{"id":"https://openalex.org/W2039128367","doi":"https://doi.org/10.1002/bbpc.19900940403","title":"Homogeneous and Heterogeneous Electron Transfer Rates of the Tetrathiafulvalene\u2010System","display_name":"Homogeneous and Heterogeneous Electron Transfer Rates of the Tetrathiafulvalene\u2010System","publication_year":1990,"publication_date":"1990-04-01","ids":{"openalex":"https://openalex.org/W2039128367","doi":"https://doi.org/10.1002/bbpc.19900940403","mag":"2039128367"},"language":"en","primary_location":{"id":"doi:10.1002/bbpc.19900940403","doi":"https://doi.org/10.1002/bbpc.19900940403","is_oa":false,"landing_page_url":"https://doi.org/10.1002/bbpc.19900940403","pdf_url":null,"source":{"id":"https://openalex.org/S4306504167","display_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","issn_l":"0005-9021","issn":["0005-9021"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111949560","display_name":"G\u00fcnter Grampp","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"G\u00fcnter Grampp","raw_affiliation_strings":["Institut fu\u0308r Physikalische und Theoretische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Erlangen, Federal Republic of Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Physikalische und Theoretische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Erlangen, Federal Republic of Germany","institution_ids":["https://openalex.org/I181369854"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006001315","display_name":"Andrzej Kapturkiewicz","orcid":"https://orcid.org/0000-0002-7934-5997","observed_orcids":["https://orcid.org/0000-0002-7934-5997"]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]},{"id":"https://openalex.org/I4210157029","display_name":"Institute of Physical Chemistry","ror":"https://ror.org/05e830h62","country_code":"PL","type":"facility","lineage":["https://openalex.org/I4210157029","https://openalex.org/I99542240"]},{"id":"https://openalex.org/I99542240","display_name":"Polish Academy of Sciences","ror":"https://ror.org/01dr6c206","country_code":"PL","type":"government","lineage":["https://openalex.org/I99542240"]}],"countries":["DE","PL"],"is_corresponding":false,"raw_author_name":"Andrej Kapturkiewicz","raw_affiliation_strings":["Institut fu\u0308r Physikalische und Theoretische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Erlangen, Federal Republic of Germany","On leave of the Institute of Physical Chemistry of the Polish Academy of Sciences, with an Alexander v. Humboldt fellowship"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Physikalische und Theoretische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Erlangen, Federal Republic of Germany","institution_ids":["https://openalex.org/I181369854"]},{"raw_affiliation_string":"On leave of the Institute of Physical Chemistry of the Polish Academy of Sciences, with an Alexander v. Humboldt fellowship","institution_ids":["https://openalex.org/I4210157029","https://openalex.org/I99542240"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5045569282","display_name":"Walther Jaenicke","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Walther Jaenicke","raw_affiliation_strings":["Institut fu\u0308r Physikalische und Theoretische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Erlangen, Federal Republic of Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Physikalische und Theoretische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Erlangen, Federal Republic of Germany","institution_ids":["https://openalex.org/I181369854"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":3.6171,"has_fulltext":false,"cited_by_count":42,"citation_normalized_percentile":{"value":0.93940947,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":95},"biblio":{"volume":"94","issue":"4","first_page":"439","last_page":"447"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11758","display_name":"Organic and Molecular Conductors Research","score":0.8345000147819519,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11758","display_name":"Organic and Molecular Conductors Research","score":0.8345000147819519,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.08209999650716782,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.05889999866485596,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/tetrathiafulvalene","display_name":"tetrathiafulvalene","score":0.9869999885559082},{"id":"https://openalex.org/keywords/electron-transfer-rate","display_name":"electron