{"id":"https://openalex.org/W2056909802","doi":"https://doi.org/10.1002/macp.1994.021950307","title":"The homogeneous photopolymerization of methyl methacrylate by colloidal cadmium sulfide","display_name":"The homogeneous photopolymerization of methyl methacrylate by colloidal cadmium sulfide","publication_year":1994,"publication_date":"1994-03-01","ids":{"openalex":"https://openalex.org/W2056909802","doi":"https://doi.org/10.1002/macp.1994.021950307","mag":"2056909802"},"language":"en","primary_location":{"id":"doi:10.1002/macp.1994.021950307","doi":"https://doi.org/10.1002/macp.1994.021950307","is_oa":false,"landing_page_url":"https://doi.org/10.1002/macp.1994.021950307","pdf_url":null,"source":{"id":"https://openalex.org/S124744586","display_name":"Macromolecular Chemistry and Physics","issn_l":"1022-1352","issn":["1022-1352","1521-3935"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecular Chemistry and Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5065880949","display_name":"Ivanka G. Popovi\u0107","orcid":"https://orcid.org/0000-0003-3812-3623","observed_orcids":["https://orcid.org/0000-0003-3812-3623"]},"institutions":[{"id":"https://openalex.org/I4068193","display_name":"University of Belgrade","ror":"https://ror.org/02qsmb048","country_code":"RS","type":"education","lineage":["https://openalex.org/I4068193"]}],"countries":["RS"],"is_corresponding":false,"raw_author_name":"Ivanka G. Popovi\u0107","raw_affiliation_strings":["Faculty of Technology and Metallurgy, Karnegijeva 4, YU-11000 Belgrade, Yugoslavia, Serbia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Technology and Metallurgy, Karnegijeva 4, YU-11000 Belgrade, Yugoslavia, Serbia","institution_ids":["https://openalex.org/I4068193"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070389655","display_name":"Lynne Katsikas","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4068193","display_name":"University of Belgrade","ror":"https://ror.org/02qsmb048","country_code":"RS","type":"education","lineage":["https://openalex.org/I4068193"]}],"countries":["RS"],"is_corresponding":false,"raw_author_name":"Lynne Katsikas","raw_affiliation_strings":["Faculty of Technology and Metallurgy, Karnegijeva 4, YU-11000 Belgrade, Yugoslavia, Serbia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Technology and Metallurgy, Karnegijeva 4, YU-11000 Belgrade, Yugoslavia, Serbia","institution_ids":["https://openalex.org/I4068193"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Udo M\u00fcller","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Udo M\u00fcller","raw_affiliation_strings":["Abteilung Photochemie, Hahn-Meitner-Institut-Berlin GmbH, Glienickerstr. 100, D-14109 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Abteilung Photochemie, Hahn-Meitner-Institut-Berlin GmbH, Glienickerstr. 100, D-14109 Berlin, Germany","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111686969","display_name":"Jovan Veli\u010dkovi\u0107","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4068193","display_name":"University of Belgrade","ror":"https://ror.org/02qsmb048","country_code":"RS","type":"education","lineage":["https://openalex.org/I4068193"]}],"countries":["RS"],"is_corresponding":false,"raw_author_name":"Jovan S. Veli\u010dkovi\u0107","raw_affiliation_strings":["Faculty of Technology and Metallurgy, Karnegijeva 4, YU-11000 Belgrade, Yugoslavia, Serbia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Technology and Metallurgy, Karnegijeva 4, YU-11000 Belgrade, Yugoslavia, Serbia","institution_ids":["https://openalex.org/I4068193"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5041865400","display_name":"Horst Weller","orcid":"https://orcid.org/0000-0003-2967-6955","observed_orcids":["https://orcid.org/0000-0003-2967-6955"]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Horst Weller","raw_affiliation_strings":["Abteilung Photochemie, Hahn-Meitner-Institut-Berlin GmbH, Glienickerstr. 100, D-14109 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Abteilung Photochemie, Hahn-Meitner-Institut-Berlin GmbH, Glienickerstr. 