{"id":"https://openalex.org/W2059487537","doi":"https://doi.org/10.1002/cjce.20256","title":"Cinetique de la reduction de l'acetate de CoIII dans l'acide acetique","display_name":"Cinetique de la reduction de l'acetate de CoIII dans l'acide acetique","publication_year":2010,"publication_date":"2010-01-26","ids":{"openalex":"https://openalex.org/W2059487537","doi":"https://doi.org/10.1002/cjce.20256","mag":"2059487537"},"language":"fr","primary_location":{"id":"doi:10.1002/cjce.20256","doi":"https://doi.org/10.1002/cjce.20256","is_oa":false,"landing_page_url":"https://doi.org/10.1002/cjce.20256","pdf_url":null,"source":{"id":"https://openalex.org/S83557516","display_name":"The Canadian Journal of Chemical Engineering","issn_l":"0008-4034","issn":["0008-4034","1939-019X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Canadian Journal of Chemical Engineering","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5077325542","display_name":"Jean Lozar","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I134560555","display_name":"Universit\u00e9 Toulouse III - Paul Sabatier","ror":"https://ror.org/02v6kpv12","country_code":"FR","type":"education","lineage":["https://openalex.org/I134560555","https://openalex.org/I4405258862"]},{"id":"https://openalex.org/I205747304","display_name":"Institut National Polytechnique de Toulouse","ror":"https://ror.org/033p9g875","country_code":"FR","type":"education","lineage":["https://openalex.org/I205747304"]},{"id":"https://openalex.org/I4210087602","display_name":"Laboratoire de G\u00e9nie Chimique","ror":"https://ror.org/003jnac13","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210087602","https://openalex.org/I4210095849","https://openalex.org/I4405258862"]},{"id":"https://openalex.org/I4405258862","display_name":"Universit\u00e9 de Toulouse","ror":"https://ror.org/01ahyrz84","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Lozar Jean","raw_affiliation_strings":["Universite\u0301 de Toulouse; INPT, UPS; Laboratoire de Ge\u0301nie Chimique; F-31062 Toulouse cedex 09, France","F-31062 Toulouse cedex 09, France","INPT, UPS","Laboratoire de Ge\u0301nie Chimique","Universite\u0301 de Toulouse"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Universite\u0301 de Toulouse; INPT, UPS; Laboratoire de Ge\u0301nie Chimique; F-31062 Toulouse cedex 09, France","institution_ids":["https://openalex.org/I134560555","https://openalex.org/I205747304","https://openalex.org/I4210087602","https://openalex.org/I4405258862"]},{"raw_affiliation_string":"F-31062 Toulouse cedex 09, France","institution_ids":[]},{"raw_affiliation_string":"INPT, UPS","institution_ids":["https://openalex.org/I134560555","https://openalex.org/I205747304"]},{"raw_affiliation_string":"Laboratoire de Ge\u0301nie Chimique","institution_ids":["https://openalex.org/I4210087602"]},{"raw_affiliation_string":"Universite\u0301 de Toulouse","institution_ids":["https://openalex.org/I4405258862"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5062036885","display_name":"Bernard Lafage","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I134560555","display_name":"Universit\u00e9 Toulouse III - Paul Sabatier","ror":"https://ror.org/02v6kpv12","country_code":"FR","type":"education","lineage":["https://openalex.org/I134560555","https://openalex.org/I4405258862"]},{"id":"https://openalex.org/I205747304","display_name":"Institut National Polytechnique de Toulouse","ror":"https://ror.org/033p9g875","country_code":"FR","type":"education","lineage":["https://openalex.org/I205747304"]},{"id":"https://openalex.org/I4210087602","display_name":"Laboratoire de G\u00e9nie Chimique","ror":"https://ror.org/003jnac13","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210087602","https://openalex.org/I4210095849","https://openalex.org/I4405258862"]},{"id":"https://openalex.org/I4405258862","display_name":"Universit\u00e9 de Toulouse","ror":"https://ror.org/01ahyrz84","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Lafage Bernard","raw_affiliation_strings":["Universite\u0301 de Toulouse; INPT, UPS; Laboratoire de Ge\u0301nie Chimique; F-31062 Toulouse cedex 09, France","F-31062 Toulouse cedex 09, France","INPT, UPS","Laboratoire de Ge\u0301nie Chimique","Universite\u0301 de Toulouse"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Universite\u0301 de Toulouse; INPT, UPS; Laboratoire de Ge\u0301nie Chimique; F-31062 Toulouse cedex 09, France","institution_ids":["https://openalex.org/I134560555","https://openalex.org/I205747304","https://openalex.org/I4210087602","https://openalex.org/I4405258862"]},{"raw_affiliation_string":"F-31062 Toulouse cedex 09, France","institution_ids":[]},{"raw_affiliation_string":"INPT, UPS","institution_ids":["https://openalex.org/I134560555","https://openalex.org/I205747304"]},{"raw_affiliation_string":"Laboratoire de Ge\u0301nie Chimique","institution_ids":["https://openalex.org/I4210087602"]},{"raw_affiliation_string":"Universite\u0301 