{"id":"https://openalex.org/W2050007464","doi":"https://doi.org/10.1039/c4ob02357a","title":"Differentiation of small alkane and alkyl halide constitutional isomers via encapsulation","display_name":"Differentiation of small alkane and alkyl halide constitutional isomers via encapsulation","publication_year":2014,"publication_date":"2014-12-15","ids":{"openalex":"https://openalex.org/W2050007464","doi":"https://doi.org/10.1039/c4ob02357a","mag":"2050007464","pmid":"https://pubmed.ncbi.nlm.nih.gov/25504155"},"language":"en","primary_location":{"id":"doi:10.1039/c4ob02357a","doi":"https://doi.org/10.1039/c4ob02357a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c4ob02357a","pdf_url":null,"source":{"id":"https://openalex.org/S179810352","display_name":"Organic & Biomolecular Chemistry","issn_l":"1477-0520","issn":["1477-0520","1477-0539"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic &amp; Biomolecular Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"Matthew R. Sullivan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I114832834","display_name":"Tulane University","ror":"https://ror.org/04vmvtb21","country_code":"US","type":"education","lineage":["https://openalex.org/I114832834"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Matthew R. Sullivan","raw_affiliation_strings":["Department of Chemistry","New Orleans","Tulane University","USA","Department of Chemistry, Tulane University, New Orleans, LA, 70118, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"New Orleans","institution_ids":[]},{"raw_affiliation_string":"Tulane University","institution_ids":["https://openalex.org/I114832834"]},{"raw_affiliation_string":"USA","institution_ids":[]},{"raw_affiliation_string":"Department of Chemistry, Tulane University, New Orleans, LA, 70118, USA","institution_ids":["https://openalex.org/I114832834"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5012045768","display_name":"Bruce C. Gibb","orcid":"https://orcid.org/0000-0002-4478-4084","observed_orcids":["https://orcid.org/0000-0002-4478-4084"]},"institutions":[{"id":"https://openalex.org/I114832834","display_name":"Tulane University","ror":"https://ror.org/04vmvtb21","country_code":"US","type":"education","lineage":["https://openalex.org/I114832834"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Bruce C. Gibb","raw_affiliation_strings":["Department of Chemistry","New Orleans","Tulane University","USA","Department of Chemistry, Tulane University, New Orleans, LA, 70118, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"New Orleans","institution_ids":[]},{"raw_affiliation_string":"Tulane University","institution_ids":["https://openalex.org/I114832834"]},{"raw_affiliation_string":"USA","institution_ids":[]},{"raw_affiliation_string":"Department of Chemistry, Tulane University, New Orleans, LA, 70118, USA","institution_ids":["https://openalex.org/I114832834"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5012045768"],"corresponding_institution_ids":["https://openalex.org/I114832834"],"apc_list":null,"apc_paid":null,"fwci":0.7339,"has_fulltext":false,"cited_by_count":11,"citation_normalized_percentile":{"value":0.66646596,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"13","issue":"6","first_page":"1869","last_page":"1877"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10532","display_name":"Molecular Sensors and Ion Detection","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11419","display_name":"Supramolecular Self-Assembly in Materials","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/host-guest-chemistry","display_name":"host-guest chemistry","score":0.8759999871253967},{"id":"https://openalex.org/keywords/encapsulation","display_name":"encapsulation","score":0.5740000009536743},{"id":"https://openalex.org/keywords/structural-isomers","display_name":"structural isomers","score":0.8920000195503235},{"id":"https://openalex.org/keywords/alkane-isomers","display_name":"alkane isomers","score":0.7549999952316284},{"id":"https://openalex.org/keywords/alkyl-halides","display_name":"alkyl halides","score":0.9200000166893005},{"id":"https://openalex.org/keywords/n-hexane","display_name":"n-hexane","score":0.8690000176429749},{"id":"https://openalex.org/keywords/self-sorting","display_name":"self-sorting","score":0.6399999856948853},{"id":"https://openalex.org/keywords/host-guest-complexation","display_name":"host-guest complexation","score":0.5299999713897705},{"id":"https://openalex.org/keywords/nmr-binding-studies","display_name":"NMR binding studies","score":0.6330000162124634}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9448030591011047},{"id":"https://openalex.org/C2778717364","wikidata":"https://www.wikidata.org/wiki/Q134192","display_name":"Butane","level":3,"score":0.8385314345359802},{"id":"https://openalex.org/C2776345496","wikidata":"https://www.wikidata.org/wiki/Q131189","display_name":"Propane","level":2,"score":0.7763804197311401},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.7590110898017883},{"id":"https://openalex.org/C2781327020","wikidata":"https://www.wikidata.org/wiki/Q41581","display_name":"Alkane","level":3,"score":0.7439450025558472},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.6952940225601196},{"id":"https://openalex.org/C2777207669","wikidata":"https://www.wikidata.org/wiki/Q43648","display_name":"Hydrocarbon","level":2,"score":0.6466713547706604},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2828037440776825},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.14170515537261963}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/c4ob02357a","doi":"https://doi.org/10.1039/c4ob02357a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c4ob02357a","pdf_url":null,"source":{"id":"https://openalex.org/S179810352","display_name":"Organic & Biomolecular Chemistry","issn_l":"1477-0520","issn":["1477-0520","1477-0539"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic &amp; Biomolecular Chemistry","raw_type":"journal-article"},{"id":"pmid:25504155","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/25504155","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic & biomolecular chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G6672011308","display_name":null,"funder_award_id":"CHE 1244024","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":36,"referenced_works":["https://openalex.org/W1967743905","https://openalex.org/W1971493096","https://openalex.org/W1984690321","https://openalex.org/W1987052717","https://openalex.org/W2007481348","https://openalex.org/W2011131705","https://openalex.org/W2013870051","https://openalex.org/W2015517515","https://openalex.org/W2027181729","https://openalex.org/W2028279608","https://openalex.org/W2039104539","https://openalex.org/W2041726179","https://openalex.org/W2046722009","https://openalex.org/W2047374880","https://openalex.org/W2057155675","https://openalex.org/W2063710534","https://openalex.org/W2063799098","https://openalex.org/W2072611698","https://openalex.org/W2079591552","https://openalex.org/W2082554384","https://openalex.org/W2083342343","https://openalex.org/W2083617041","https://openalex.org/W2088440349","https://openalex.org/W2100003552","https://openalex.org/W2118896268","https://openalex.org/W2130277649","https://openalex.org/W2131754023","https://openalex.org/W2139902274","https://openalex.org/W2147830504","https://openalex.org/W2157598818","https://openalex.org/W2160104545","https://openalex.org/W2171518995","https://openalex.org/W2315561311","https://openalex.org/W2322759533","https://openalex.org/W2341937827","https://openalex.org/W4246247403"],"related_works":["https://openalex.org/W7220754544","https://openalex.org/W617932628","https://openalex.org/W7039582676","https://openalex.org/W4399683475","https://openalex.org/W4317883014","https://openalex.org/W2072639625","https://openalex.org/W2165041377","https://openalex.org/W2150570431","https://openalex.org/W2550218163","https://openalex.org/W2951190049"],"abstract_inverted_index":{"Previously":[0],"we":[1,61],"have":[2],"demonstrated":[3,152],"that":[4,85],"host":[5,31,53,99],"1":[6,100],"is":[7,96,137],"capable":[8],"of":[9,16,29,50,67,70,73,76,92,132,134,145,173,191],"hydrocarbon":[10],"gas":[11],"separation":[12],"by":[13],"selective":[14],"sequestration":[15],"butane":[17],"from":[18],"a":[19,27,55,102,108,119],"mixture":[20],"with":[21,87,107],"propane":[22],"in":[23],"the":[24,30,48,68,171],"headspace":[25],"above":[26],"solution":[28],"(C.":[32],"L.":[33],"D.":[34],"Gibb,":[35,38],"B.":[36],"C.":[37],"J.":[39],"Am.":[40],"Chem.":[41],"Soc.,":[42],"2006,":[43],"128,":[44],"16498-16499).":[45],"Expanding":[46],"on":[47,64],"idea":[49],"using":[51],"this":[52],"as":[54],"means":[56],"to":[57,104,155,166],"affect":[58],"guest":[59,94],"discrimination,":[60],"report":[62],"here":[63],"NMR":[65],"studies":[66],"binding":[69,95,133,180],"constitutional":[71],"isomers":[72,136],"two":[74],"classes":[75,91],"small":[77],"molecules:":[78],"hexanes":[79],"and":[80,116,182,189],"chloropentanes.":[81],"Our":[82],"results":[83],"indicate":[84],"even":[86],"these":[88,135],"relatively":[89],"straightforward":[90],"molecules,":[93],"complicated.":[97],"Overall,":[98],"displays":[101],"preference":[103,120],"bind":[105],"guests":[106,123,151,174],"X-C(R2)-C(R2)-Me":[109],"(X":[110],"=":[111],"Cl":[112],"or":[113],"Me)":[114],"structure,":[115,183],"more":[117],"generally,":[118],"for":[121],"branched":[122],"rather":[124],"than":[125],"highly":[126],"flexible,":[127],"unbranched":[128],"derivatives.":[129],"The":[130],"complexity":[131],"magnified":[138],"when":[139],"considering":[140],"molecular":[141],"differentiation":[142],"between":[143,179,187],"pairs":[144],"guests.":[146],"In":[147],"such":[148],"cases,":[149],"different":[150,153],"propensities":[154],"self-sort;":[156],"some":[157,176],"self-sort":[158],"exclusively,":[159],"while":[160],"others":[161],"show":[162],"very":[163],"little":[164],"propensity":[165],"do":[167],"so.":[168],"However,":[169],"whereas":[170],"pool":[172],"reveals":[175],"general":[177],"correlations":[178],"strength":[181],"no":[184],"obvious":[185],"relationship":[186],"structure":[188],"degree":[190],"self-sorting":[192],"was":[193],"observed.":[194]},"counts_by_year":[{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":2},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":4}],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}
