{"id":"https://openalex.org/W2054718002","doi":"https://doi.org/10.1021/ma9600163","title":"Controlled/\u201cLiving\u201d Radical Polymerization with Dendrimers Containing Stable Radicals","display_name":"Controlled/\u201cLiving\u201d Radical Polymerization with Dendrimers Containing Stable Radicals","publication_year":1996,"publication_date":"1996-01-01","ids":{"openalex":"https://openalex.org/W2054718002","doi":"https://doi.org/10.1021/ma9600163","mag":"2054718002"},"language":"en","primary_location":{"id":"doi:10.1021/ma9600163","doi":"https://doi.org/10.1021/ma9600163","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ma9600163","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5056539244","display_name":"Krzysztof Aleksander Matyjaszewski","orcid":"https://orcid.org/0000-0003-1960-3402","observed_orcids":["https://orcid.org/0000-0003-1960-3402"]},"institutions":[{"id":"https://openalex.org/I205783295","display_name":"Cornell University","ror":"https://ror.org/05bnh6r87","country_code":"US","type":"education","lineage":["https://openalex.org/I205783295"]},{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Krzysztof Matyjaszewski","raw_affiliation_strings":["Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, and Baker Laboratory, Department of Chemistry, Cornell University, Ithaca, New York 14853-1301"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, and Baker Laboratory, Department of Chemistry, Cornell University, Ithaca, New York 14853-1301","institution_ids":["https://openalex.org/I205783295","https://openalex.org/I74973139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046979145","display_name":"Takeo Shigemoto","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I205783295","display_name":"Cornell University","ror":"https://ror.org/05bnh6r87","country_code":"US","type":"education","lineage":["https://openalex.org/I205783295"]},{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Takeo Shigemoto","raw_affiliation_strings":["Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, and Baker Laboratory, Department of Chemistry, Cornell University, Ithaca, New York 14853-1301"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, and Baker Laboratory, Department of Chemistry, Cornell University, Ithaca, New York 14853-1301","institution_ids":["https://openalex.org/I205783295","https://openalex.org/I74973139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002152167","display_name":"Jean M. J. Fr\u00e9chet","orcid":"https://orcid.org/0000-0001-6419-0163","observed_orcids":["https://orcid.org/0000-0001-6419-0163"]},"institutions":[{"id":"https://openalex.org/I205783295","display_name":"Cornell University","ror":"https://ror.org/05bnh6r87","country_code":"US","type":"education","lineage":["https://openalex.org/I205783295"]},{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jean M. J. Fr\u00e9chet","raw_affiliation_strings":["Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, and Baker Laboratory, Department of Chemistry, Cornell University, Ithaca, New York 14853-1301"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, and Baker Laboratory, Department of Chemistry, Cornell University, Ithaca, New York 14853-1301","institution_ids":["https://openalex.org/I205783295","https://openalex.org/I74973139"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5011115707","display_name":"Marc R. Leduc","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I205783295","display_name":"Cornell University","ror":"https://ror.org/05bnh6r87","country_code":"US","type":"education","lineage":["https://openalex.org/I205783295"]},{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Marc Leduc","raw_affiliation_strings":["Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, and Baker Laboratory, Department of Chemistry, Cornell University, Ithaca, New York 14853-1301"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, and Baker Laboratory, Department of Chemistry, Cornell University, Ithaca, New York 