{"id":"https://openalex.org/W2057779682","doi":"https://doi.org/10.1002/app.30665","title":"Terminal functionalized hydroxyl\u2010terminated polybutadiene: An energetic binder for propellant","display_name":"Terminal functionalized hydroxyl\u2010terminated polybutadiene: An energetic binder for propellant","publication_year":2009,"publication_date":"2009-06-08","ids":{"openalex":"https://openalex.org/W2057779682","doi":"https://doi.org/10.1002/app.30665","mag":"2057779682"},"language":"en","primary_location":{"id":"doi:10.1002/app.30665","doi":"https://doi.org/10.1002/app.30665","is_oa":false,"landing_page_url":"https://doi.org/10.1002/app.30665","pdf_url":null,"source":{"id":"https://openalex.org/S200764475","display_name":"Journal of Applied Polymer Science","issn_l":"0021-8995","issn":["0021-8995","1097-4628"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Applied Polymer Science","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5017684102","display_name":"Rajavelu Murali Shankar","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I36893310","display_name":"University of Hyderabad","ror":"https://ror.org/04a7rxb17","country_code":"IN","type":"education","lineage":["https://openalex.org/I36893310"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Rajavelu Murali Shankar","raw_affiliation_strings":["School of Chemistry, University of Hyderabad, Hyderabad, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry, University of Hyderabad, Hyderabad, India","institution_ids":["https://openalex.org/I36893310"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036950027","display_name":"Tapta Kanchan Roy","orcid":"https://orcid.org/0000-0003-2757-1711","observed_orcids":["https://orcid.org/0000-0003-2757-1711"]},"institutions":[{"id":"https://openalex.org/I36893310","display_name":"University of Hyderabad","ror":"https://ror.org/04a7rxb17","country_code":"IN","type":"education","lineage":["https://openalex.org/I36893310"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Tapta Kanchan Roy","raw_affiliation_strings":["School of Chemistry, University of Hyderabad, Hyderabad, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry, University of Hyderabad, Hyderabad, India","institution_ids":["https://openalex.org/I36893310"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5079096354","display_name":"Tushar Jana","orcid":"https://orcid.org/0000-0002-3680-2959","observed_orcids":["https://orcid.org/0000-0002-3680-2959"]},"institutions":[{"id":"https://openalex.org/I36893310","display_name":"University of Hyderabad","ror":"https://ror.org/04a7rxb17","country_code":"IN","type":"education","lineage":["https://openalex.org/I36893310"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Tushar Jana","raw_affiliation_strings":["School of Chemistry, University of Hyderabad, Hyderabad, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry, University of Hyderabad, Hyderabad, India","institution_ids":["https://openalex.org/I36893310"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5079096354"],"corresponding_institution_ids":["https://openalex.org/I36893310"],"apc_list":{"value":4140,"currency":"USD","value_usd":4140},"apc_paid":null,"fwci":2.1107,"has_fulltext":false,"cited_by_count":85,"citation_normalized_percentile":{"value":0.85349884,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"114","issue":"2","first_page":"732","last_page":"741"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10806","display_name":"Energetic Materials and Combustion","score":0.9648000001907349,"subfield":{"id":"https://openalex.org/subfields/2211","display_name":"Mechanics of Materials"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10806","display_name":"Energetic Materials and Combustion","score":0.9648000001907349,"subfield":{"id":"https://openalex.org/subfields/2211","display_name":"Mechanics of Materials"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12513","display_name":"Rocket and propulsion systems research","score":0.02889999933540821,"subfield":{"id":"https://openalex.org/subfields/2202","display_name":"Aerospace Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydroxyl-terminated-polybutadiene","display_name":"hydroxyl-terminated polybutadiene","score":0.9959999918937683},{"id":"https://openalex.org/keywords/energetic-binders","display_name":"energetic binders","score":0.777999997138977},{"id":"https://openalex.org/keywords/dinitrochlorobenzene","display_name":"1-chloro-2,4-dinitrobenzene","score":0.9660000205039978},{"id":"https://openalex.org/keywords/terminal-functionalization","display_name":"terminal functionalization","score":0.7179999947547913},{"id":"https://openalex.org/keywords/intermolecular-hydrogen-bonding","display_name":"intermolecular hydrogen bonding","score":0.8209999799728394},{"id":"https://openalex.org/keywords/pi-electron-delocalization","display_name":"\u03c0-electron delocalization","score":0.8809999823570251},{"id":"https://openalex.org/keywords/electron-withdrawing-effect","display_name":"electron-withdrawing effect","score":0.6959999799728394},{"id":"https://openalex.org/keywords/detonation-performance","display_name":"detonation performance","score":0.7960000038146973},{"id":"https://openalex.org/keywords/solid-propellant-binders","display_name":"solid propellant binders","score":0.7760000228881836},{"id":"https://openalex.org/keywords/covalent-modification","display_name":"covalent modification","score":0.6620000004768372}],"concepts":[{"id":"https://openalex.org/C2780901341","wikidata":"https://www.wikidata.org/wiki/Q143668","display_name":"Polybutadiene","level":4,"score":0.8804558515548706},{"id":"https://openalex.org/C180577832","wikidata":"https://www.wikidata.org/wiki/Q127920","display_name":"Covalent