transfer rate","score":0.6700000166893005},{"id":"https://openalex.org/keywords/homogeneous-electron-transfer","display_name":"homogeneous electron transfer","score":0.7289999723434448},{"id":"https://openalex.org/keywords/heterogeneous-electron-transfer","display_name":"heterogeneous electron transfer","score":0.9810000061988831},{"id":"https://openalex.org/keywords/electron-self-exchange","display_name":"electron self-exchange","score":0.7979999780654907},{"id":"https://openalex.org/keywords/marcus-theory","display_name":"Marcus theory","score":0.8190000057220459},{"id":"https://openalex.org/keywords/reorganization-energy","display_name":"reorganization energy","score":0.6050000190734863},{"id":"https://openalex.org/keywords/geometric-factor","display_name":"geometric factor","score":0.5120000243186951},{"id":"https://openalex.org/keywords/solvent-polarity","display_name":"solvent polarity","score":0.5130000114440918},{"id":"https://openalex.org/keywords/electrode-adsorption","display_name":"electrode adsorption","score":0.5600000023841858},{"id":"https://openalex.org/keywords/counterion-adsorption","display_name":"counterion adsorption","score":0.7889999747276306},{"id":"https://openalex.org/keywords/activation-parameters","display_name":"activation parameters","score":0.4359999895095825}],"concepts":[{"id":"https://openalex.org/C2778421084","wikidata":"https://www.wikidata.org/wiki/Q2179180","display_name":"Tetrathiafulvalene","level":3,"score":0.7930279970169067},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6858721971511841},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.5959856510162354},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.5870232582092285},{"id":"https://openalex.org/C2776029896","wikidata":"https://www.wikidata.org/wiki/Q3935810","display_name":"Relaxation (psychology)","level":2,"score":0.5509313344955444},{"id":"https://openalex.org/C2777869211","wikidata":"https://www.wikidata.org/wiki/Q1147647","display_name":"Cyclic voltammetry","level":4,"score":0.48398900032043457},{"id":"https://openalex.org/C2776617069","wikidata":"https://www.wikidata.org/wiki/Q25111100","display_name":"Dithiol","level":2,"score":0.4755373001098633},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.4553144872188568},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.43197306990623474},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.3971659541130066},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.34336066246032715},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.32706499099731445},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.2345103621482849},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.21620073914527893},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.18038028478622437},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.09163066744804382},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0903729498386383},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08894410729408264},{"id":"https://openalex.org/C15744967","wikidata":"https://www.wikidata.org/wiki/Q9418","display_name":"Psychology","level":0,"score":0.0},{"id":"https://openalex.org/C77805123","wikidata":"https://www.wikidata.org/wiki/Q161272","display_name":"Social psychology","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/bbpc.19900940403","doi":"https://doi.org/10.1002/bbpc.19900940403","is_oa":false,"landing_page_url":"https://doi.org/10.1002/bbpc.19900940403","pdf_url":null,"source":{"id":"https://openalex.org/S4306504167","display_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","issn_l":"0005-9021","issn":["0005-9021"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":67,"referenced_works":["https://openalex.org/W1498404029","https://openalex.org/W1594749659","https://openalex.org/W1595560306","https://openalex.org/W1601422968","https://openalex.org/W1974708164","https://openalex.org/W1975019668","https://openalex.org/W1975590978","https://openalex.org/W1975898147","https://openalex.org/W1977184192","https://openalex.org/W1978483959","https://openalex.org/W1982062565","https://openalex.org/W1984410957","https://openalex.org/W1985543955","https://openalex.org/W1985556891","https://openalex.org/W1988457665","https://openalex.org/W1992128155","https