{"id":"https://openalex.org/W2046559751","doi":"https://doi.org/10.1002/pol.1982.180200110","title":"Poly(P\u2010phenylene sulfide) hexafluoroarsenate: A novel conducting polymer","display_name":"Poly(P\u2010phenylene sulfide) hexafluoroarsenate: A novel conducting polymer","publication_year":1982,"publication_date":"1982-01-01","ids":{"openalex":"https://openalex.org/W2046559751","doi":"https://doi.org/10.1002/pol.1982.180200110","mag":"2046559751"},"language":"en","primary_location":{"id":"doi:10.1002/pol.1982.180200110","doi":"https://doi.org/10.1002/pol.1982.180200110","is_oa":false,"landing_page_url":"https://doi.org/10.1002/pol.1982.180200110","pdf_url":null,"source":{"id":"https://openalex.org/S4210201723","display_name":"Journal of Polymer Science Polymer Physics Edition","issn_l":"0098-1273","issn":["0098-1273","1542-9385"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science: Polymer Physics Edition","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110193087","display_name":"Thomas Curtis Clarke","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1341412227","display_name":"IBM (United States)","ror":"https://ror.org/05hh8d621","country_code":"US","type":"company","lineage":["https://openalex.org/I1341412227"]},{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"T. C. Clarke","raw_affiliation_strings":["IBM Research Laboratory, San Jose, California 95193"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Research Laboratory, San Jose, California 95193","institution_ids":["https://openalex.org/I1341412227","https://openalex.org/I4210085935"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036557139","display_name":"K. Keiji Kanazawa","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1341412227","display_name":"IBM (United States)","ror":"https://ror.org/05hh8d621","country_code":"US","type":"company","lineage":["https://openalex.org/I1341412227"]},{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"K. K. Kanazawa","raw_affiliation_strings":["IBM Research Laboratory, San Jose, California 95193"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Research Laboratory, San Jose, California 95193","institution_ids":["https://openalex.org/I1341412227","https://openalex.org/I4210085935"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5027060293","display_name":"V. Y. Lee","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1341412227","display_name":"IBM (United States)","ror":"https://ror.org/05hh8d621","country_code":"US","type":"company","lineage":["https://openalex.org/I1341412227"]},{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"V. Y. Lee","raw_affiliation_strings":["IBM Research Laboratory, San Jose, California 95193"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Research Laboratory, San Jose, California 95193","institution_ids":["https://openalex.org/I1341412227","https://openalex.org/I4210085935"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110041689","display_name":"John F. Rabolt","orcid":"https://orcid.org/0000-0003-4132-4266","observed_orcids":["https://orcid.org/0000-0003-4132-4266"]},"institutions":[{"id":"https://openalex.org/I1341412227","display_name":"IBM (United States)","ror":"https://ror.org/05hh8d621","country_code":"US","type":"company","lineage":["https://openalex.org/I1341412227"]},{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"J. F. Rabolt","raw_affiliation_strings":["IBM Research Laboratory, San Jose, California 95193"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Research Laboratory, San Jose, California 95193","institution_ids":["https://openalex.org/I1341412227","https://openalex.org/I4210085935"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038429579","display_name":"John R. Reynolds","orcid":"https://orcid.org/0000-0002-7417-4869","observed_orcids":["https://orcid.org/0000-0002-7417-4869"]},"institutions":[{"id":"https://openalex.org/I1341412227","display_name":"IBM (United States)","ror":"https://ror.org/05hh8d621","country_code":"US","type":"company","lineage":["https://openalex.org/I1341412227"]},{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"J. R. Reynolds","raw_affiliation_strings":["IBM Research