100, D-14109 Berlin, Germany","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5041865400"],"corresponding_institution_ids":[],"apc_list":{"value":4220,"currency":"USD","value_usd":4220},"apc_paid":null,"fwci":1.7813,"has_fulltext":false,"cited_by_count":25,"citation_normalized_percentile":{"value":0.82294776,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":95},"biblio":{"volume":"195","issue":"3","first_page":"889","last_page":"904"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12570","display_name":"Photopolymerization techniques and applications","score":0.7148000001907349,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12570","display_name":"Photopolymerization techniques and applications","score":0.7148000001907349,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.27950000762939453,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.0010000000474974513,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/methyl-methacrylate","display_name":"methyl methacrylate","score":0.8100000023841858},{"id":"https://openalex.org/keywords/photopolymerization","display_name":"photopolymerization","score":0.8679999709129333},{"id":"https://openalex.org/keywords/polymerization-mechanism","display_name":"polymerization mechanism","score":0.8119999766349792},{"id":"https://openalex.org/keywords/chain-end-structure","display_name":"chain-end structure","score":0.6520000100135803},{"id":"https://openalex.org/keywords/thermal-stability","display_name":"thermal stability","score":0.5180000066757202},{"id":"https://openalex.org/keywords/poly-methyl-methacrylate","display_name":"poly(methyl methacrylate)","score":0.8579999804496765}],"concepts":[{"id":"https://openalex.org/C2779921683","wikidata":"https://www.wikidata.org/wiki/Q179619","display_name":"Cadmium sulfide","level":2,"score":0.8203856945037842},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.7764009833335876},{"id":"https://openalex.org/C2777935641","wikidata":"https://www.wikidata.org/wiki/Q382897","display_name":"Methyl methacrylate","level":4,"score":0.6653611063957214},{"id":"https://openalex.org/C15487406","wikidata":"https://www.wikidata.org/wiki/Q2631097","display_name":"Photopolymer","level":4,"score":0.6476824283599854},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.6084468364715576},{"id":"https://openalex.org/C121120078","wikidata":"https://www.wikidata.org/wiki/Q3737603","display_name":"Chain transfer","level":5,"score":0.510620653629303},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.47712042927742004},{"id":"https://openalex.org/C2780596425","wikidata":"https://www.wikidata.org/wiki/Q221205","display_name":"Sulfide","level":2,"score":0.44289085268974304},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4395246207714081},{"id":"https://openalex.org/C111998727","wikidata":"https://www.wikidata.org/wiki/Q2620998","display_name":"Radical polymerization","level":4,"score":0.41330069303512573},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3991033434867859},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.38159802556037903},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.34357893466949463},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.152419775724411},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.0937422513961792},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1002/macp.1994.021950307","doi":"https://doi.org/10.1002/macp.1994.021950307","is_oa":false,"landing_page_url":"https://doi.org/10.1002/macp.1994.021950307","pdf_url":null,"source":{"id":"https://openalex.org/S124744586","display_name":"Macromolecular Chemistry and Physics","issn_l":"1022-1352","issn":["1022-1352","1521-3935"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecular Chemistry and Physics","raw_type":"journal-article"},{"id":"pmh:oai:TechnoRep.tmf.bg.ac.rs:123456789/58","doi":null,"is_oa":false,"landing_page_url":"https://TechnoRep.tmf.bg.ac.rs/handle/123456789/58","pdf_url":null,"source":{"id":"https://openalex.org/S4306402472","display_name":"TechnoRep (University of Belgrade \u2013 Faculty of Technology and Metallurgy)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210101313","host_organization_name":"University Hospital Center Dr Dragi\u0161a Mi\u0161ovi\u0107","host_organization_lineage":["https://openalex.org/I4210101313"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecular Chemistry and Physics","raw_type":"article"},{"id":"pmh:oai:helmholtz.HZB:-3295","doi":null,"is_oa":false,"landing_page_url":"https://www.helmholtz-berlin.de/pubbin/oai_publication?VT=1&ID=-3295","pdf_url":null,"source":{"id":"https://openalex.org/S4306402598","display_name":"HZB