{"id":"https://openalex.org/W2053974085","doi":"https://doi.org/10.1021/ic00011a014","title":"Stepwise ligand-additivity effects on electrode potentials and charge-transfer spectra in hexahalide, mixed halide/nitrile, and hexakis(nitrile) complexes of ruthenium(IV), -(III), and -(II)","display_name":"Stepwise ligand-additivity effects on electrode potentials and charge-transfer spectra in hexahalide, mixed halide/nitrile, and hexakis(nitrile) complexes of ruthenium(IV), -(III), and -(II)","publication_year":1991,"publication_date":"1991-05-01","ids":{"openalex":"https://openalex.org/W2053974085","doi":"https://doi.org/10.1021/ic00011a014","mag":"2053974085"},"language":"en","primary_location":{"id":"doi:10.1021/ic00011a014","doi":"https://doi.org/10.1021/ic00011a014","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic00011a014","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5033491514","display_name":"Colleen M. Duff","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Colleen M. Duff","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5108480928","display_name":"Graham A. Heath","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Graham A. Heath","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":5.2878,"has_fulltext":false,"cited_by_count":106,"citation_normalized_percentile":{"value":0.96789806,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"30","issue":"11","first_page":"2528","last_page":"2535"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.8925999999046326,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.8925999999046326,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.0723000019788742,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.007000000216066837,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ruthenium-complexes","display_name":"ruthenium complexes","score":0.9240000247955322},{"id":"https://openalex.org/keywords/electrode-potential","display_name":"electrode potential","score":0.8799999952316284},{"id":"https://openalex.org/keywords/charge-transfer-spectra","display_name":"charge-transfer spectra","score":0.9620000123977661},{"id":"https://openalex.org/keywords/ruthenium-iv","display_name":"ruthenium(IV)","score":0.9290000200271606},{"id":"https://openalex.org/keywords/ruthenium-iii","display_name":"ruthenium(III)","score":0.9990000128746033},{"id":"https://openalex.org/keywords/ruthenium-ii","display_name":"ruthenium(II)","score":0.9900000095367432},{"id":"https://openalex.org/keywords/redox-chemistry","display_name":"redox chemistry","score":0.45500001311302185},{"id":"https://openalex.org/keywords/nitrile-ligands","display_name":"nitrile ligands","score":0.6230000257492065}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9716963768005371},{"id":"https://openalex.org/C2779240715","wikidata":"https://www.wikidata.org/wiki/Q333936","display_name":"Nitrile","level":2,"score":0.9463473558425903},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.7442693710327148},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.7350096106529236},{"id":"https://openalex.org/C188082385","wikidata":"https://www.wikidata.org/wiki/Q73792","display_name":"Charge (physics)","level":2,"score":0.5056214332580566},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.4866269528865814},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.4644833207130432},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.4636121690273285},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4452809989452362},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.34099334478378296},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2246612012386322},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17805790901184082},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.05362024903297424},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ic00011a014","doi":"https://doi.org/10.1021/ic00011a014","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic00011a014","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2085535326","https://openalex.org/W2082879742","https://openalex.org/W2328578958","https://openalex.org/W1981560979","https://openalex.org/W2010702236","https://openalex.org/W4286493987","https://openalex.org/W2055045143","https://openalex.org/W98880914","https://openalex.org/W1992364889","https://openalex.org/W2072727133"],"abstract_inverted_index":{"ADVERTISEMENT":[0],"RETURN":[1],"TO":[2],"ISSUEPREVArticleNEXTStepwise":[3],"ligand-additivity":[4],"effects":[5],"on":[6,134,162],"electrode":[7],"potentials":[8],"and":[9,16,22,26,72,77,106,150,167,183,185],"charge-transfer":[10],"spectra":[11],"in":[12],"hexahalide,":[13],"mixed":[14],"halide/nitrile,":[15],"hexakis(nitrile)":[17],"complexes":[18],"of":[19,62,97,123],"ruthenium(IV),":[20],"-(III),":[21],"-(II)Colleen":[23],"M.":[24],"Duff":[25],"Graham":[27],"A.":[28],"HeathCite":[29],"this:":[30],"Inorg.":[31],"Chem.":[32],"1991,":[33],"30,":[34],"11,":[35],"2528\u20132535Publication":[36],"Date":[37],"(Print):May":[38],"1,":[39],"1991Publication":[40],"History":[41],"Published":[42],"online1":[43],"May":[44,48],"2002Published":[45],"inissue":[46],"1":[47],"1991https://pubs.acs.org/doi/10.1021/ic00011a014https://doi.org/10.1021/ic00011a014research-articleACS":[49],"PublicationsRequest":[50],"reuse":[51],"permissionsArticle":[52],"Views442Altmetric-Citations89LEARN":[53],"ABOUT":[54],"THESE":[55],"METRICSArticle":[56],"Views":[57],"are":[58,81,94],"the":[59,90,95,124,135,148,151,156,163,169],"COUNTER-compliant":[60],"sum":[61],"full":[63],"text":[64],"article":[65,129],"downloads":[66],"since":[67],"November":[68],"2008":[69],"(both":[70],"PDF":[71],"HTML)":[73],"across":[74],"all":[75],"institutions":[76],"individuals.":[78],"These":[79],"metrics":[80],"regularly":[82],"updated":[83,107],"to":[84,89],"reflect":[85],"usage":[86],"leading":[87],"up":[88],"last":[91],"few":[92],"days.Citations":[93],"number":[96],"other":[98],"articles":[99],"citing":[100],"this":[101],"article,":[102],"calculated":[103],"by":[104],"Crossref":[105,113],"daily.":[108],"Find":[109,159],"more":[110,160],"information":[111,161],"about":[112,147],"citation":[114],"counts.The":[115],"Altmetric":[116,164],"Attention":[117,165],"Score":[118,166],"is":[119,171],"a":[120,127,140],"quantitative":[121],"measure":[122],"attention":[125],"that":[126],"research":[128],"has":[130],"received":[131],"online.":[132],"Clicking":[133],"donut":[136],"icon":[137],"will":[138],"load":[139],"page":[141],"at":[142],"altmetric.com":[143],"with":[144,179],"additional":[145],"details":[146],"score":[149,170],"social":[152],"media":[153],"presence":[154],"for":[155],"given":[157],"article.":[158],"how":[168],"calculated.":[172],"Share":[173,188],"Add":[174],"toView":[175],"InAdd":[176],"Full":[177],"Text":[178],"ReferenceAdd":[180],"Description":[181],"ExportRISCitationCitation":[182],"abstractCitation":[184],"referencesMore":[186],"Options":[187],"onFacebookTwitterWechatLinked":[189],"InRedditEmail":[190],"Other":[191],"access":[192],"optionsGet":[193],"e-AlertscloseSupporting":[194],"Info":[195],"(1)\u00bbSupporting":[196],"Information":[197,199],"Supporting":[198],"Get":[200],"e-Alerts":[201]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":1}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}