"Department#R#of Molecular and#R#Cell Biology, University of Connecticut, Storrs, Connecticut 06269-3125, United States","institution_ids":["https://openalex.org/I140172145"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5089718436"],"corresponding_institution_ids":["https://openalex.org/I140172145"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.0869,"has_fulltext":false,"cited_by_count":69,"citation_normalized_percentile":{"value":0.92458777,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"77","issue":"15","first_page":"6480","last_page":"6494"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10957","display_name":"Photodynamic Therapy Research Studies","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2740","display_name":"Pulmonary and Respiratory Medicine"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T12441","display_name":"Porphyrin Metabolism and Disorders","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chlorins","display_name":"chlorins","score":0.671999990940094},{"id":"https://openalex.org/keywords/permanganate-oxidation","display_name":"potassium permanganate oxidation","score":0.8550000190734863},{"id":"https://openalex.org/keywords/nucleophilic-substitution","display_name":"nucleophilic substitution","score":0.8519999980926514},{"id":"https://openalex.org/keywords/photophysical-properties","display_name":"photophysical properties","score":0.9409999847412109},{"id":"https://openalex.org/keywords/q-band-red-shift","display_name":"Q-band red shift","score":0.7009999752044678},{"id":"https://openalex.org/keywords/oscillator-strengths","display_name":"oscillator strengths","score":0.6729999780654907},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.6639999747276306},{"id":"https://openalex.org/keywords/steric-interactions","display_name":"steric interactions","score":0.675000011920929}],"concepts":[{"id":"https://openalex.org/C111335779","wikidata":"https://www.wikidata.org/wiki/Q3454686","display_name":"Reduction (mathematics)","level":2,"score":0.6772558093070984},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.3338102698326111},{"id":"https://openalex.org/C144133560","wikidata":"https://www.wikidata.org/wiki/Q4830453","display_name":"Business","level":0,"score":0.3244941532611847},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.19559600949287415},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D007783","descriptor_name":"Lactones","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D007783","descriptor_name":"Lactones","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D008958","descriptor_name":"Models, Molecular","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010084","descriptor_name":"Oxidation-Reduction","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D015394","descriptor_name":"Molecular Structure","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D018360","descriptor_name":"Crystallography, X-Ray","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":4,"locations":[{"id":"doi:10.1021/jo300963m","doi":"https://doi.org/10.1021/jo300963m","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo300963m","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},{"id":"pmid:22734444","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/22734444","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of organic chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:europepmc.org:2725019","doi":null,"is_oa":true,"landing_page_url":"http://europepmc.org/articles/PMC3411881","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"","raw_type":"Text"},{"id":"pmh:oai:pubmedcentral.nih.gov:3411881","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/3411881","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"J Org Chem","raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:europepmc.org:2725019","doi":null,"is_oa":true,"landing_page_url":"http://europepmc.org/articles/PMC3411881","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"","raw_type":"Text"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"score":0.44999998807907104,"display_name":"Clean water and sanitation","id":"https://metadata.un.org/sdg/6"}],"study_designs":[],"awards":[{"id":"https://openalex.org/G1247865617","display_name":"Photobiology of Rhodopsin and the Cone Pigments","funder_award_id":"R01GM034548","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G6466440037","display_name":null,"funder_award_id":"GM 