{"id":"https://openalex.org/W2060175615","doi":"https://doi.org/10.1021/ja035434j","title":"Polyyn-diyls Capped by Diruthenium Termini: A New Family of Carbon-Rich Organometallic Compounds and Distance-Dependent Electronic Coupling Therein","display_name":"Polyyn-diyls Capped by Diruthenium Termini: A New Family of Carbon-Rich Organometallic Compounds and Distance-Dependent Electronic Coupling Therein","publication_year":2003,"publication_date":"2003-07-25","ids":{"openalex":"https://openalex.org/W2060175615","doi":"https://doi.org/10.1021/ja035434j","mag":"2060175615","pmid":"https://pubmed.ncbi.nlm.nih.gov/12914469"},"language":"en","primary_location":{"id":"doi:10.1021/ja035434j","doi":"https://doi.org/10.1021/ja035434j","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja035434j","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5102902562","display_name":"Guolin Xu","orcid":"https://orcid.org/0000-0001-6230-4454","observed_orcids":["https://orcid.org/0000-0001-6230-4454"]},"institutions":[{"id":"https://openalex.org/I145608581","display_name":"University of Miami","ror":"https://ror.org/02dgjyy92","country_code":"US","type":"education","lineage":["https://openalex.org/I145608581"]},{"id":"https://openalex.org/I67031392","display_name":"Carleton University","ror":"https://ror.org/02qtvee93","country_code":"CA","type":"education","lineage":["https://openalex.org/I67031392"]}],"countries":["CA","US"],"is_corresponding":false,"raw_author_name":"Guo-Lin Xu","raw_affiliation_strings":["Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada","institution_ids":["https://openalex.org/I145608581","https://openalex.org/I67031392"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020387219","display_name":"Gang Zou","orcid":"https://orcid.org/0000-0002-1313-648X","observed_orcids":["https://orcid.org/0000-0002-1313-648X"]},"institutions":[{"id":"https://openalex.org/I145608581","display_name":"University of Miami","ror":"https://ror.org/02dgjyy92","country_code":"US","type":"education","lineage":["https://openalex.org/I145608581"]},{"id":"https://openalex.org/I67031392","display_name":"Carleton University","ror":"https://ror.org/02qtvee93","country_code":"CA","type":"education","lineage":["https://openalex.org/I67031392"]}],"countries":["CA","US"],"is_corresponding":false,"raw_author_name":"Gang Zou","raw_affiliation_strings":["Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada","institution_ids":["https://openalex.org/I145608581","https://openalex.org/I67031392"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020150478","display_name":"Yuhua Ni","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I145608581","display_name":"University of Miami","ror":"https://ror.org/02dgjyy92","country_code":"US","type":"education","lineage":["https://openalex.org/I145608581"]},{"id":"https://openalex.org/I67031392","display_name":"Carleton University","ror":"https://ror.org/02qtvee93","country_code":"CA","type":"education","lineage":["https://openalex.org/I67031392"]}],"countries":["CA","US"],"is_corresponding":false,"raw_author_name":"Yu-Hua Ni","raw_affiliation_strings":["Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada","institution_ids":["https://openalex.org/I145608581","https://openalex.org/I67031392"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5066891093","display_name":"Maria C. DeRosa","orcid":"https://orcid.org/0000-0003-1868-6357","observed_orcids":["https://orcid.org/0000-0003-1868-6357"]},"institutions":[{"id":"https://openalex.org/I145608581","display_name":"University of Miami","ror":"https://ror.org/02dgjyy92","country_code":"US","type":"education","lineage":["https://openalex.org/I145608581"]},{"id":"https://openalex.org/I67031392","display_name":"Carleton University","ror":"https://ror.org/02qtvee93","country_code":"CA","type":"education","lineage":["https://openalex.org/I67031392"]}],"countries":["CA","US"],"is_corresponding":false,"raw_author_name":"Maria C. DeRosa","raw_affiliation_strings":["Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada","institution_ids":["https://openalex.org/I145608581","https://openalex.org/I67031392"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5056205193","display_name":"Robert J. Crutchley","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I145608581","display_name":"University of Miami","ror":"https://ror.org/02dgjyy92","country_code":"US","type":"education","lineage":["https://openalex.org/I145608581"]},{"id":"https://openalex.org/I67031392","display_name":"Carleton University","ror":"https://ror.org/02qtvee93","country_code":"CA","type":"education","lineage":["https://openalex.org/I67031392"]}],"countries":["CA","US"],"is_corresponding":false,"raw_author_name":"Robert