14853-1301","institution_ids":["https://openalex.org/I205783295","https://openalex.org/I74973139"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":7.7919,"has_fulltext":false,"cited_by_count":113,"citation_normalized_percentile":{"value":0.98495128,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"29","issue":"12","first_page":"4167","last_page":"4171"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9965999722480774,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9965999722480774,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11686","display_name":"Dendrimers and Hyperbranched Polymers","score":0.003000000026077032,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13013","display_name":"Free Radicals and Antioxidants","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/controlled-radical-polymerization","display_name":"controlled radical polymerization","score":0.9089999794960022},{"id":"https://openalex.org/keywords/dendrimers","display_name":"dendrimers","score":0.9079999923706055},{"id":"https://openalex.org/keywords/stable-radicals","display_name":"stable radicals","score":0.8479999899864197},{"id":"https://openalex.org/keywords/tempo","display_name":"tempo","score":0.9739999771118164},{"id":"https://openalex.org/keywords/styrene-polymerization","display_name":"styrene polymerization","score":0.7419999837875366},{"id":"https://openalex.org/keywords/vinyl-acetate","display_name":"vinyl acetate","score":0.9269999861717224},{"id":"https://openalex.org/keywords/methyl-methacrylate","display_name":"methyl methacrylate","score":0.9459999799728394},{"id":"https://openalex.org/keywords/n-butyl-acrylate","display_name":"butyl acrylate","score":0.9570000171661377},{"id":"https://openalex.org/keywords/polydispersity","display_name":"polydispersity","score":0.8569999933242798},{"id":"https://openalex.org/keywords/self-initiation","display_name":"self-initiation","score":0.722000002861023},{"id":"https://openalex.org/keywords/homolytic-cleavage","display_name":"homolytic cleavage","score":0.6819999814033508}],"concepts":[{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.6988292932510376},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.6866413950920105},{"id":"https://openalex.org/C111998727","wikidata":"https://www.wikidata.org/wiki/Q2620998","display_name":"Radical polymerization","level":4,"score":0.6587944626808167},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6476863622665405},{"id":"https://openalex.org/C121120078","wikidata":"https://www.wikidata.org/wiki/Q3737603","display_name":"Chain transfer","level":5,"score":0.5783221125602722},{"id":"https://openalex.org/C89760097","wikidata":"https://www.wikidata.org/wiki/Q304519","display_name":"Living free-radical polymerization","level":5,"score":0.5580673217773438},{"id":"https://openalex.org/C48396125","wikidata":"https://www.wikidata.org/wiki/Q903447","display_name":"Living polymerization","level":5,"score":0.5246244072914124},{"id":"https://openalex.org/C167076587","wikidata":"https://www.wikidata.org/wiki/Q11821744","display_name":"Chain-growth polymerization","level":5,"score":0.5223706364631653},{"id":"https://openalex.org/C55637122","wikidata":"https://www.wikidata.org/wiki/Q903923","display_name":"Dendrimer","level":2,"score":0.5191758871078491},{"id":"https://openalex.org/C90958600","wikidata":"https://www.wikidata.org/wiki/Q3406609","display_name":"Precipitation polymerization","level":5,"score":0.5157464146614075},{"id":"https://openalex.org/C16728422","wikidata":"https://www.wikidata.org/wiki/Q17145489","display_name":"Kinetic chain length","level":5,"score":0.44780057668685913},{"id":"https://openalex.org/C206707181","wikidata":"https://www.wikidata.org/wiki/Q5051386","display_name":"Catalytic chain transfer","level":5,"score":0.4414522051811218},{"id":"https://openalex.org/C84687054","wikidata":"https://www.wikidata.org/wiki/Q17125192","display_name":"Ionic polymerization","level":5,"score":0.43287891149520874},{"id":"https://openalex.org/C34594497","wikidata":"https://www.wikidata.org/wiki/Q639983","display_name":"Reversible addition\u2212fragmentation chain-transfer