{"id":"https://openalex.org/W2038247199","doi":"https://doi.org/10.1021/ac00085a021","title":"Temperature-Jump Investigation of Sorption/Desorption Kinetics at Reversed-Phase Chromatographic Silica/Solution Interfaces","display_name":"Temperature-Jump Investigation of Sorption/Desorption Kinetics at Reversed-Phase Chromatographic Silica/Solution Interfaces","publication_year":1994,"publication_date":"1994-07-01","ids":{"openalex":"https://openalex.org/W2038247199","doi":"https://doi.org/10.1021/ac00085a021","mag":"2038247199"},"language":"en","primary_location":{"id":"doi:10.1021/ac00085a021","doi":"https://doi.org/10.1021/ac00085a021","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ac00085a021","pdf_url":null,"source":{"id":"https://openalex.org/S191963794","display_name":"Analytical Chemistry","issn_l":"0003-2700","issn":["0003-2700","1520-6882"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","jufo-3","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Analytical Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.osti.gov/servlets/purl/2481361","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5015892284","display_name":"Scott W. Waite","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I223532165","display_name":"University of Utah","ror":"https://ror.org/03r0ha626","country_code":"US","type":"education","lineage":["https://openalex.org/I223532165"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"S. W. Waite","raw_affiliation_strings":["University of Utah,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Utah,","institution_ids":["https://openalex.org/I223532165"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5011717530","display_name":"David B. Marshall","orcid":"https://orcid.org/0000-0002-8313-1123","observed_orcids":["https://orcid.org/0000-0002-8313-1123"]},"institutions":[{"id":"https://openalex.org/I223532165","display_name":"University of Utah","ror":"https://ror.org/03r0ha626","country_code":"US","type":"education","lineage":["https://openalex.org/I223532165"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"D. B. Marshall","raw_affiliation_strings":["University of Utah,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Utah,","institution_ids":["https://openalex.org/I223532165"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5078927573","display_name":"Joel Mark Harris","orcid":"https://orcid.org/0000-0002-7081-8188","observed_orcids":["https://orcid.org/0000-0002-7081-8188"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"J. M. Harris","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.1195,"has_fulltext":true,"cited_by_count":23,"citation_normalized_percentile":{"value":0.86329912,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"66","issue":"13","first_page":"2052","last_page":"2061"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10908","display_name":"Analytical Chemistry and Chromatography","score":0.9951000213623047,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10908","display_name":"Analytical Chemistry and Chromatography","score":0.9951000213623047,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13604","display_name":"Adsorption, diffusion, and thermodynamic properties of materials","score":0.003700000001117587,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10412","display_name":"Microfluidic and Capillary Electrophoresis Applications","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/sorption-kinetics","display_name":"sorption kinetics","score":0.9700000286102295},{"id":"https://openalex.org/keywords/desorption-kinetics","display_name":"desorption kinetics","score":0.9950000047683716},{"id":"https://openalex.org/keywords/temperature-jump-relaxation","display_name":"temperature-jump relaxation","score":0.8370000123977661},{"id":"https://openalex.org/keywords/reversed-phase-liquid-chromatography","display_name":"reversed-phase liquid chromatography","score":0.8830000162124634},{"id":"https://openalex.org/keywords/1-anilino-8-naphthalene-sulfonate","display_name":"1-anilino-8-naphthalene sulfonate","score":0.9110000133514404},{"id":"https://openalex.org/keywords/fluorescent-probes","display_name":"fluorescent probes","score":0.7110000252723694},{"id":"https://openalex.org/keywords/ionic-solutes","display_name":"ionic solutes","score":0.6710000038146973},{"id":"https://openalex.org/keywords/adsorption-rate","display_name":"adsorption rate","score":0.6859999895095825},{"id":"https://openalex.org/keywords/band-broadening","display_name":"band broadening","score":0.7570000290870667},{"id":"https://openalex.org/keywords/mobile-phase-composition","display_name":"mobile phase composition","score":0.5370000004768372}],"concepts":[{"id":"https://openalex.org/C162711632","wikidata":"https://www.wikidata.org/wiki/Q905514","display_name":"Desorption","level":3,"score":0.6725994944572449},{"id":"https://openalex.org/C58445606","wikidata":"https://www.wikidata.org/wiki/Q898533","display_name":"Sorption","level":3,"score":0.6500868201255798},{"id":"https://openalex.org/C2778447006","wikidata":"https://www.wikidata.org/wiki/Q1156474","display_name":"Icon","level":2,"score":0.6408771276473999},{"id":"https://openalex.org/C2778805511","wikidata":"https://www.wikidata.org/wiki/Q1713","display_name":"Citation","level":2,"score":0.6376230716705322},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.4988272190093994},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.44817838072776794},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.34048885107040405},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.32588648796081543},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.28948819637298584},{"id":"https://openalex.org/C136764020","wikidata":"https://www.wikidata.org/wiki/Q466","display_name":"World Wide