{"id":"https://openalex.org/W2053923926","doi":"https://doi.org/10.1126/science.1179713","title":"Selective Phenol Hydrogenation to Cyclohexanone Over a Dual Supported Pd\u2013Lewis Acid Catalyst","display_name":"Selective Phenol Hydrogenation to Cyclohexanone Over a Dual Supported Pd\u2013Lewis Acid Catalyst","publication_year":2009,"publication_date":"2009-11-27","ids":{"openalex":"https://openalex.org/W2053923926","doi":"https://doi.org/10.1126/science.1179713","mag":"2053923926","pmid":"https://pubmed.ncbi.nlm.nih.gov/19965472"},"language":"en","primary_location":{"id":"doi:10.1126/science.1179713","doi":"https://doi.org/10.1126/science.1179713","is_oa":false,"landing_page_url":"https://doi.org/10.1126/science.1179713","pdf_url":null,"source":{"id":"https://openalex.org/S3880285","display_name":"Science","issn_l":"0036-8075","issn":["0036-8075","0193-4511","1095-9203"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","erih-plus","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310315823","host_organization_name":"American Association for the Advancement of Science","host_organization_lineage":["https://openalex.org/P4310315823"],"host_organization_lineage_names":["American Association for the Advancement of Science"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Science","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5046040180","display_name":"Huizhen Liu","orcid":"https://orcid.org/0000-0002-6801-7816","observed_orcids":["https://orcid.org/0000-0002-6801-7816"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210116048","display_name":"Beijing National Laboratory for Molecular Sciences","ror":"https://ror.org/02601yx74","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210116048"]},{"id":"https://openalex.org/I4210155088","display_name":"Institute of Chemistry","ror":"https://ror.org/048y1rc66","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210155088"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Huizhen Liu","raw_affiliation_strings":["Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210116048","https://openalex.org/I4210155088"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101523049","display_name":"Tao Jiang","orcid":"https://orcid.org/0009-0002-0550-4147","observed_orcids":["https://orcid.org/0009-0002-0550-4147"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210116048","display_name":"Beijing National Laboratory for Molecular Sciences","ror":"https://ror.org/02601yx74","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210116048"]},{"id":"https://openalex.org/I4210155088","display_name":"Institute of Chemistry","ror":"https://ror.org/048y1rc66","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210155088"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Tao Jiang","raw_affiliation_strings":["Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210116048","https://openalex.org/I4210155088"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111928301","display_name":"Buxing Han","orcid":"https://orcid.org/0000-0003-0440-809X","observed_orcids":["https://orcid.org/0000-0003-0440-809X"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210116048","display_name":"Beijing National Laboratory for Molecular Sciences","ror":"https://ror.org/02601yx74","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210116048"]},{"id":"https://openalex.org/I4210155088","display_name":"Institute of Chemistry","ror":"https://ror.org/048y1rc66","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210155088"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Buxing Han","raw_affiliation_strings":["Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210116048","https://openalex.org/I4210155088"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110075804","display_name":"Shuguang Liang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210116048","display_name":"Beijing National Laboratory for Molecular Sciences","ror":"https://ror.org/02601yx74","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210116048"]},{"id":"https://openalex.org/I4210155088","display_name":"Institute of Chemistry","ror":"https://ror.org/048y1rc66","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210155088"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shuguang