J. Crutchley","raw_affiliation_strings":["Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada","institution_ids":["https://openalex.org/I145608581","https://openalex.org/I67031392"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5059304767","display_name":"Tong Ren","orcid":"https://orcid.org/0000-0002-1148-0746","observed_orcids":["https://orcid.org/0000-0002-1148-0746"]},"institutions":[{"id":"https://openalex.org/I145608581","display_name":"University of Miami","ror":"https://ror.org/02dgjyy92","country_code":"US","type":"education","lineage":["https://openalex.org/I145608581"]},{"id":"https://openalex.org/I67031392","display_name":"Carleton University","ror":"https://ror.org/02qtvee93","country_code":"CA","type":"education","lineage":["https://openalex.org/I67031392"]}],"countries":["CA","US"],"is_corresponding":false,"raw_author_name":"Tong Ren","raw_affiliation_strings":["Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida 33146, and Department of Chemistry, Carleton University, Ottawa, ON K1S 5B6, Canada","institution_ids":["https://openalex.org/I145608581","https://openalex.org/I67031392"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":11.1846,"has_fulltext":false,"cited_by_count":190,"citation_normalized_percentile":{"value":0.99495171,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"125","issue":"33","first_page":"10057","last_page":"10065"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.375,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.375,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.17329999804496765,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.05550000071525574,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/dinuclear-ruthenium-complexes","display_name":"dinuclear ruthenium complexes","score":0.8759999871253967},{"id":"https://openalex.org/keywords/donor-acceptor-systems","display_name":"donor-acceptor systems","score":0.8190000057220459},{"id":"https://openalex.org/keywords/metathesis","display_name":"metathesis","score":0.578000009059906},{"id":"https://openalex.org/keywords/spectroelectrochemistry","display_name":"spectroelectrochemistry","score":0.7580000162124634},{"id":"https://openalex.org/keywords/redox-properties","display_name":"redox properties","score":0.44200000166893005}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9146302938461304},{"id":"https://openalex.org/C153914509","wikidata":"https://www.wikidata.org/wiki/Q191090","display_name":"Metathesis","level":4,"score":0.6609000563621521},{"id":"https://openalex.org/C2779892579","wikidata":"https://www.wikidata.org/wiki/Q912138","display_name":"Acceptor","level":2,"score":0.567279577255249},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.45928430557250977},{"id":"https://openalex.org/C131584629","wikidata":"https://www.wikidata.org/wiki/Q4308705","display_name":"Coupling (piping)","level":2,"score":0.45310115814208984},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4514235854148865},{"id":"https://openalex.org/C91967747","wikidata":"https://www.wikidata.org/wiki/Q2770033","display_name":"Group 2 organometallic chemistry","level":3,"score":0.42745715379714966},{"id":"https://openalex.org/C184720557","wikidata":"https://www.wikidata.org/wiki/Q7825049","display_name":"Topology (electrical circuits)","level":2,"score":0.3666021525859833},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.2645021080970764},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.14447081089019775},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.07726463675498962},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0},{"id":"https://openalex.org/C26873012","wikidata":"https://www.wikidata.org/wiki/Q214781","display_name":"Condensed matter physics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C114614502","wikidata":"https://www.wikidata.org/wiki/Q76592","display_name":"Combinatorics","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C78519656","wikidata":"https://www.wikidata.org/wiki/Q101333","display_name":"Mechanical