34548","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"}],"funders":[{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":73,"referenced_works":["https://openalex.org/W61540687","https://openalex.org/W411954668","https://openalex.org/W1002288058","https://openalex.org/W1825789202","https://openalex.org/W1964034779","https://openalex.org/W1964315121","https://openalex.org/W1970706879","https://openalex.org/W1971642455","https://openalex.org/W1973345678","https://openalex.org/W1980999313","https://openalex.org/W1985385791","https://openalex.org/W1985517366","https://openalex.org/W1985523318","https://openalex.org/W1991510021","https://openalex.org/W1994708118","https://openalex.org/W1997061528","https://openalex.org/W1998148469","https://openalex.org/W2001370442","https://openalex.org/W2004382175","https://openalex.org/W2007525857","https://openalex.org/W2009387794","https://openalex.org/W2011067524","https://openalex.org/W2014832811","https://openalex.org/W2016853567","https://openalex.org/W2017469586","https://openalex.org/W2017482212","https://openalex.org/W2019557881","https://openalex.org/W2019923061","https://openalex.org/W2020506262","https://openalex.org/W2021193306","https://openalex.org/W2028883774","https://openalex.org/W2029002065","https://openalex.org/W2033461657","https://openalex.org/W2036271518","https://openalex.org/W2039814463","https://openalex.org/W2047626962","https://openalex.org/W2049061162","https://openalex.org/W2054439090","https://openalex.org/W2060433251","https://openalex.org/W2066594522","https://openalex.org/W2067602128","https://openalex.org/W2069327909","https://openalex.org/W2069563350","https://openalex.org/W2070702169","https://openalex.org/W2073813230","https://openalex.org/W2079494194","https://openalex.org/W2089676926","https://openalex.org/W2091663124","https://openalex.org/W2091881016","https://openalex.org/W2093871271","https://openalex.org/W2101326641","https://openalex.org/W2111911787","https://openalex.org/W2113305715","https://openalex.org/W2114111609","https://openalex.org/W2121293249","https://openalex.org/W2123789809","https://openalex.org/W2127603974","https://openalex.org/W2134295461","https://openalex.org/W2136613480","https://openalex.org/W2137952320","https://openalex.org/W2162335948","https://openalex.org/W2169143876","https://openalex.org/W2171897590","https://openalex.org/W2313198442","https://openalex.org/W2333065922","https://openalex.org/W2400950971","https://openalex.org/W2479260091","https://openalex.org/W2491055736","https://openalex.org/W2951314039","https://openalex.org/W2952292372","https://openalex.org/W2953266253","https://openalex.org/W4252839946","https://openalex.org/W4376849570"],"related_works":["https://openalex.org/W2314842424","https://openalex.org/W2039839565","https://openalex.org/W1980526522","https://openalex.org/W2952118788","https://openalex.org/W108167678","https://openalex.org/W1977360671","https://openalex.org/W3020821546","https://openalex.org/W1964034779","https://openalex.org/W2073161415","https://openalex.org/W2102251335"],"abstract_inverted_index":{"The":[0,45,64,80,130,153],"rational":[1],"syntheses":[2],"of":[3,12,35,48,56,66,84,88,122,135,157,176],"meso-tetraaryl-3-oxo-2-oxaporphyrins":[4],"5,":[5],"known":[6],"as":[7],"porpholactones,":[8],"via":[9],"MnO(4)(-)-mediated":[10],"oxidations":[11],"the":[13,25,49,54,85,104,120,136,145,149,166,172,177],"corresponding":[14],"meso-tetraaryl-2,3-dihydroxychlorins":[15],"(7)":[16],"is":[17,22,78],"detailed.":[18],"Since":[19],"chlorin":[20,57],"7":[21],"prepared":[23],"from":[24,171],"parent":[26,105],"porphyrin":[27],"1,":[28],"this":[29],"amounts":[30],"to":[31,70,183],"a":[32,36,89,140],"2-step":[33],"replacement":[34,87],"pyrrole":[37,90],"moiety":[38,99],"in":[39,53,160],"1":[40],"by":[41,73],"an":[42,92],"oxazolone":[43,93],"moiety.":[44],"stepwise":[46],"reduction":[47],"porpholactone":[50],"5":[51],"results":[52],"formation":[55],"analogues,":[58],"meso-tetraaryl-3-hydroxy-2-oxachlorin":[59],"(11)":[60],"and":[61,76,117,124,148,179],"meso-tetraaryl-2-oxachlorins":[62],"(12).":[63],"reactivity":[65],"11":[67],"with":[68,91,111],"respect":[69],"nucleophilic":[71],"substitution":[72],"O-,":[74],"N-,":[75],"S-nucleophiles":[77],"described.":[79],"profound":[81],"photophysical":[82],"consequences":[83],"formal":[86],"(porphyrin-like":[94],"chromophore)":[95],"or":[96],"(substituted)":[97],"oxazole":[98],"(chlorin-like":[100],"chromophore":[101],"with,":[102],"for":[103],"oxazolochlorin":[106],"12,":[107],"red-shifted":[108],"Q(x)":[109],"band":[110],"enhanced":[112],"oscillator":[113],"strengths)":[114],"are":[115,180],"detailed":[116],"rationalized":[118],"on":[119],"basis":[121],"SAC-CI":[123],"MNDO-PSDCI":[125],"molecular":[126],"orbital":[127],"theory":[128],"calculations.":[129],"single":[131],"crystal":[132],"X-ray":[133],"structures":[134,156],"porpholactones":[137],"point":[138],"at":[139],"minor":[141],"steric":[142],"interaction":[143],"between":[144],"carbonyl":[146],"oxygen":[147],"flanking":[150],"phenyl":[151],"group.":[152],"essentially":[154],"planar":[155],"all":[158,161],"chromophores":[159,178],"oxidation":[162],"states":[163],"prove":[164],"that":[165],"observed":[167],"optical":[168],"properties":[169,175],"originate":[170],"intrinsic":[173],"electronic":[174],"not":[181],"subject":[182],"conformational":[184],"modulation.":[185]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":4},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":5},{"year":2020,"cited_by_count":6},{"year":2019,"cited_by_count":4},{"year":2018,"cited_by_count":5},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":12},{"year":2015,"cited_by_count":5},{"year":2014,"cited_by_count":7},{"year":2013,"cited_by_count":8},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}