Laboratory, San Jose, California 95193"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Research Laboratory, San Jose, California 95193","institution_ids":["https://openalex.org/I1341412227","https://openalex.org/I4210085935"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5113542221","display_name":"G. B. Street","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1341412227","display_name":"IBM (United States)","ror":"https://ror.org/05hh8d621","country_code":"US","type":"company","lineage":["https://openalex.org/I1341412227"]},{"id":"https://openalex.org/I4210085935","display_name":"IBM Research - Almaden","ror":"https://ror.org/005w8dd04","country_code":"US","type":"facility","lineage":["https://openalex.org/I1341412227","https://openalex.org/I4210085935","https://openalex.org/I4210114115"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"G. B. Street","raw_affiliation_strings":["IBM Research Laboratory, San Jose, California 95193"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IBM Research Laboratory, San Jose, California 95193","institution_ids":["https://openalex.org/I1341412227","https://openalex.org/I4210085935"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":12.8193,"has_fulltext":false,"cited_by_count":83,"citation_normalized_percentile":{"value":0.99346405,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":95},"biblio":{"volume":"20","issue":"1","first_page":"117","last_page":"130"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10660","display_name":"Conducting polymers and applications","score":0.9047999978065491,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10660","display_name":"Conducting polymers and applications","score":0.9047999978065491,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12084","display_name":"Synthesis and properties of polymers","score":0.07460000365972519,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10045","display_name":"Organic Electronics and Photovoltaics","score":0.005400000140070915,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/polyphenylene-sulfide","display_name":"polyphenylene sulfide","score":1.0},{"id":"https://openalex.org/keywords/hexafluoroarsenate","display_name":"hexafluoroarsenate","score":0.968999981880188},{"id":"https://openalex.org/keywords/conducting-polymers","display_name":"conducting polymers","score":0.847000002861023},{"id":"https://openalex.org/keywords/arsenic-pentafluoride","display_name":"arsenic pentafluoride","score":0.7480000257492065},{"id":"https://openalex.org/keywords/doping","display_name":"doping","score":0.7739999890327454},{"id":"https://openalex.org/keywords/p-type-conductivity","display_name":"p-type conductivity","score":0.6190000176429749},{"id":"https://openalex.org/keywords/seebeck-coefficient","display_name":"Seebeck coefficient","score":0.9120000004768372},{"id":"https://openalex.org/keywords/polymer-crystallinity","display_name":"polymer crystallinity","score":0.7839999794960022},{"id":"https://openalex.org/keywords/cross-linking","display_name":"crosslinking","score":0.8569999933242798},{"id":"https://openalex.org/keywords/polymer-derivatives","display_name":"polymer derivatives","score":0.4339999854564667}],"concepts":[{"id":"https://openalex.org/C46275449","wikidata":"https://www.wikidata.org/wiki/Q2458815","display_name":"Crystallinity","level":2,"score":0.8103927373886108},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.7637944221496582},{"id":"https://openalex.org/C2780596425","wikidata":"https://www.wikidata.org/wiki/Q221205","display_name":"Sulfide","level":2,"score":0.74156653881073},{"id":"https://openalex.org/C57863236","wikidata":"https://www.wikidata.org/wiki/Q1130571","display_name":"Doping","level":2,"score":0.6901705265045166},{"id":"https://openalex.org/C2775939985","wikidata":"https://www.wikidata.org/wiki/Q3232180","display_name":"Poly(p-phenylene)","level":3,"score":0.6572587490081787},{"id":"https://openalex.org/C2776026683","wikidata":"https://www.wikidata.org/wiki/Q43342","display_name":"Phenylene","level":3,"score":0.6331776976585388},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5812506079673767},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5811108946800232},{"id":"https://openalex.org/C131540310","wikidata":"https://www.wikidata.org/wiki/Q907564","display_name":"Conductivity","level":2,"score":0.5214614272117615},{"id":"https://openalex.org/C133495861","wikidata":"https://www.wikidata.org/wiki/Q412798","display_name":"Conductive