{"id":"https://openalex.org/W2049459272","doi":"https://doi.org/10.1021/ja0615573","title":"Structure and Enhanced Reactivity Rates of the D5h Sc3N@C80 and Lu3N@C80 Metallofullerene Isomers: The Importance of the Pyracylene Motif","display_name":"Structure and Enhanced Reactivity Rates of the D5h Sc3N@C80 and Lu3N@C80 Metallofullerene Isomers: The Importance of the Pyracylene Motif","publication_year":2006,"publication_date":"2006-06-13","ids":{"openalex":"https://openalex.org/W2049459272","doi":"https://doi.org/10.1021/ja0615573","mag":"2049459272","pmid":"https://pubmed.ncbi.nlm.nih.gov/16802825"},"language":"en","primary_location":{"id":"doi:10.1021/ja0615573","doi":"https://doi.org/10.1021/ja0615573","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja0615573","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5018238644","display_name":"Ting Cai","orcid":"https://orcid.org/0000-0001-7510-9295","observed_orcids":["https://orcid.org/0000-0001-7510-9295"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]},{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ting Cai","raw_affiliation_strings":["Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616","institution_ids":["https://openalex.org/I84218800","https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5039921630","display_name":"Liaosa Xu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]},{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Liaosa Xu","raw_affiliation_strings":["Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616","institution_ids":["https://openalex.org/I84218800","https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5091382015","display_name":"Mark R. Anderson","orcid":"https://orcid.org/0000-0001-5627-4148","observed_orcids":["https://orcid.org/0000-0001-5627-4148"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]},{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mark R. Anderson","raw_affiliation_strings":["Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616","institution_ids":["https://openalex.org/I84218800","https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101196299","display_name":"Zhongxin Ge","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]},{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Zhongxin Ge","raw_affiliation_strings":["Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616","institution_ids":["https://openalex.org/I84218800","https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101124124","display_name":"Tianming Zuo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]},{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Tianming Zuo","raw_affiliation_strings":["Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616","institution_ids":["https://openalex.org/I84218800","https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5079679645","display_name":"Xuelei Wang","orcid":"https://orcid.org/0000-0001-5067-4730","observed_orcids":["https://orcid.org/0000-0001-5067-4730"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]},{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Xuelei Wang","raw_affiliation_strings":["Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616","institution_ids":["https://openalex.org/I84218800","https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009326683","display_name":"Marilyn M. Olmstead","orcid":"https://orcid.org/0000-0002-6160-1622","observed_orcids":["https://orcid.org/0000-0002-6160-1622"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]},{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Marilyn M. Olmstead","raw_affiliation_strings":["Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616","institution_ids":["https://openalex.org/I84218800","https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067879544","display_name":"Alan L. Balch","orcid":"https://orcid.org/0000-0002-8813-6281","observed_orcids":["https://orcid.org/0000-0002-8813-6281"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]},{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Alan L. Balch","raw_affiliation_strings":["Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616","institution_ids":["https://openalex.org/I84218800","https://openalex.org/I859038795"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5027026248","display_name":"Harry W. Gibson","orcid":"https://orcid.org/0000-0001-9178-6691","observed_orcids":["https://orcid.org/0000-0001-9178-6691"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]},{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Harry W. Gibson","raw_affiliation_strings":["Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616","institution_ids":["https://openalex.org/I84218800","https://openalex.org/I859038795"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5071786154","display_name":"Harry C. Dorn","orcid":"https://orcid.org/0000-0002-3150-5314","observed_orcids":["https://orcid.org/0000-0002-3150-5314"]},"institutions":[{"id":"https://openalex.org/I84218800","display_name":"University of California, Davis","ror":"https://ror.org/05rrcem69","country_code":"US","type":"education","lineage":["https://openalex.org/I84218800"]},{"id":"https://openalex.org/I859038795","display_name":"Virginia Tech","ror":"https://ror.org/02smfhw86","country_code":"US","type":"education","lineage":["https://openalex.org/I859038795"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Harry C. Dorn","raw_affiliation_strings":["Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Departments