://openalex.org/W1996823187","https://openalex.org/W1997777572","https://openalex.org/W2001270915","https://openalex.org/W2001696262","https://openalex.org/W2005505456","https://openalex.org/W2008536746","https://openalex.org/W2008631597","https://openalex.org/W2010446932","https://openalex.org/W2012482917","https://openalex.org/W2013159783","https://openalex.org/W2016090732","https://openalex.org/W2019194950","https://openalex.org/W2019699386","https://openalex.org/W2022427677","https://openalex.org/W2022660517","https://openalex.org/W2024368762","https://openalex.org/W2026686862","https://openalex.org/W2028163978","https://openalex.org/W2035656059","https://openalex.org/W2036610165","https://openalex.org/W2037254453","https://openalex.org/W2046777020","https://openalex.org/W2049778013","https://openalex.org/W2050566437","https://openalex.org/W2054784420","https://openalex.org/W2056592537","https://openalex.org/W2059099979","https://openalex.org/W2061068348","https://openalex.org/W2070820417","https://openalex.org/W2076004384","https://openalex.org/W2077973224","https://openalex.org/W2078629529","https://openalex.org/W2083088477","https://openalex.org/W2085059324","https://openalex.org/W2085266415","https://openalex.org/W2086864852","https://openalex.org/W2089186259","https://openalex.org/W2090084145","https://openalex.org/W2091237955","https://openalex.org/W2091492487","https://openalex.org/W2104166397","https://openalex.org/W2107774245","https://openalex.org/W2113274671","https://openalex.org/W2133241382","https://openalex.org/W2161435083","https://openalex.org/W2312861382","https://openalex.org/W2325776576","https://openalex.org/W2330576647","https://openalex.org/W2490969086","https://openalex.org/W2950452300","https://openalex.org/W3022618257"],"related_works":["https://openalex.org/W2081258048","https://openalex.org/W4239497882","https://openalex.org/W2334608208","https://openalex.org/W2053915177","https://openalex.org/W2078815528","https://openalex.org/W2041909900","https://openalex.org/W2167311569","https://openalex.org/W2100845036","https://openalex.org/W1975512671","https://openalex.org/W4239160294"],"abstract_inverted_index":{"Abstract":[0],"Using":[1],"ESR":[2],"spectroscopy":[3],"and":[4,12,31,89,108,121,133],"cyclic":[5],"voltammetry":[6],"the":[7,18,46,56,66,72,77,79,104,115,118,126,137,143,148,164,167,171],"rate":[8,41,138],"constants":[9,42,139],"of":[10,28,62,68,114,136,150,163,166],"homogeneous":[11,119],"heterogeneous":[13,127],"electron":[14],"self":[15],"exchange":[16],"in":[17,26,60,71],"system":[19],"TTF/TTF":[20],"were":[21,43],"measured":[22],"at":[23],"different":[24,29],"temperatures":[25],"solvents":[27],"polarities":[30],"relaxation":[32,74],"times":[33],"(TTF":[34],"=":[35,37,83,95,100],"tetrathiafulvalene":[36],"2\u2010(1,3\u2010dithiol\u20102\u2010ylidene)\u20101,3":[38],"dithiol).":[39],"The":[40],"expressed":[44],"by":[45,155,160],"preequilibrium":[47],"encounter":[48],"model":[49,92],"for":[50,65],"adiabatic":[51],"processes.":[52],"For":[53],"both":[54],"reactions":[55],"results":[57],"are":[58],"discussed":[59],"terms":[61,135],"Marcus's":[63],"theory":[64],"reorganization":[67],"ellipsoidal":[69],"molecules":[70],"overdamped":[73],"case.":[75],"From":[76],"experiments":[78],"geometric":[80],"term":[81],"g":[82],"1/r\u0304":[84],"\u2212":[85],"1/d'":[86],"was":[87],"derived":[88],"compared":[90],"with":[91,142],"calculations":[93],"r\u0304":[94],"mean":[96],"molecular":[97],"radius,":[98],"d'":[99,158],"formal":[101],"distance":[102],"between":[103],"reactants":[105,116],"resp.":[106],"reactant":[107],"image":[109],"charge).":[110],"Approximately":[111],"interaction":[112],"energies":[113],"(in":[117,125],"case)":[120,128],"double":[122],"layer":[123],"correction":[124],"can":[129],"be":[130],"neglected.":[131],"Preexponential":[132],"activation":[134],"agree":[140],"satisfactorily":[141],"theory.":[144],"g(het)":[145],"is":[146,153],"about":[147],"tenfold":[149],"g(hom).":[151],"This":[152],"explained":[154],"an":[156],"increased":[157],"caused":[159],"strong":[161],"adsorption":[162],"counterions":[165],"supporting":[168],"electrolyte":[169],"on":[170],"electrode.":[172]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2015,"cited_by_count":2},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-24T09:50:30.924529","created_date":"2016-06-24T00:00:00"}