Liang","raw_affiliation_strings":["Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210116048","https://openalex.org/I4210155088"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5103554996","display_name":"Yinxi Zhou","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210116048","display_name":"Beijing National Laboratory for Molecular Sciences","ror":"https://ror.org/02601yx74","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210116048"]},{"id":"https://openalex.org/I4210155088","display_name":"Institute of Chemistry","ror":"https://ror.org/048y1rc66","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210155088"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yinxi Zhou","raw_affiliation_strings":["Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210116048","https://openalex.org/I4210155088"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5101523049","https://openalex.org/A5111928301"],"corresponding_institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210116048","https://openalex.org/I4210155088"],"apc_list":null,"apc_paid":null,"fwci":9.8138,"has_fulltext":false,"cited_by_count":702,"citation_normalized_percentile":{"value":0.99097767,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"326","issue":"5957","first_page":"1250","last_page":"1252"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12240","display_name":"Nanomaterials for catalytic reactions","score":0.9086999893188477,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12240","display_name":"Nanomaterials for catalytic reactions","score":0.9086999893188477,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11009","display_name":"Catalysis for Biomass Conversion","score":0.03759999945759773,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.0215000007301569,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/phenol-hydrogenation","display_name":"phenol hydrogenation","score":0.949999988079071},{"id":"https://openalex.org/keywords/cyclohexanone","display_name":"cyclohexanone","score":0.9779999852180481},{"id":"https://openalex.org/keywords/palladium-catalysts","display_name":"palladium catalysts","score":0.8379999995231628},{"id":"https://openalex.org/keywords/lewis-acid-cocatalyst","display_name":"Lewis acid cocatalyst","score":0.7590000033378601},{"id":"https://openalex.org/keywords/aluminum-chloride","display_name":"aluminum chloride","score":0.9139999747276306},{"id":"https://openalex.org/keywords/selective-hydrogenation","display_name":"selective hydrogenation","score":0.6269999742507935},{"id":"https://openalex.org/keywords/nay-zeolite","display_name":"NaY zeolite","score":0.8360000252723694},{"id":"https://openalex.org/keywords/co2-solvent","display_name":"CO2 solvent","score":0.6690000295639038},{"id":"https://openalex.org/keywords/hydrogenation-kinetics","display_name":"hydrogenation kinetics","score":0.6600000262260437}],"concepts":[{"id":"https://openalex.org/C2780450521","wikidata":"https://www.wikidata.org/wiki/Q409178","display_name":"Cyclohexanone","level":3,"score":0.9597634077072144},{"id":"https://openalex.org/C2776606100","wikidata":"https://www.wikidata.org/wiki/Q423282","display_name":"Cyclohexanol","level":3,"score":0.8841285705566406},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7978070974349976},{"id":"https://openalex.org/C163638829","wikidata":"https://www.wikidata.org/wiki/Q900337","display_name":"Lewis acids and bases","level":3,"score":0.7801985740661621},{"id":"https://openalex.org/C2777702071","wikidata":"https://www.wikidata.org/wiki/Q130336","display_name":"Phenol","level":2,"score":0.7677024602890015},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7436361312866211},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.652758002281189},{"id":"https://openalex.org/C2777738585","wikidata":"https://www.wikidata.org/wiki/Q170744","display_name":"Ketone","level":2,"score":0.5310364961624146},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4620802402496338},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.447877436876297},{"id":"https://openalex.org/C2778077586","wikidata":"https://www.wikidata.org/wiki/Q181332","display_name":"Zeolite","level":3,"score":0.4375768303871155},{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.427923321723938}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1126/science.1179713","doi":"https://doi.org/10.1126/science.1179713","is_oa":false,"landing_page_url":"https://doi.org/10.1126/science.1179713","pdf_url":null,"source":{"id":"https://openalex.org/S3880285","display_name":"Science","issn_l":"0036-8075","issn":["0036-8075","0193-4511","1095-9203"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","erih-plus","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310315823","host_organization_name":"American