{"id":"https://openalex.org/W2044892012","doi":"https://doi.org/10.1021/la0107805","title":"Surface Morphology and Molecular Chemical Structure of Poly(n-butyl methacrylate)/Polystyrene Blend Studied by Atomic Force Microscopy (AFM) and Sum Frequency Generation (SFG) Vibrational Spectroscopy","display_name":"Surface Morphology and Molecular Chemical Structure of Poly(n-butyl methacrylate)/Polystyrene Blend Studied by Atomic Force Microscopy (AFM) and Sum Frequency Generation (SFG) Vibrational Spectroscopy","publication_year":2002,"publication_date":"2002-01-26","ids":{"openalex":"https://openalex.org/W2044892012","doi":"https://doi.org/10.1021/la0107805","mag":"2044892012"},"language":"en","primary_location":{"id":"doi:10.1021/la0107805","doi":"https://doi.org/10.1021/la0107805","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la0107805","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5041836364","display_name":"Chunyan Chen","orcid":"https://orcid.org/0000-0001-9220-4569","observed_orcids":["https://orcid.org/0000-0001-9220-4569"]},"institutions":[{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Chunyan Chen","raw_affiliation_strings":["Department of Chemistry and Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109","institution_ids":["https://openalex.org/I27837315"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100440015","display_name":"Jie Wang","orcid":"https://orcid.org/0000-0001-8010-0500","observed_orcids":["https://orcid.org/0000-0001-8010-0500"]},"institutions":[{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jie Wang","raw_affiliation_strings":["Department of Chemistry and Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109","institution_ids":["https://openalex.org/I27837315"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020196350","display_name":"Sara E. Woodcock","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Sara E. Woodcock","raw_affiliation_strings":["Department of Chemistry and Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109","institution_ids":["https://openalex.org/I27837315"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5054123780","display_name":"Zhan Chen","orcid":"https://orcid.org/0000-0001-8687-8348","observed_orcids":["https://orcid.org/0000-0001-8687-8348"]},"institutions":[{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Zhan Chen","raw_affiliation_strings":["Department of Chemistry and Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109","institution_ids":["https://openalex.org/I27837315"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I27837315"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":5.2107,"has_fulltext":false,"cited_by_count":47,"citation_normalized_percentile":{"value":0.95315315,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"18","issue":"4","first_page":"1302","last_page":"1309"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":0.36079999804496765,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":0.36079999804496765,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.28690001368522644,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":0.10350000113248825,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/poly-butyl-methacrylate","display_name":"poly(butyl methacrylate)","score":0.9190000295639038},{"id":"https://openalex.org/keywords/polystyrene","display_name":"polystyrene","score":0.9990000128746033},{"id":"https://openalex.org/keywords/surface-morphology","display_name":"surface morphology","score":0.7720000147819519},{"id":"https://openalex.org/keywords/surface-segregation","display_name":"surface segregation","score":0.7590000033378601},{"id":"https://openalex.org/keywords/phenyl-group-orientation","display_name":"phenyl group orientation","score":0.8659999966621399},{"id":"https://openalex.org/keywords/surface-tension","display_name":"surface tension","score":0.6330000162124634},{"id":"https://openalex.org/keywords/domain-structure","display_name":"domain structure","score":0.4869999885559082},{"id":"https://openalex.org/keywords/cyclohexane","display_name":"cyclohexane","score":0.8960000276565552},{"id":"https://openalex.org/keywords/annealing","display_name":"annealing","score":0.7490000128746033},{"id":"https://openalex.org/keywords/solvent-effects","display_name":"solvent effects","score":0.8939999938011169},{"id":"https://openalex.org/keywords/surface-chemical-structure","display_name":"surface chemical structure","score":0.39500001072883606}],"concepts":[{"id":"https://openalex.org/C2777922577","wikidata":"https://www.wikidata.org/wiki/Q146243","display_name":"Polystyrene","level":3,"score":0.8135889768600464},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.630628228187561},{"id":"https://openalex.org/C2778237882","wikidata":"https://www.wikidata.org/wiki/Q211433","display_name":"Cyclohexane","level":2,"score":0.6102901697158813},{"id":"https://openalex.org/C6556556","wikidata":"https://www.wikidata.org/wiki/Q899239","display_name":"Contact angle","level":2,"score":0.5853578448295593},{"id":"https://openalex.org/C132050475","wikidata":"https://www.wikidata.org/wiki/Q736232","display_name":"Methacrylate","level":4,"score":0.503745973110199},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4889024794101715},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.4531649649143219},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.43818527460098267},{"id":"https://openalex.org/C160018778","wikidata":"https://www.wikidata.org/wiki/Q3123190","display_name":"Sum-frequency