Web","level":1,"score":0.2567901611328125},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.20528441667556763},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.1751222014427185},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.13579070568084717},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ac00085a021","doi":"https://doi.org/10.1021/ac00085a021","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ac00085a021","pdf_url":null,"source":{"id":"https://openalex.org/S191963794","display_name":"Analytical Chemistry","issn_l":"0003-2700","issn":["0003-2700","1520-6882"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","jufo-3","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Analytical Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:osti.gov:2481361","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/2481361","pdf_url":"https://www.osti.gov/servlets/purl/2481361","source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:osti.gov:2481361","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/2481361","pdf_url":"https://www.osti.gov/servlets/purl/2481361","source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G590953419","display_name":"NEW GRANT -  TIME RESOLVED ANALYTICAL METHODS FOR LIQUID/SOLID INTERFACES  P.I. - JOEL M. HARRIS","funder_award_id":"FG0393ER14333","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"}],"funders":[{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2038247199.pdf","grobid_xml":"https://content.openalex.org/works/W2038247199.grobid-xml"},"referenced_works_count":40,"referenced_works":["https://openalex.org/W1487260360","https://openalex.org/W1526308134","https://openalex.org/W1587013658","https://openalex.org/W1964624545","https://openalex.org/W1967552034","https://openalex.org/W1971781745","https://openalex.org/W1979036884","https://openalex.org/W1980857913","https://openalex.org/W1981963470","https://openalex.org/W1982722768","https://openalex.org/W1983078427","https://openalex.org/W1984897675","https://openalex.org/W1985113407","https://openalex.org/W1985494136","https://openalex.org/W1991302949","https://openalex.org/W1993169515","https://openalex.org/W1999295782","https://openalex.org/W2012140767","https://openalex.org/W2014590137","https://openalex.org/W2016845690","https://openalex.org/W2040831819","https://openalex.org/W2043809328","https://openalex.org/W2045041020","https://openalex.org/W2056917158","https://openalex.org/W2057416487","https://openalex.org/W2058268963","https://openalex.org/W2060233471","https://openalex.org/W2060417904","https://openalex.org/W2062067670","https://openalex.org/W2069610606","https://openalex.org/W2071995109","https://openalex.org/W2074163428","https://openalex.org/W2076807342","https://openalex.org/W2077152715","https://openalex.org/W2078443852","https://openalex.org/W2078689544","https://openalex.org/W2082207425","https://openalex.org/W2091757717","https://openalex.org/W2093889067","https://openalex.org/W3005161365"],"related_works":["https://openalex.org/W2046591234","https://openalex.org/W2027964060","https://openalex.org/W2019027952","https://openalex.org/W2040831819","https://openalex.org/W2065638405","https://openalex.org/W2054677283","https://openalex.org/W2010008561","https://openalex.org/W2295338595","https://openalex.org/W2038483071","https://openalex.org/W1976781032"],"abstract_inverted_index":{"Most":[0],"of":[1,4,23,61,106,131,137,155,175,220],"our":[2],"understanding":[3],"chromatographic":[5],"processes":[6],"has":[7],"been":[8],"inferred":[9],"from":[10,182,233],"retention":[11,29,105,229],"measurements.":[12],"These":[13],"measurements":[14],"do":[15],"not":[16],"generally":[17,196],"provide":[18],"information":[19],"about":[20],"the":[21,48,107,125,128,132,135,138,141,152,168,172,214,218],"role":[22,203],"sorption":[24,121,173,193],"and":[25,163,226],"desorption":[26],"kinetics":[27,46,75,122,194],"on":[28,65,134,213],"equilibria.":[30],"In":[31],"this":[32,145,156],"work,":[33],"we":[34],"show":[35,209],"that":[36,102,120,151,210,227],"temperature-jump":[37],"relaxation":[38,74,96,126],"techniques":[39],"can":[40,231],"be":[41,224],"used":[42,55],"to":[43,56,190,199],"monitor":[44],"reversible":[45],"at":[47,83],"liquid/solid":[49],"interface.":[50],"A":[51],"Joule-discharge":[52],"apparatus":[53],"is":[54,159],"heat":[57],"a":[58,66,77,84,89,94,100,183,187,201],"packed":[59],"bed":[60],"porous":[62],"silica":[63,86],"gel":[64],"microsecond":[67],"time":[68,92],"scale.":[69],"We":[70],"have":[71],"observed":[72],"sorption/desorption":[73],"for":[76],"fluorescent":[78],"probe,":[79],"1-anilino-8-naphthalene":[80],"sulfonate":[81],"(ANS)":[82],"C18-modified":[85],"surface.":[87],"On":[88],"100":[90],"\u03bcs":[91],"scale,":[93],"slow":[95],"was":[97,109],"detected":[98],"having":[99],"rate":[101,133,154],"increased":[103,110],"as":[104],"solute":[108],"by":[111],"changes":[112],"in":[113,140,204,217],"mobile":[114,142],"phase":[115,143],"composition.":[116],"This":[117],"behavior":[118],"suggested":[119],"were":[123,180],"controlling":[124],"rate;":[127],"linear":[129],"dependence":[130],"concentration":[136],"probe":[139,158],"verified":[144],"postulate.":[146],"The":[147],"results":[148,208],"showed":[149],"further":[150],"adsorption":[153],"ionic":[157,221],"slower":[160],"than":[161],"diffusion-limited":[162],"exhibits":[164],"significant":[165,202],"influence":[166,212],"over":[167],"equilibrium":[169,215],"constant.":[170],"Here,":[171],"rates":[174],"two":[176],"neutral":[177],"probes,":[178],"however,":[179],"indistinguishable":[181],"diffusion":[184],"limit":[185],"indicating":[186],"negligible":[188],"barrier":[189],"sorption.":[191],"While":[192],"are":[195],"too":[197],"fast":[198],"play":[200],"band":[205],"broadening,":[206],"these":[207],"their":[211],"constant":[216],"case":[219],"solutes":[222],"cannot":[223],"overlooked,":[225],"similar":[228],"equilibria":[230],"arise":[232],"vastly":[234],"different":[235],"underlying":[236],"kinetic":[237],"mechanisms.":[238]},"counts_by_year":[],"updated_date":"2026-10-16T09:59:22.235173","created_date":"2016-06-24T00:00:00"}