polymerization","level":5,"score":0.4233062267303467},{"id":"https://openalex.org/C152236973","wikidata":"https://www.wikidata.org/wiki/Q5375766","display_name":"End-group","level":4,"score":0.4145708382129669},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3917338252067566},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.36323145031929016},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.21354997158050537}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ma9600163","doi":"https://doi.org/10.1021/ma9600163","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ma9600163","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":17,"referenced_works":["https://openalex.org/W1492488181","https://openalex.org/W1964172595","https://openalex.org/W1970945403","https://openalex.org/W2001220467","https://openalex.org/W2010542051","https://openalex.org/W2017917112","https://openalex.org/W2037071136","https://openalex.org/W2046888666","https://openalex.org/W2065080959","https://openalex.org/W2074554162","https://openalex.org/W2088073395","https://openalex.org/W2088890545","https://openalex.org/W2094947865","https://openalex.org/W2095060054","https://openalex.org/W2317295301","https://openalex.org/W2333852227","https://openalex.org/W3023242395"],"related_works":["https://openalex.org/W2041548684","https://openalex.org/W2107700201","https://openalex.org/W2039347288","https://openalex.org/W2045200701","https://openalex.org/W2006135202","https://openalex.org/W2062992238","https://openalex.org/W2144152364","https://openalex.org/W2002536695","https://openalex.org/W2064398281","https://openalex.org/W2171279753"],"abstract_inverted_index":{"TEMPO-based":[0],"stable":[1],"radicals":[2],"were":[3,165,171],"attached":[4,148,238],"to":[5,12,115,117,149,203,239],"dendrimers":[6,136,187,198,241],"of":[7,16,24,44,72,90,131,134,143,155,185,196,209,218,230,236,266],"variable":[8],"size":[9],"and":[10,20,51,93,161,190],"used":[11],"control":[13,204],"radical":[14],"polymerization":[15,23,43,130,211,217],"styrene,":[17],"vinyl":[18,157],"acetate,":[19,158],"(meth)acrylates.":[21],"Thermal":[22],"styrene":[25,45,132],"with":[26,38,47,61,100,146,173,272],"[G-2]-TEMPO":[27],"proceeded":[28],"in":[29,69,212],"a":[30],"similar":[31],"but":[32,224,263],"not":[33,112,200,258],"better":[34,222],"controlled":[35,223],"manner":[36],"than":[37,68],"TEMPO":[39],"alone.":[40],"In":[41],"the":[42,49,52,57,64,70,81,88,91,101,107,122,128,135,140,153,168,174,183,186,194,197,205,210,227,231,240,249,253,273],"initiated":[46],"BPO,":[48],"kinetics":[50],"molecular":[53],"weight/conversion":[54],"relations":[55],"showed":[56],"same":[58],"tendency":[59],"as":[60,137,139],"TEMPO,":[62],"though":[63],"polydispersity":[65],"was":[66,199],"higher":[67,108,123,254],"absence":[71],"dendrimers.":[73,150,175],"This":[74],"indicates":[75],"that":[76,106,216,248],"homolytic":[77],"cleavage":[78],"occurs":[79],"at":[80,96,226],"reaction":[82],"temperature,":[83],"monomer":[84],"can":[85],"diffuse":[86],"inside":[87],"cavity":[89,184],"dendrimer,":[92],"polymer":[94],"is":[95,221,257],"least":[97],"partially":[98],"compatible":[99],"dendrimer.":[102],"Model":[103],"reactions":[104],"indicate":[105,215],"observed":[109,255],"polydispersities":[110,124,256],"could":[111,125],"be":[113],"ascribed":[114],"transfer":[116],"benzyl":[118],"hydrogen":[119],"atoms.":[120],"Therefore,":[121],"originate":[126],"from":[127,182],"self-initiated":[129],"outside":[133],"well":[138],"slow":[141,274],"exchange":[142],"these":[144,219],"chains":[145,147,178,262],"To":[151],"evaluate":[152],"effect":[154],"self-initiation,":[156],"methyl":[159],"methacrylate,":[160],"n":[162],"-butyl":[163],"acrylate":[164],"used;":[166],"however,":[167],"resulting":[169],"polymers":[170,237],"incompatibile":[172],"The":[176,207,233],"growing":[177,261],"are":[179],"easily":[180],"released":[181],"into":[188,193],"solution,":[189],"their":[191],"return":[192],"cavities":[195],"fast":[201],"enough":[202],"polymerization.":[206,244],"results":[208,246],"decalin":[213],"solution":[214],"monomers":[220],"only":[225],"early":[228],"stages":[229],"polymerizations.":[232],"subsequent":[234],"precipitation":[235],"prevents":[242],"further":[243],"These":[245],"suggest":[247],"main":[250],"reason":[251],"for":[252],"termination":[259],"between":[260],"either":[264],"decomposition":[265],"alkoxyamines":[267],"or":[268],"self-initiation":[269],"occurring":[270],"simultaneously":[271],"propagation.":[275]},"counts_by_year":[{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":5}],"updated_date":"2026-10-07T09:51:55.459714","created_date":"2016-06-24T00:00:00"}