generation","level":4,"score":0.43684327602386475},{"id":"https://openalex.org/C499950583","wikidata":"https://www.wikidata.org/wiki/Q183252","display_name":"Morphology (biology)","level":2,"score":0.431692510843277},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.4301050305366516},{"id":"https://openalex.org/C8892853","wikidata":"https://www.wikidata.org/wiki/Q170749","display_name":"Surface tension","level":2,"score":0.41470348834991455},{"id":"https://openalex.org/C115537861","wikidata":"https://www.wikidata.org/wiki/Q7645993","display_name":"Surface modification","level":2,"score":0.4145958423614502},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.34357377886772156},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.27683180570602417},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.2685369849205017},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.23596301674842834},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.1380240023136139},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.10522785782814026},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.09270307421684265},{"id":"https://openalex.org/C78854221","wikidata":"https://www.wikidata.org/wiki/Q756033","display_name":"Nonlinear optics","level":3,"score":0.0},{"id":"https://openalex.org/C54355233","wikidata":"https://www.wikidata.org/wiki/Q7162","display_name":"Genetics","level":1,"score":0.0},{"id":"https://openalex.org/C86803240","wikidata":"https://www.wikidata.org/wiki/Q420","display_name":"Biology","level":0,"score":0.0},{"id":"https://openalex.org/C520434653","wikidata":"https://www.wikidata.org/wiki/Q38867","display_name":"Laser","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/la0107805","doi":"https://doi.org/10.1021/la0107805","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la0107805","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":34,"referenced_works":["https://openalex.org/W123543948","https://openalex.org/W583465461","https://openalex.org/W1978451062","https://openalex.org/W1986957283","https://openalex.org/W1988870851","https://openalex.org/W1991418495","https://openalex.org/W1994014080","https://openalex.org/W1995374596","https://openalex.org/W1995939926","https://openalex.org/W2017330172","https://openalex.org/W2022331936","https://openalex.org/W2026736298","https://openalex.org/W2040894300","https://openalex.org/W2041068952","https://openalex.org/W2047501009","https://openalex.org/W2048981720","https://openalex.org/W2049036427","https://openalex.org/W2051087226","https://openalex.org/W2056154520","https://openalex.org/W2058536206","https://openalex.org/W2066016457","https://openalex.org/W2074969682","https://openalex.org/W2085161139","https://openalex.org/W2093483432","https://openalex.org/W2093862063","https://openalex.org/W2108363120","https://openalex.org/W2111356108","https://openalex.org/W2121242766","https://openalex.org/W2137246310","https://openalex.org/W2153626526","https://openalex.org/W2165372810","https://openalex.org/W2312359470","https://openalex.org/W2598397112","https://openalex.org/W4246108954"],"related_works":["https://openalex.org/W1973229137","https://openalex.org/W2745886707","https://openalex.org/W2057324282","https://openalex.org/W2085793941","https://openalex.org/W2075469770","https://openalex.org/W2035594928","https://openalex.org/W2031761140","https://openalex.org/W1971585423","https://openalex.org/W2002650530","https://openalex.org/W2037904817"],"abstract_inverted_index":{"Sum":[0],"frequency":[1],"generation":[2],"(SFG)":[3],"vibrational":[4],"spectroscopy":[5],"and":[6,150,179],"atomic":[7],"force":[8],"microscopy":[9],"(AFM)":[10],"have":[11,187],"been":[12,168,189],"applied":[13],"to":[14,30,32,52,170],"study":[15],"the":[16,33,46,53,66,70,74,80,83,92,94,101,111,115,120,124,136,160,174,183],"poly(":[17],"n":[18],"-butyl":[19],"methacrylate)":[20],"(PBMA)/polystyrene":[21],"(PS)":[22],"blend":[23,34,75,84,138,162,176,184],"surfaces.":[24,163],"SFG":[25],"showed":[26,146],"that":[27,147],"PBMA":[28,63,90,151],"tended":[29],"segregate":[31],"surfaces":[35,139,152],"because":[36],"of":[37,62,69,82,114,119,130],"its":[38],"lower":[39],"surface":[40,49,54,81,125,185],"tension.":[41],"The":[42],"phenyl":[43,71,95,121],"groups":[44,72,96,122],"on":[45,73,79,110,135,159,173,182],"pure":[47,148],"PS":[48,131,149],"orientated":[50],"closely":[51],"normal":[55],"with":[56,85,140],"a":[57],"narrow":[58],"angle":[59,68,118],"distribution.":[60],"Presence":[61],"dramatically":[64],"affected":[65],"orientation":[67,117],"surface.":[76,112,177],"For":[77],"example,":[78],"only":[86],"4":[87],"wt":[88],"%":[89],"in":[91],"bulk,":[93],"would":[97],"tilt":[98],"more":[99],"toward":[100],"surface,":[102],"but":[103,155],"they":[104],"did":[105],"not":[106],"completely":[107],"lie":[108],"down":[109],"Because":[113],"larger":[116],"versus":[123],"normal,":[126],"no":[127],"ppp":[128],"signal":[129],"could":[132],"be":[133],"detected":[134],"PBMA/PS":[137,175],"our":[141],"experimental":[142],"geometry.":[143],"AFM":[144],"results":[145],"were":[153],"flat,":[154],"domain":[156],"structures":[157],"existed":[158],"polymer":[161],"Selective":[164],"solvent":[165,180],"cyclohexane":[166],"has":[167],"used":[169],"identify":[171],"species":[172],"Annealing":[178],"effects":[181],"morphology":[186],"also":[188],"investigated.":[190]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":5}],"updated_date":"2026-10-13T10:08:12.033832","created_date":"2016-06-24T00:00:00"}