bond","level":2,"score":0.6883929371833801},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.6539349555969238},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.6155681610107422},{"id":"https://openalex.org/C2780096503","wikidata":"https://www.wikidata.org/wiki/Q3115617","display_name":"Hydroxyl-terminated polybutadiene","level":5,"score":0.5742068290710449},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.5516541600227356},{"id":"https://openalex.org/C70050531","wikidata":"https://www.wikidata.org/wiki/Q899089","display_name":"Delocalized electron","level":2,"score":0.5460607409477234},{"id":"https://openalex.org/C166950319","wikidata":"https://www.wikidata.org/wiki/Q245031","display_name":"Intermolecular force","level":3,"score":0.5069618225097656},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.48561182618141174},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3893125355243683},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.33493754267692566},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.2770846486091614},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.23977673053741455},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.21933326125144958}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/app.30665","doi":"https://doi.org/10.1002/app.30665","is_oa":false,"landing_page_url":"https://doi.org/10.1002/app.30665","pdf_url":null,"source":{"id":"https://openalex.org/S200764475","display_name":"Journal of Applied Polymer Science","issn_l":"0021-8995","issn":["0021-8995","1097-4628"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Applied Polymer Science","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":28,"referenced_works":["https://openalex.org/W227801651","https://openalex.org/W412802914","https://openalex.org/W603237125","https://openalex.org/W649100716","https://openalex.org/W1522782451","https://openalex.org/W1966012013","https://openalex.org/W1967117047","https://openalex.org/W1980082167","https://openalex.org/W1985279332","https://openalex.org/W1989798462","https://openalex.org/W1991290331","https://openalex.org/W2006770564","https://openalex.org/W2013903733","https://openalex.org/W2020088781","https://openalex.org/W2022824750","https://openalex.org/W2023271753","https://openalex.org/W2027475281","https://openalex.org/W2045605793","https://openalex.org/W2063974213","https://openalex.org/W2075121807","https://openalex.org/W2075396713","https://openalex.org/W2075793373","https://openalex.org/W2079850930","https://openalex.org/W2082316230","https://openalex.org/W2129561329","https://openalex.org/W2143981217","https://openalex.org/W2315892064","https://openalex.org/W3004455425"],"related_works":["https://openalex.org/W1981149032","https://openalex.org/W4411516918","https://openalex.org/W4387107916","https://openalex.org/W3093198263","https://openalex.org/W1963706519","https://openalex.org/W4200018154","https://openalex.org/W3134320218","https://openalex.org/W2604522313","https://openalex.org/W4400865984","https://openalex.org/W2022633679"],"abstract_inverted_index":{"Abstract":[0],"We":[1,111],"report":[2],"the":[3,18,23,28,31,36,41,44,60,67,72,88,92,97,101,104,109,113,117,124,129,135,140,145,148,153,162,166,169,173,179,183,193,199,206,212,221,226,229,235,245],"functionalization":[4],"of":[5,22,27,43,71,87,100,108,119,128,144,165,172,178,186,189,198,208,224,247],"hydroxyl":[6,126],"terminated":[7],"polybutadiene":[8],"(HTPB)":[9],"backbone":[10],"by":[11,30],"covalently":[12,64],"attaching":[13],"1\u2010chloro\u20102,":[14],"4\u2010dinitrobenzene":[15],"(DNCB)":[16],"at":[17,103,139],"terminal":[19,68,105,125,141],"carbon":[20,69,106,142],"atoms":[21,70,143],"HTPB.":[24,46,73,110,130,174],"The":[25,74],"modification":[26],"HTPB":[29,146,154,181,248],"DNCB":[32,61,89,102,137,167,200,227],"does":[33],"not":[34],"alter":[35],"unique":[37],"physico\u2013chemical":[38],"properties":[39],"and":[40,54,156,168,214,228],"microstructure":[42],"parent":[45],"IR,":[47],"1H\u2010NMR,":[48],"13C\u2010NMR,":[49],"size":[50],"exclusion":[51],"chromatography":[52],"(SEC)":[53],"absorption":[55],"spectroscopy":[56],"studies":[57],"prove":[58],"that":[59,134,220],"molecules":[62,138],"are":[63,91,112,231],"attached":[65,136],"to":[66,79,115,192,243],"\u03c0":[75,187],"electron":[76,84,188,195],"delocalization":[77,185],"owing":[78],"long":[80],"polymer":[81],"chain,":[82],"strong":[83,194],"withdrawing":[85,196],"effect":[86,197],"molecule":[90],"major":[93],"driving":[94],"forces":[95],"for":[96,251],"covalent":[98],"attachment":[99],"atom":[107],"first":[114],"observe":[116],"existence":[118,207],"intermolecular":[120,149],"hydrogen":[121,150,159,209],"bonding":[122,151,160,210],"between":[123,152,161,211],"groups":[127,164,171],"IR":[131],"study":[132,177],"shows":[133,219],"breaks":[147],"chains":[155],"forms":[157],"a":[158],"NO2":[163,215],"OH":[170,213],"Absorption":[175],"spectral":[176],"modified":[180],"indicates":[182],"better":[184],"butadiene":[190],"due":[191],"molecules.":[201],"Theoretical":[202,217],"calculation":[203,218],"also":[204],"supports":[205],"groups.":[216],"detonation":[222],"performance":[223],"both":[225],"HTPB\u2010DNCB":[230,233],"promising.":[232],"is":[234],"new":[236],"generation":[237],"energetic":[238],"binder":[239,250],"which":[240],"has":[241],"potential":[242],"replace":[244],"use":[246],"as":[249],"propellant.\u00a9":[252],"2009":[253,261],"Wiley":[254],"Periodicals,":[255],"Inc.":[256],"J":[257],"Appl":[258],"Polym":[259],"Sci,":[260]},"counts_by_year":[{"year":2026,"cited_by_count":6},{"year":2025,"cited_by_count":6},{"year":2024,"cited_by_count":5},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":6},{"year":2020,"cited_by_count":10},{"year":2019,"cited_by_count":11},{"year":2018,"cited_by_count":9},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":4},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}