of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24060-0212, and University of California, Davis, California 95616","institution_ids":["https://openalex.org/I84218800","https://openalex.org/I859038795"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":7.6737,"has_fulltext":false,"cited_by_count":157,"citation_normalized_percentile":{"value":0.9833286,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"128","issue":"26","first_page":"8581","last_page":"8589"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10956","display_name":"Fullerene Chemistry and Applications","score":0.9965999722480774,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10956","display_name":"Fullerene Chemistry and Applications","score":0.9965999722480774,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12557","display_name":"Inorganic Chemistry and Materials","score":0.0010999999940395355,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12055","display_name":"Boron Compounds in Chemistry","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/2741","display_name":"Radiology, Nuclear Medicine and Imaging"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/sc3n-c80","display_name":"Sc3N@C80","score":0.9330000281333923},{"id":"https://openalex.org/keywords/metallofullerenes","display_name":"metallofullerenes","score":0.972000002861023},{"id":"https://openalex.org/keywords/diels-alder-reaction","display_name":"Diels-Alder reaction","score":0.8989999890327454},{"id":"https://openalex.org/keywords/1-3-dipolar-cycloaddition","display_name":"1,3-dipolar cycloaddition","score":0.9779999852180481},{"id":"https://openalex.org/keywords/fullerene-cage-structure","display_name":"fullerene cage structure","score":0.49799999594688416},{"id":"https://openalex.org/keywords/band-gap","display_name":"band gap","score":0.6050000190734863},{"id":"https://openalex.org/keywords/fullerene-adducts","display_name":"fullerene adducts","score":0.7289999723434448},{"id":"https://openalex.org/keywords/isomer-conversion","display_name":"isomer conversion","score":0.4300000071525574}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8741538524627686},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.7411990165710449},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.6646274328231812},{"id":"https://openalex.org/C2779664164","wikidata":"https://www.wikidata.org/wiki/Q898648","display_name":"Cycloaddition","level":3,"score":0.6529821157455444},{"id":"https://openalex.org/C2779167645","wikidata":"https://www.wikidata.org/wiki/Q420686","display_name":"Ylide","level":2,"score":0.5645282864570618},{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.5060276389122009},{"id":"https://openalex.org/C155860418","wikidata":"https://www.wikidata.org/wiki/Q863695","display_name":"Bond length","level":3,"score":0.4578825533390045},{"id":"https://openalex.org/C2777869211","wikidata":"https://www.wikidata.org/wiki/Q1147647","display_name":"Cyclic voltammetry","level":4,"score":0.4308483302593231},{"id":"https://openalex.org/C201194858","wikidata":"https://www.wikidata.org/wiki/Q898238","display_name":"Steric effects","level":2,"score":0.4302137494087219},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.42364197969436646},{"id":"https://openalex.org/C68381374","wikidata":"https://www.wikidata.org/wiki/Q258652","display_name":"Double bond","level":2,"score":0.41296449303627014},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.39317476749420166},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.16037362813949585},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.08414533734321594},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D003198","descriptor_name":"Computer Simulation","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D003500","descriptor_name":"Cyclization","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D004563","descriptor_name":"Electrochemistry","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D007536","descriptor_name":"Isomerism","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D007700","descriptor_name":"Kinetics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008187","descriptor_name":"Lutetium","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008956","descriptor_name":"Models, Chemical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008958","descriptor_name":"Models, Molecular","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D009942","descriptor_name":"Organometallic Compounds","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":false},{"descriptor_ui":"D009942","descriptor_name":"Organometallic Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D012538","descriptor_name":"Scandium","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D013997","descriptor_name":"Time Factors","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D014320","descriptor_name":"Triphenylmethyl Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D015394","descriptor_name":"Molecular Structure","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D018360","descriptor_name":"Crystallography, X-Ray","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D023303","descriptor_name":"Oxazolidinones","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D037741","descriptor_name":"Fullerenes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1021/ja0615573","doi":"https://doi.org/10.1021/ja0615573","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja0615573","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:16802825","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/16802825","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1865581822","display_name":"Metallofullerene