engineering","level":1,"score":0.0},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ja035434j","doi":"https://doi.org/10.1021/ja035434j","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja035434j","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:12914469","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/12914469","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":81,"referenced_works":["https://openalex.org/W32310619","https://openalex.org/W213791877","https://openalex.org/W274377105","https://openalex.org/W306089196","https://openalex.org/W567644629","https://openalex.org/W1492841978","https://openalex.org/W1516949595","https://openalex.org/W1535944448","https://openalex.org/W1602932472","https://openalex.org/W1691067281","https://openalex.org/W1835764176","https://openalex.org/W1968732229","https://openalex.org/W1971944253","https://openalex.org/W1973779222","https://openalex.org/W1974599100","https://openalex.org/W1975879685","https://openalex.org/W1976881666","https://openalex.org/W1977790529","https://openalex.org/W1981881531","https://openalex.org/W1982011836","https://openalex.org/W1987460080","https://openalex.org/W1989555721","https://openalex.org/W1996328691","https://openalex.org/W1996370883","https://openalex.org/W1997133305","https://openalex.org/W1998035594","https://openalex.org/W2000806165","https://openalex.org/W2000862731","https://openalex.org/W2002268476","https://openalex.org/W2004969995","https://openalex.org/W2005575796","https://openalex.org/W2006008657","https://openalex.org/W2006447494","https://openalex.org/W2007892970","https://openalex.org/W2009668810","https://openalex.org/W2013031135","https://openalex.org/W2014126110","https://openalex.org/W2015210907","https://openalex.org/W2016592851","https://openalex.org/W2020068892","https://openalex.org/W2020247738","https://openalex.org/W2021416828","https://openalex.org/W2022063555","https://openalex.org/W2024887669","https://openalex.org/W2033928452","https://openalex.org/W2034531272","https://openalex.org/W2034564636","https://openalex.org/W2043127396","https://openalex.org/W2049734783","https://openalex.org/W2055202374","https://openalex.org/W2060757838","https://openalex.org/W2063811836","https://openalex.org/W2065301809","https://openalex.org/W2076010240","https://openalex.org/W2076649802","https://openalex.org/W2083240081","https://openalex.org/W2085626852","https://openalex.org/W2086653307","https://openalex.org/W2088021124","https://openalex.org/W2088529109","https://openalex.org/W2089364192","https://openalex.org/W2090240721","https://openalex.org/W2090665363","https://openalex.org/W2094623166","https://openalex.org/W2094876073","https://openalex.org/W2095351425","https://openalex.org/W2105510993","https://openalex.org/W2110408336","https://openalex.org/W2116970516","https://openalex.org/W2127612636","https://openalex.org/W2136209035","https://openalex.org/W2147294959","https://openalex.org/W2244695449","https://openalex.org/W2314822101","https://openalex.org/W2318411184","https://openalex.org/W2319788209","https://openalex.org/W2321798101","https://openalex.org/W2612765547","https://openalex.org/W2949693762","https://openalex.org/W2952481713","https://openalex.org/W2953024617"],"related_works":["https://openalex.org/W2052136330","https://openalex.org/W2035603229","https://openalex.org/W1482317516","https://openalex.org/W2318188976","https://openalex.org/W2045406438","https://openalex.org/W2330615623","https://openalex.org/W2000862731","https://openalex.org/W2007251954","https://openalex.org/W2335100551","https://openalex.org/W2951610854"],"abstract_inverted_index":{"Polyyn-diyls":[0],"capped":[1],"by":[2],"Ru(2)(ap)(4)":[3],"termini":[4,101],"(ap":[5],"=":[6,15],"2-anilinopyridinate),":[7],"that":[8,83],"is,":[9],"[Ru2(ap)4](mu-C,C'-C2m)[Ru2(ap)4]":[10],"(compounds":[11],"1-5":[12],"with":[13],"m":[14],"1-4":[16],"and":[17,28,46,58,67,71,76,79,85,92],"6),":[18],"were":[19],"synthesized":[20],"through":[21],"either":[22],"a":[23,31],"metathesis":[24],"reaction":[25,34],"between":[26],"Ru2(ap)4Cl":[27],"LiC(2m)Li":[29],"or":[30],"Glaser":[32],"homocoupling":[33],"of":[35,43,55,88,111],"Ru2(ap)4(CmH)":[36],"under":[37],"Eglinton/Hay":[38],"conditions.":[39],"X-ray":[40],"diffraction":[41],"studies":[42,81],"compounds":[44,57],"2":[45],"4":[47],"revealed":[48],"both":[49],"the":[50,59,64,99,109,112],"linear":[51],"rigid":[52],"rod":[53],"topology":[54],"these":[56],"fine":[60],"structural":[61],"details":[62],"about":[63],"Ru2":[65,100],"cores":[66],"polyyn-diyl":[68,113],"chains.":[69],"Cyclic":[70],"differential":[72],"pulse":[73],"voltammetric":[74],"(CV":[75],"DPV)":[77],"measurements":[78],"spectroelectrochemical":[80],"show":[82],"reduced":[84],"oxidized":[86],"forms":[87],"1,":[89],"2,":[90],"4,":[91],"5":[93],"are":[94,102],"donor-acceptor":[95],"systems":[96],"in":[97],"which":[98],"coupled":[103],"to":[104],"varying":[105],"degrees":[106],"depending":[107],"upon":[108],"length":[110],"bridge.":[114]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":5},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":5},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":5},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":11},{"year":2015,"cited_by_count":11},{"year":2014,"cited_by_count":9},{"year":2013,"cited_by_count":12},{"year":2012,"cited_by_count":6}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}