Association for the Advancement of Science","host_organization_lineage":["https://openalex.org/P4310315823"],"host_organization_lineage_names":["American Association for the Advancement of Science"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Science","raw_type":"journal-article"},{"id":"pmid:19965472","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/19965472","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Science (New York, N.Y.)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":28,"referenced_works":["https://openalex.org/W1978042914","https://openalex.org/W1978879366","https://openalex.org/W1982550662","https://openalex.org/W1982723682","https://openalex.org/W1984861911","https://openalex.org/W1997498238","https://openalex.org/W1999732684","https://openalex.org/W2001808040","https://openalex.org/W2002896967","https://openalex.org/W2005962279","https://openalex.org/W2009047538","https://openalex.org/W2010422626","https://openalex.org/W2014349614","https://openalex.org/W2014501192","https://openalex.org/W2018779437","https://openalex.org/W2024823274","https://openalex.org/W2038713651","https://openalex.org/W2047375407","https://openalex.org/W2054563002","https://openalex.org/W2057856741","https://openalex.org/W2075366555","https://openalex.org/W2085560749","https://openalex.org/W2126969240","https://openalex.org/W2153036200","https://openalex.org/W2159262369","https://openalex.org/W2163910099","https://openalex.org/W2502043876","https://openalex.org/W4246452518"],"related_works":["https://openalex.org/W4381302015","https://openalex.org/W2902874157","https://openalex.org/W2955678295","https://openalex.org/W4406800928","https://openalex.org/W3097453164","https://openalex.org/W4234751417","https://openalex.org/W1971756988","https://openalex.org/W4400339719","https://openalex.org/W3216755809","https://openalex.org/W2775034949"],"abstract_inverted_index":{"Cyclohexanone":[0],"is":[1,23],"an":[2],"industrially":[3],"important":[4],"intermediate":[5],"in":[6,87],"the":[7,100,105,117],"synthesis":[8],"of":[9,21,37,107,116],"materials":[10],"such":[11,54],"as":[12,55],"nylon,":[13],"but":[14],"preparing":[15],"it":[16],"efficiently":[17],"through":[18],"direct":[19],"hydrogenation":[20,106,115],"phenol":[22,108],"hindered":[24],"by":[25],"over-reduction":[26],"to":[27,109],"cyclohexanol.":[28],"Here":[29],"we":[30],"report":[31],"that":[32,99],"a":[33,51,88],"previously":[34],"unappreciated":[35],"combination":[36],"two":[38],"common":[39],"commercial":[40],"catalysts-nanoparticulate":[41],"palladium":[42],"(supported":[43],"on":[44],"carbon,":[45],"alumina,":[46],"or":[47,86],"NaY":[48],"zeolite)":[49],"and":[50,75,95,111],"Lewis":[52,101],"acid":[53,102],"AlCl3-synergistically":[56],"promotes":[57],"this":[58],"reaction.":[59],"Conversion":[60],"exceeding":[61],"99.9%":[62],"was":[63,81],"achieved":[64],"with":[65],">99.9%":[66],"selectivity":[67],"within":[68],"7":[69],"hours":[70],"at":[71,83],"1.0-megapascal":[72],"hydrogen":[73],"pressure":[74],"50":[76],"degrees":[77],"C.":[78],"The":[79],"reaction":[80],"accelerated":[82],"higher":[84],"temperature":[85],"compressed":[89],"CO(2)":[90],"solvent":[91],"medium.":[92],"Preliminary":[93],"kinetic":[94],"spectroscopic":[96],"studies":[97],"suggest":[98],"sequentially":[103],"enhances":[104],"cyclohexanone":[110],"then":[112],"inhibits":[113],"further":[114],"ketone.":[118]},"counts_by_year":[{"year":2026,"cited_by_count":31},{"year":2025,"cited_by_count":47},{"year":2024,"cited_by_count":53},{"year":2023,"cited_by_count":44},{"year":2022,"cited_by_count":49},{"year":2021,"cited_by_count":61},{"year":2020,"cited_by_count":57},{"year":2019,"cited_by_count":40},{"year":2018,"cited_by_count":45},{"year":2017,"cited_by_count":43},{"year":2016,"cited_by_count":41},{"year":2015,"cited_by_count":45},{"year":2014,"cited_by_count":43},{"year":2013,"cited_by_count":37},{"year":2012,"cited_by_count":31}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}
