{"id":"https://openalex.org/W2043779873","doi":"https://doi.org/10.1063/1.455820","title":"Chemistry of semiconductor clusters: A study of the reactions of size selected Si+n (n=3\u201324) with C2H4 using selected ion drift tube techniques","display_name":"Chemistry of semiconductor clusters: A study of the reactions of size selected Si+n (n=3\u201324) with C2H4 using selected ion drift tube techniques","publication_year":1989,"publication_date":"1989-04-01","ids":{"openalex":"https://openalex.org/W2043779873","doi":"https://doi.org/10.1063/1.455820","mag":"2043779873"},"language":"en","primary_location":{"id":"doi:10.1063/1.455820","doi":"https://doi.org/10.1063/1.455820","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.455820","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5063887646","display_name":"Martin F. Jarrold","orcid":"https://orcid.org/0000-0001-7084-176X","observed_orcids":["https://orcid.org/0000-0001-7084-176X"]},"institutions":[{"id":"https://openalex.org/I1283103587","display_name":"AT&T (United States)","ror":"https://ror.org/02bbd5539","country_code":"US","type":"company","lineage":["https://openalex.org/I1283103587"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"M. F. Jarrold","raw_affiliation_strings":["AT&T Bell Laboratories, Murray Hill, New Jersey 07974"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"AT&T Bell Laboratories, Murray Hill, New Jersey 07974","institution_ids":["https://openalex.org/I1283103587"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111334680","display_name":"J. E. Bower","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1283103587","display_name":"AT&T (United States)","ror":"https://ror.org/02bbd5539","country_code":"US","type":"company","lineage":["https://openalex.org/I1283103587"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"J. E. Bower","raw_affiliation_strings":["AT&T Bell Laboratories, Murray Hill, New Jersey 07974"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"AT&T Bell Laboratories, Murray Hill, New Jersey 07974","institution_ids":["https://openalex.org/I1283103587"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5112447867","display_name":"Kathleen M. Creegan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1283103587","display_name":"AT&T (United States)","ror":"https://ror.org/02bbd5539","country_code":"US","type":"company","lineage":["https://openalex.org/I1283103587"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"K. Creegan","raw_affiliation_strings":["AT&T Bell Laboratories, Murray Hill, New Jersey 07974"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"AT&T Bell Laboratories, Murray Hill, New Jersey 07974","institution_ids":["https://openalex.org/I1283103587"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I1283103587"],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":9.4545,"has_fulltext":false,"cited_by_count":115,"citation_normalized_percentile":{"value":0.99161596,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":97},"biblio":{"volume":"90","issue":"7","first_page":"3615","last_page":"3628"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":0.2517000138759613,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":0.2517000138759613,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":0.23319999873638153,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10956","display_name":"Fullerene Chemistry and Applications","score":0.05469999834895134,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/silicon-clusters","display_name":"silicon clusters","score":0.9670000076293945},{"id":"https://openalex.org/keywords/ethylene-adsorption","display_name":"ethylene adsorption","score":0.7570000290870667},{"id":"https://openalex.org/keywords/cluster-reactions","display_name":"cluster reactions","score":0.4090000092983246},{"id":"https://openalex.org/keywords/binding-energy","display_name":"binding energy","score":0.5759999752044678},{"id":"https://openalex.org/keywords/structural-isomers","display_name":"structural isomers","score":0.7260000109672546},{"id":"https://openalex.org/keywords/cluster-reactivity","display_name":"cluster reactivity","score":0.4519999921321869},{"id":"https://openalex.org/keywords/pi-bonding","display_name":"\u03c0-bonding","score":0.6359999775886536},{"id":"https://openalex.org/keywords/dehydrogenation","display_name":"dehydrogenation","score":0.7179999947547913},{"id":"https://openalex.org/keywords/rate-constants","display_name":"rate constants","score":0.5680000185966492}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8058727979660034},{"id":"https://openalex.org/C164866538","wikidata":"https://www.wikidata.org/wiki/Q367351","display_name":"Cluster (spacecraft)","level":2,"score":0.6517244577407837},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.6095096468925476},{"id":"https://openalex.org/C93282013","wikidata":"https://www.wikidata.org/wiki/Q420754","display_name":"Binding energy","level":2,"score":0.6063395738601685},{"id":"https://openalex.org/C544956773","wikidata":"https://www.wikidata.org/wiki/Q670","display_name":"Silicon","level":2,"score":0.6001096367835999},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.5666228532791138},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.5081534385681152},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5042580366134644},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.4968748390674591},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.4772860109806061},{"id":"https://openalex.org/C2992829418","wikidata":"https://www.wikidata.org/wiki/Q1255409","display_name":"Drift tube","level":3,"score":0.44116273522377014},{"id":"https://openalex.org/C175113610","wikidata":"https://www.wikidata.org/wiki/Q3394849","display_name":"Reaction