polymer","level":3,"score":0.4181784689426422},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.3875255286693573},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.32227206230163574},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2999095320701599},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.07748419046401978},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/pol.1982.180200110","doi":"https://doi.org/10.1002/pol.1982.180200110","is_oa":false,"landing_page_url":"https://doi.org/10.1002/pol.1982.180200110","pdf_url":null,"source":{"id":"https://openalex.org/S4210201723","display_name":"Journal of Polymer Science Polymer Physics Edition","issn_l":"0098-1273","issn":["0098-1273","1542-9385"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science: Polymer Physics Edition","raw_type":"journal-article"},{"id":"pmh:ADA102290","doi":null,"is_oa":false,"landing_page_url":"http://oai.dtic.mil/oai/oai?&verb=getRecord&metadataPrefix=html&identifier=ADA102290","pdf_url":null,"source":{"id":"https://openalex.org/S4406923043","display_name":"Defense Technical Information Center (DTIC)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"DTIC AND NTIS","raw_type":"Text"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":28,"referenced_works":["https://openalex.org/W619968919","https://openalex.org/W1868310350","https://openalex.org/W1979428343","https://openalex.org/W1993209440","https://openalex.org/W1996322474","https://openalex.org/W1998933636","https://openalex.org/W2007578704","https://openalex.org/W2011216188","https://openalex.org/W2014096831","https://openalex.org/W2014722962","https://openalex.org/W2022819895","https://openalex.org/W2031906022","https://openalex.org/W2036241770","https://openalex.org/W2041907058","https://openalex.org/W2044270216","https://openalex.org/W2060806160","https://openalex.org/W2071261379","https://openalex.org/W2075764893","https://openalex.org/W2079519737","https://openalex.org/W2084771875","https://openalex.org/W2086189970","https://openalex.org/W2087103648","https://openalex.org/W2113183772","https://openalex.org/W2171497258","https://openalex.org/W2319129238","https://openalex.org/W2322048135","https://openalex.org/W2489796216","https://openalex.org/W4212973228"],"related_works":["https://openalex.org/W2070586958","https://openalex.org/W16544495","https://openalex.org/W2086138125","https://openalex.org/W1954291835","https://openalex.org/W2089723387","https://openalex.org/W2143889769","https://openalex.org/W2019000299","https://openalex.org/W2771526889","https://openalex.org/W7120668244","https://openalex.org/W2041907058"],"abstract_inverted_index":{"Abstract":[0],"Poly(p\u2010phenylene":[1],"sulfide)":[2],"(PPS)":[3],"is":[4,33,69],"a":[5,16,20],"melt\u2010":[6],"and":[7,48,89,96],"solution\u2010processible":[8],"polymer":[9,32,76],"which":[10],"on":[11],"treatment":[12],"with":[13,19,37,81],"AsF5":[14],"forms":[15],"blue\u2010black":[17],"material":[18],"conductivity":[21],"of":[22,40,50,62,64,72,74,85,91,94,98],"1\u201310":[23],"\u03a9\u22121":[24],"cm\u22121.":[25],"Thermopower":[26],"measurements":[27],"indicate":[28],"that":[29],"the":[30,41,44,60,65,75,79,87,92],"resulting":[31],"p":[34],"type,":[35],"consistent":[36],"partial":[38],"oxidation":[39],"PPS":[42,95],"by":[43],"AsF5.":[45,82],"The":[46,83],"rate":[47],"extent":[49],"this":[51],"doping":[52,93],"process":[53],"prove":[54],"to":[55,59],"be":[56],"particularly":[57],"sensitive":[58],"degree":[61],"crystallinity":[63],"starting":[66],"polymer.":[67],"There":[68],"also":[70],"evidence":[71],"crosslinking":[73],"chains":[77],"during":[78],"reaction":[80],"details":[84],"both":[86],"chemistry":[88],"physics":[90],"several":[97],"its":[99],"derivatives":[100],"are":[101],"presented.":[102]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-10-27T15:51:10.671819","created_date":"2016-06-24T00:00:00"}