{"id":"https://openalex.org/W2042954596","doi":"https://doi.org/10.1039/tf9686403265","title":"Photolysis of aromatic azides. Part 4.\u2014Lifetimes of aromatic nitrenes and absolute rates of some of their reactions","display_name":"Photolysis of aromatic azides. Part 4.\u2014Lifetimes of aromatic nitrenes and absolute rates of some of their reactions","publication_year":1968,"publication_date":"1968-01-01","ids":{"openalex":"https://openalex.org/W2042954596","doi":"https://doi.org/10.1039/tf9686403265","mag":"2042954596"},"language":"en","primary_location":{"id":"doi:10.1039/tf9686403265","doi":"https://doi.org/10.1039/tf9686403265","is_oa":false,"landing_page_url":"https://doi.org/10.1039/tf9686403265","pdf_url":null,"source":{"id":"https://openalex.org/S164507617","display_name":"Transactions of the Faraday Society","issn_l":"0014-7672","issn":["0014-7672","2050-5647"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Trans. Faraday Soc.","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5062565910","display_name":"Arnost Reiser","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"A. Reiser","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5063118532","display_name":"F. W. Willets","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"F. W. Willets","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5066989231","display_name":"G. C. Terry","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"G. C. Terry","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":null,"display_name":"V. Williams","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"V. Williams","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5006950876","display_name":"R. Marley","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"R. Marley","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":2.2396,"has_fulltext":false,"cited_by_count":120,"citation_normalized_percentile":{"value":0.85941196,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"64","issue":"0","first_page":"3265","last_page":"3275"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13253","display_name":"Chemical Reactions and Mechanisms","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13253","display_name":"Chemical Reactions and Mechanisms","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12251","display_name":"Synthesis and Catalytic Reactions","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/aromatic-azides","display_name":"aromatic azides","score":0.9760000109672546},{"id":"https://openalex.org/keywords/triplet-nitrene","display_name":"triplet nitrene","score":0.8980000019073486},{"id":"https://openalex.org/keywords/hydrogen-abstraction","display_name":"hydrogen abstraction","score":0.8050000071525574},{"id":"https://openalex.org/keywords/diffusion-limited-reactions","display_name":"diffusion-controlled reaction","score":0.7210000157356262},{"id":"https://openalex.org/keywords/intramolecular-hydrogen-abstraction","display_name":"intramolecular hydrogen abstraction","score":0.7250000238418579},{"id":"https://openalex.org/keywords/poly-methyl-methacrylate","display_name":"poly(methyl methacrylate)","score":0.878000020980835},{"id":"https://openalex.org/keywords/reaction-rate","display_name":"reaction rate","score":0.38499999046325684}],"concepts":[{"id":"https://openalex.org/C38489247","wikidata":"https://www.wikidata.org/wiki/Q413110","display_name":"Nitrene","level":3,"score":0.930185079574585},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8924870491027832},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.625457763671875},{"id":"https://openalex.org/C81022585","wikidata":"https://www.wikidata.org/wiki/Q5954884","display_name":"Hydrogen atom abstraction","level":3,"score":0.6216909885406494},{"id":"https://openalex.org/C512968161","wikidata":"https://www.wikidata.org/wiki/Q556","display_name":"Hydrogen","level":2,"score":0.5107462406158447},{"id":"https://openalex.org/C54582936","wikidata":"https://www.wikidata.org/wiki/Q16814","display_name":"Photodissociation","level":2,"score":0.47710520029067993},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.45037874579429626},{"id":"https://openalex.org/C2777922577","wikidata":"https://www.wikidata.org/wiki/Q146243","display_name":"Polystyrene","level":3,"score":0.4498054087162018},{"id":"https://openalex.org/C13472781","wikidata":"https://www.wikidata.org/wiki/Q5457567","display_name":"Flash photolysis","level":4,"score":0.4297350347042084},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.19455796480178833},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.1558171510696411},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.1136293113231659},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0771830677986145},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/tf9686403265","doi":"https://doi.org/10.1039/tf9686403265","is_oa":false,"landing_page_url":"https://doi.org/10.1039/tf9686403265","pdf_url":null,"source":{"id":"https://openalex.org/S164507617","display_name":"Transactions of the Faraday Society","issn_l":"0014-7672","issn":["0014-7672","2050-5647"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Trans. Faraday Soc.","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2466886129","https://openalex.org/W2592024658","https://openalex.org/W2060522924","https://openalex.org/W1994655284","https://openalex.org/W2953145354","https://openalex.org/W1971268441","https://openalex.org/W2021543697","https://openalex.org/W2135443898","https://openalex.org/W2582183311","https://openalex.org/W2046003689"],"abstract_inverted_index":{"The":[0],"transients":[1],"in":[2,27,31,42,114,128],"the":[3,53,58,73,77,122,129,156,166],"flash":[4],"photolysis":[5],"of":[6,25,44,57,102,124,131,162],"several":[7,32],"aromatic":[8,89],"azides":[9],"are":[10,20,40],"identified":[11],"as":[12],"triplet":[13],"nitrenes":[14],"by":[15,87,112,121],"their":[16],"spectra.":[17],"Their":[18],"half-lives":[19],"determined":[21],"over":[22],"a":[23,92,98],"range":[24],"concentrations":[26],"hexane,":[28],"ethanol":[29],"and":[30,39,55,120],"polymeric":[33,142],"matrices":[34,117],"(polystyrene,":[35],"sucrose":[36],"benzoate,":[37],"polymethylmethacrylate)":[38],"interpreted":[41],"terms":[43],"three":[45],"processes":[46],":":[47],"nitrene":[48,59,90],"recombination,":[49],"hydrogen":[50,85,126,144],"abstraction":[51,86,127,145],"from":[52,150],"solvent":[54],"reaction":[56,78],"with":[60,79],"an":[61,80,88],"azido":[62,81],"group.":[63,82],"Recombination":[64],"is":[65,91,110,146,159],"diffusion-controlled":[66],"(rate":[67],"constant":[68],"\u223c109":[69],"1.":[70],"mole\u20131":[71],"sec\u20131);":[72],"same":[74],"applies":[75],"to":[76,97,133,152],"In":[83,140],"contrast,":[84],"comparatively":[93],"slow":[94],"process,":[95],"corresponding":[96],"life-time":[99],"(in":[100],"ethanol)":[101],"about":[103],"2":[104,153],"\u00d7":[105,137],"10\u20134":[106,138],"sec.":[107],"This":[108],"value":[109],"corroborated":[111],"experiments":[113],"soft":[115],"polystyrene":[116],"(half-life":[118,135],"10\u20133sec)":[119],"rate":[123],"intramolecular":[125],"cyclization":[130],"2-nitrenobiphenyl":[132],"carbazole":[134],"8":[136],"sec).":[139,154],"hard":[141],"matrices,":[143],"considerably":[147],"slower":[148],"(half-lives":[149],"0.1":[151],"Here":[155],"rate-determining":[157],"step":[158],"configurational":[160],"diffusion":[161],"CH":[163],"bonds":[164],"towards":[165],"electron-deficient":[167],"nitrogen.":[168]},"counts_by_year":[{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":3},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":3},{"year":2015,"cited_by_count":2},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":3}],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2016-06-24T00:00:00"}