Nanoplatform for Imaging & Treatment","funder_award_id":"R01CA119371","funder_id":"https://openalex.org/F4320337351","funder_display_name":"National Cancer Institute"}],"funders":[{"id":"https://openalex.org/F4320337351","display_name":"National Cancer Institute","ror":"https://ror.org/040gcmg81"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":41,"referenced_works":["https://openalex.org/W1494168269","https://openalex.org/W1613238598","https://openalex.org/W1674015533","https://openalex.org/W1677079521","https://openalex.org/W1963712833","https://openalex.org/W1967733626","https://openalex.org/W1974143524","https://openalex.org/W1979271488","https://openalex.org/W1983679562","https://openalex.org/W1984363765","https://openalex.org/W1986164512","https://openalex.org/W1993490230","https://openalex.org/W2011618527","https://openalex.org/W2015110118","https://openalex.org/W2016044314","https://openalex.org/W2021187273","https://openalex.org/W2022584373","https://openalex.org/W2029052484","https://openalex.org/W2033050479","https://openalex.org/W2040711210","https://openalex.org/W2041785309","https://openalex.org/W2042476195","https://openalex.org/W2043397641","https://openalex.org/W2048565323","https://openalex.org/W2066740735","https://openalex.org/W2068013292","https://openalex.org/W2080307937","https://openalex.org/W2086957099","https://openalex.org/W2094630859","https://openalex.org/W2094777378","https://openalex.org/W2095153601","https://openalex.org/W2096743407","https://openalex.org/W2100643402","https://openalex.org/W2100667298","https://openalex.org/W2101737897","https://openalex.org/W2105054788","https://openalex.org/W2108268430","https://openalex.org/W2134210000","https://openalex.org/W2134909467","https://openalex.org/W2159022139","https://openalex.org/W4255777388"],"related_works":["https://openalex.org/W2143088159","https://openalex.org/W2761558167","https://openalex.org/W2791240154","https://openalex.org/W1613238598","https://openalex.org/W1977145846","https://openalex.org/W2122558071","https://openalex.org/W2321600307","https://openalex.org/W2068452589","https://openalex.org/W2113530400","https://openalex.org/W1964008960"],"abstract_inverted_index":{"In":[0],"this":[1],"paper":[2],"we":[3],"report":[4],"enhanced":[5],"reactivity":[6,122,135],"of":[7,19,34,38,55,63,70,76,85,92,99,120,127,133,160,169,178,200],"the":[8,14,32,35,61,71,77,95,100,111,118,124,131,138,150,161,185,193,197,201,207,212],"D(5h)":[9,36,125,139,151,170,202],"isomers":[10,18,152],"in":[11,123,196],"comparison":[12],"with":[13,130,190],"more":[15],"common":[16],"I(h)":[17,162],"Sc(3)N@C(80)":[20,39,171,203],"and":[21,25,89,143,167,205,224],"Lu(3)N@C(80)":[22],"toward":[23],"Diels-Alder":[24],"1,3-dipolar":[26,176],"tritylazomethine":[27,179],"ylide":[28],"cycloaddition":[29,177],"reactions.":[30],"Also,":[31],"structure":[33],"isomer":[37,126],"has":[40],"been":[41,173],"determined":[42],"through":[43],"single-crystal":[44],"X-ray":[45],"diffraction":[46],"on":[47],"D(5h)-Sc(3)N@C(80).Ni(OEP).2benzene":[48],"(OEP":[49],"=":[50],"octaethylporphyrin).":[51],"The":[52,83,164,181],"Sc(3)N":[53],"portion":[54],"D(5h)-Sc(3)N@C(80)":[56],"is":[57,67,108,188,206],"strictly":[58],"planar,":[59],"but":[60],"plane":[62,75],"these":[64,116],"four":[65],"atoms":[66,98],"tipped":[68],"out":[69],"noncrystallographic,":[72],"horizontal":[73],"mirror":[74],"fullerene":[78],"by":[79],"30":[80],"degrees":[81],".":[82],"combination":[84],"short":[86],"bond":[87],"length":[88],"high":[90],"degree":[91],"pyramidization":[93],"for":[94,137,184],"central":[96],"carbon":[97],"pyracylene":[101,198],"sites":[102,119],"situated":[103],"along":[104],"a":[105],"belt":[106],"that":[107,115,149],"perpendicular":[109],"to":[110,220],"C(5)":[112],"axis":[113],"suggests":[114],"are":[117,228],"greatest":[121],"Sc(3)N@C(80).":[128],"Consistent":[129],"observation":[132],"higher":[134],"observed":[136],"isomers,":[140],"cyclic":[141],"voltammetry":[142],"molecular":[144],"orbital":[145],"(MO)":[146],"calculations":[147],"demonstrate":[148],"have":[153,172],"slightly":[154],"smaller":[155],"energy":[156],"gaps":[157],"than":[158],"those":[159],"isomers.":[163],"first":[165],"mono-":[166],"bis-adducts":[168],"synthesized":[174],"via":[175],"ylide.":[180],"NMR":[182],"spectrum":[183],"monoadduct":[186,215],"2b":[187],"consistent":[189],"reaction":[191],"at":[192],"6,6-ring":[194],"juncture":[195],"unit":[199],"cage":[204],"thermodynamically":[208],"stable":[209],"isomer.":[210],"On":[211],"other":[213,221],"hand,":[214],"2a":[216],"undergoes":[217],"thermal":[218],"conversion":[219],"isomeric":[222],"monoadducts,":[223],"three":[225],"possible":[226],"structures":[227],"proposed.":[229]},"counts_by_year":[{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":7},{"year":2021,"cited_by_count":6},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":6},{"year":2018,"cited_by_count":9},{"year":2017,"cited_by_count":11},{"year":2016,"cited_by_count":6},{"year":2015,"cited_by_count":6},{"year":2014,"cited_by_count":5},{"year":2013,"cited_by_count":10},{"year":2012,"cited_by_count":10}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}