rate","level":3,"score":0.41784948110580444},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.38380998373031616},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.3594319820404053},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3449380397796631},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.2598271071910858},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.2169816792011261},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.17527613043785095},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.10460624098777771},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1063/1.455820","doi":"https://doi.org/10.1063/1.455820","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.455820","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":63,"referenced_works":["https://openalex.org/W345590036","https://openalex.org/W1502110558","https://openalex.org/W1523417784","https://openalex.org/W1965189031","https://openalex.org/W1969440271","https://openalex.org/W1969921866","https://openalex.org/W1971094535","https://openalex.org/W1973032372","https://openalex.org/W1973442035","https://openalex.org/W1976539120","https://openalex.org/W1977073570","https://openalex.org/W1978254018","https://openalex.org/W1979349408","https://openalex.org/W1981218938","https://openalex.org/W1988734215","https://openalex.org/W1992478085","https://openalex.org/W1997166366","https://openalex.org/W2000351131","https://openalex.org/W2001035153","https://openalex.org/W2001107581","https://openalex.org/W2004945157","https://openalex.org/W2009387482","https://openalex.org/W2010198621","https://openalex.org/W2013396388","https://openalex.org/W2017845625","https://openalex.org/W2018333093","https://openalex.org/W2019737727","https://openalex.org/W2025653057","https://openalex.org/W2027925174","https://openalex.org/W2033229920","https://openalex.org/W2036122746","https://openalex.org/W2039806470","https://openalex.org/W2041153256","https://openalex.org/W2042669865","https://openalex.org/W2043209824","https://openalex.org/W2044320062","https://openalex.org/W2045084786","https://openalex.org/W2046325281","https://openalex.org/W2047446322","https://openalex.org/W2052651192","https://openalex.org/W2052977473","https://openalex.org/W2053514515","https://openalex.org/W2054622402","https://openalex.org/W2056977978","https://openalex.org/W2063632929","https://openalex.org/W2069438435","https://openalex.org/W2071752343","https://openalex.org/W2073136157","https://openalex.org/W2077053389","https://openalex.org/W2077899805","https://openalex.org/W2080195121","https://openalex.org/W2081794701","https://openalex.org/W2081922067","https://openalex.org/W2084504758","https://openalex.org/W2093047126","https://openalex.org/W2093412273","https://openalex.org/W2094755153","https://openalex.org/W2113011315","https://openalex.org/W2325331833","https://openalex.org/W2481312605","https://openalex.org/W2949461759","https://openalex.org/W2953089120","https://openalex.org/W3004750359"],"related_works":["https://openalex.org/W2002510929","https://openalex.org/W2952466993","https://openalex.org/W2512166944","https://openalex.org/W2069286474","https://openalex.org/W1971094535","https://openalex.org/W2014289852","https://openalex.org/W2951363365","https://openalex.org/W1984338975","https://openalex.org/W33288235","https://openalex.org/W1971436656"],"abstract_inverted_index":{"The":[0,44,62,73,135],"chemical":[1],"reactions":[2,63,117],"of":[3,38,70,104,118,124,128,146,181,194,233,255],"size":[4],"selected":[5,18],"Si+n":[6,243],"(n=3\u201324)":[7],"clusters":[8,170,221],"with":[9,50,252],"C2H4":[10,28,39,131,163,214,240,257],"have":[11,245],"been":[12,246],"studied":[13,65],"at":[14],"thermal":[15],"energies":[16,137,145],"using":[17],"ion":[19],"drift":[20],"tube":[21],"techniques.":[22],"Except":[23],"for":[24,88,155,178,186,230],"Si+3":[25],"(which":[26],"dehydrogenates":[27],"to":[29,58,96,114,132,152,167,204,223,238],"yield":[30],"Si3C2H+2)":[31],"the":[32,41,77,85,89,102,105,116,125,129,162,168,179,191,208,219,231,234,253],"dominant":[33],"products":[34],"arise":[35],"from":[36,201],"adsorption":[37,232],"onto":[40,218],"silicon":[42,169,220],"clusters.":[43,134,188],"reaction":[45],"rates":[46,86],"show":[47,249],"large":[48,250],"variations":[49,251],"cluster":[51,91],"size.":[52],"Si+13":[53],"and":[54,120,141],"Si+14":[55],"were":[56,64],"found":[57,185],"be":[59,153,199],"particularly":[60],"unreactive.":[61],"over":[66],"a":[67,172],"temperature":[68,78],"range":[69],"143\u2013298":[71],"K.":[72],"reactivity":[74],"increases":[75],"as":[76],"is":[79,93,165],"lowered":[80],"indicating":[81],"that":[82,161],"variation":[83],"in":[84],"observed":[87],"different":[90],"sizes":[92],"not":[94],"due":[95],"an":[97,122,195],"activation":[98],"barrier,":[99],"but":[100],"reflects":[101],"stability":[103],"SinC2H+4":[106],"adducts.":[107],"Statistical":[108],"phase":[109],"space":[110],"theory":[111],"was":[112,184],"used":[113],"model":[115],"Si+4\u2013Si+10":[119],"provide":[121],"estimate":[123],"binding":[126,136],"energy":[127],"first":[130,235],"these":[133],"vary":[138],"between":[139],"0.8":[140],"2.0":[142],"eV.":[143],"Binding":[144],"this":[147],"magnitude":[148],"are":[149],"too":[150],"small":[151],"accounted":[154],"by":[156,171,206],"strong":[157],"di-\u03c3":[158],"bonding,":[159],"suggesting":[160],"molecule":[164,215],"bound":[166],"weaker":[173],"\u03c0-bonding":[174],"interaction.":[175],"Kinetic":[176],"evidence":[177],"presence":[180],"structural":[182],"isomers":[183],"several":[187],"With":[189],"Si+9":[190],"relative":[192],"abundance":[193],"unreactive":[196],"isomer":[197],"could":[198],"changed":[200],"\u223c1%":[202],"up":[203],"17%":[205],"changing":[207],"source":[209],"conditions.":[210],"More":[211],"than":[212],"one":[213],"will":[216],"adsorb":[217,225],"(up":[222,237],"eight":[224],"on":[226,242],"Si+4).":[227],"Rate":[228],"constants":[229],"few":[236],"seven)":[239],"molecules":[241],"(n=4\u201310)":[244],"determined.":[247],"They":[248],"number":[254],"adsorbed":[256],"molecules.":[258]},"counts_by_year":[{"year":2021,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}