de Toulouse","institution_ids":["https://openalex.org/I4405258862"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5077325542"],"corresponding_institution_ids":["https://openalex.org/I134560555","https://openalex.org/I205747304","https://openalex.org/I4210087602","https://openalex.org/I4405258862"],"apc_list":{"value":3690,"currency":"USD","value_usd":3690},"apc_paid":null,"fwci":0.1814,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.52596431,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"88","issue":"1","first_page":"67","last_page":"75"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.9696999788284302,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.9696999788284302,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.019300000742077827,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.00279999990016222,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cobalt-iii-acetate","display_name":"cobalt(III) acetate","score":0.9649999737739563},{"id":"https://openalex.org/keywords/reduction-kinetics","display_name":"reduction kinetics","score":0.8379999995231628},{"id":"https://openalex.org/keywords/acetic-acid","display_name":"acetic acid","score":0.8989999890327454},{"id":"https://openalex.org/keywords/isosbestic-point","display_name":"isosbestic point","score":0.8349999785423279},{"id":"https://openalex.org/keywords/cobalt-iii-complexes","display_name":"cobalt(III) complexes","score":0.8379999995231628},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.8009999990463257},{"id":"https://openalex.org/keywords/rate-constants","display_name":"rate constants","score":0.828000009059906},{"id":"https://openalex.org/keywords/activation-energy","display_name":"activation energy","score":0.9340000152587891},{"id":"https://openalex.org/keywords/visible-absorption-spectra","display_name":"visible absorption spectra","score":0.3790000081062317},{"id":"https://openalex.org/keywords/spectral-deconvolution","display_name":"spectral deconvolution","score":0.6909999847412109}],"concepts":[{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.666549563407898}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/cjce.20256","doi":"https://doi.org/10.1002/cjce.20256","is_oa":false,"landing_page_url":"https://doi.org/10.1002/cjce.20256","pdf_url":null,"source":{"id":"https://openalex.org/S83557516","display_name":"The Canadian Journal of Chemical Engineering","issn_l":"0008-4034","issn":["0008-4034","1939-019X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Canadian Journal of Chemical Engineering","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":12,"referenced_works":["https://openalex.org/W51404012","https://openalex.org/W2020040040","https://openalex.org/W2028702945","https://openalex.org/W2030074204","https://openalex.org/W2036760076","https://openalex.org/W2044111706","https://openalex.org/W2076184497","https://openalex.org/W2086514688","https://openalex.org/W2087598201","https://openalex.org/W2314665711","https://openalex.org/W2323950959","https://openalex.org/W2950070730"],"related_works":["https://openalex.org/W2605701297","https://openalex.org/W339405985","https://openalex.org/W1984678592","https://openalex.org/W1963510697","https://openalex.org/W2161147604","https://openalex.org/W4250250249","https://openalex.org/W2137411690","https://openalex.org/W2399432390","https://openalex.org/W2607183357","https://openalex.org/W2066623506"],"abstract_inverted_index":{"Abstract":[0],"On":[1,27],"\u00e9tudie":[2],"par":[3,31],"spectrophotom\u00e9trie":[4],"dans":[5,20],"le":[6,73,114],"visible":[7],"(470\u2013820":[8],"nm)":[9],"la":[10,32,89],"cin\u00e9tique":[11],"de":[12,14,16,71,78,88,97],"r\u00e9duction":[13],"l'ac\u00e9tate":[15],"${\\rm":[17,45,49,54,98,103,109,116],"Co}^{{\\rm":[18,46,117],"III}}$":[19,47,52,57,101,106,112],"l'acide":[21],"ac\u00e9tique,":[22],"entre":[23],"35\u00b0C":[24],"et":[25,53,70,80,102],"80\u00b0C.":[26],"met":[28],"en":[29],"\u00e9vidence":[30],"pr\u00e9sence":[33],"d'un":[34],"point":[35],"isobestique":[36],"\u00e0":[37],"\u03bb":[38],"=":[39],"670":[40],"nm":[41],"deux":[42],"complexes":[43],"du":[44],",":[48],"Co}_\\alpha":[50,99,110],"{}^{{\\rm":[51,56,100,105,111],"Co}_\\beta":[55,104],".":[58],"La":[59,93],"d\u00e9convolution":[60],"des":[61,67,84,95],"spectres":[62,96],"permet":[63,107],"d'acc\u00e9der":[64],"aux":[65],"absorbances":[66],"diverses":[68],"esp\u00e8ces":[69],"proposer":[72],"m\u00e9canisme":[74],"suivant:":[75],"Les":[76],"constantes":[77],"vitesse":[79],"les":[81],"\u00e9nergies":[82],"d'activation":[83],"trois":[85],"\u00e9tapes":[86],"\u00e9l\u00e9mentaires":[87],"r\u00e9action":[90],"sont":[91],"obtenues.":[92],"d\u00e9termination":[94],"d'identifier":[108],"avec":[113],"complexe":[115],"IIIs}}$":[118],"d\u00e9j\u00e0":[119],"connu.":[120]},"counts_by_year":[{"year":2013,"cited_by_count":1}],"updated_date":"2026-09-25T08:18:29.962427","created_date":"2016-06-24T00:00:00"}