Repository (Helmholtz-Zentrum Berlin f\u00fcr Materialien und Energie GmbH (HZB))","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I3018134672","host_organization_name":"Helmholtz Munich","host_organization_lineage":["https://openalex.org/I3018134672"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Macromolecular Chemistry and Physics 195 1994 , p. 889 904","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":37,"referenced_works":["https://openalex.org/W170992918","https://openalex.org/W292562412","https://openalex.org/W312466162","https://openalex.org/W1501404534","https://openalex.org/W1508237257","https://openalex.org/W1968926231","https://openalex.org/W1982437908","https://openalex.org/W1996212045","https://openalex.org/W2008498840","https://openalex.org/W2009981131","https://openalex.org/W2013331996","https://openalex.org/W2025949854","https://openalex.org/W2029023208","https://openalex.org/W2034555980","https://openalex.org/W2034564976","https://openalex.org/W2038137833","https://openalex.org/W2044566006","https://openalex.org/W2055310008","https://openalex.org/W2055702689","https://openalex.org/W2063431185","https://openalex.org/W2063913273","https://openalex.org/W2074823474","https://openalex.org/W2078557907","https://openalex.org/W2083091661","https://openalex.org/W2086578481","https://openalex.org/W2087002485","https://openalex.org/W2087909109","https://openalex.org/W2089799296","https://openalex.org/W2091359125","https://openalex.org/W2108707092","https://openalex.org/W2148092984","https://openalex.org/W2153192004","https://openalex.org/W2158374511","https://openalex.org/W2205457129","https://openalex.org/W2315289246","https://openalex.org/W3115622617","https://openalex.org/W4240637533"],"related_works":["https://openalex.org/W1966548177","https://openalex.org/W3016448162","https://openalex.org/W2082021948","https://openalex.org/W2010027826","https://openalex.org/W2073385497","https://openalex.org/W2058883244","https://openalex.org/W4230423831","https://openalex.org/W2149530197","https://openalex.org/W1976991068","https://openalex.org/W2109728732"],"abstract_inverted_index":{"Abstract":[0],"A":[1,33],"completely":[2],"new":[3],"method":[4],"of":[5,11,22,76,108,123,156,173],"initiating":[6],"the":[7,20,44,52,77,97,109,121,133,151,170],"homogeneous":[8,171],"radical":[9],"polymerization":[10,34,102,122],"methyl":[12,55],"methacrylate":[13,56],"in":[14,17,27,42,65,71,104,176],"bulk":[15],"or":[16],"solution":[18],"via":[19],"photogeneration":[21],"an":[23,37],"electron":[24],"hole":[25,63],"pair":[26],"colloidal":[28],"cadmium":[29,39,87],"sulfide":[30,40,88],"is":[31,49,58,90,118,161],"presented.":[32],"mechanism":[35,103],"involving":[36],"excited":[38,86],"particle":[41],"both":[43],"initiation":[45,53],"and":[46,116],"termination":[47],"steps":[48],"proposed.":[50],"In":[51,149],"a":[54,61,66,72,100,177],"molecule":[57],"oxidized":[59],"by":[60,127],"positive":[62],"photogenerated":[64],"CdS":[67,174],"particle,":[68],"which":[69,105],"results":[70],"novel":[73],"chain\u2010end":[74],"structure":[75],"poly(methyl":[78],"methacrylate)":[79],"(PMMA).":[80],"Degradative":[81],"chain":[82,93,114],"transfer":[83,115],"to":[84,144,165],"reduced":[85],"particles":[89,175],"responsible":[91],"for":[92,96,120],"termination.":[94],"Thus,":[95],"first":[98],"time,":[99],"detailed":[101],"all":[106],"states":[107],"polymerization,":[110],"i.e.,":[111],"initiation,":[112],"propagation,":[113],"termination,":[117],"presented":[119],"vinyl":[124],"monomers":[125],"initiated":[126],"semiconductors.":[128],"Thermogravimetry":[129],"(TG)":[130],"showed":[131],"that":[132,155],"newly":[134],"synthesized":[135],"PMMA":[136,159],"has":[137],"greatly":[138],"enhanced":[139],"thermal":[140,152],"stability":[141,153],"when":[142],"compared":[143],"normal":[145],"radically":[146],"prepared":[147,158],"PMMA.":[148],"fact,":[150],"approaches":[154],"anionically":[157],"but":[160],"experimentally":[162],"much":[163],"easier":[164],"prepare.":[166],"This":[167],"technique":[168],"enables":[169],"embedding":[172],"polymer":[178],"matrix.":[179]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1}],"updated_date":"2026-10-14T16:39:01.820549","created_date":"2016-06-24T00:00:00"}