{"id":"https://openalex.org/W2037636622","doi":"https://doi.org/10.1021/om8001729","title":"Carbon\u2212Carbon Bond Formation on Reaction of a Copper(I) Stannyl Complex with Carbon Dioxide","display_name":"Carbon\u2212Carbon Bond Formation on Reaction of a Copper(I) Stannyl Complex with Carbon Dioxide","publication_year":2008,"publication_date":"2008-05-20","ids":{"openalex":"https://openalex.org/W2037636622","doi":"https://doi.org/10.1021/om8001729","mag":"2037636622"},"language":"en","primary_location":{"id":"doi:10.1021/om8001729","doi":"https://doi.org/10.1021/om8001729","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om8001729","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5113872660","display_name":"Koyel Bhattacharyya","orcid":"https://orcid.org/0000-0003-4221-4894","observed_orcids":["https://orcid.org/0000-0003-4221-4894"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Koyel X. Bhattacharyya","raw_affiliation_strings":["Department of Chemistry, Massachusetts Institute of Technology, 18-344, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Massachusetts Institute of Technology, 18-344, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139","institution_ids":["https://openalex.org/I63966007"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070270103","display_name":"Jennifer A. Akana","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jennifer A. Akana","raw_affiliation_strings":["Department of Chemistry, Massachusetts Institute of Technology, 18-344, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Massachusetts Institute of Technology, 18-344, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139","institution_ids":["https://openalex.org/I63966007"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5048134412","display_name":"David S. Laitar","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"David S. Laitar","raw_affiliation_strings":["Department of Chemistry, Massachusetts Institute of Technology, 18-344, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Massachusetts Institute of Technology, 18-344, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139","institution_ids":["https://openalex.org/I63966007"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062107682","display_name":"Jacob M. Berlin","orcid":"https://orcid.org/0000-0001-7498-766X","observed_orcids":["https://orcid.org/0000-0001-7498-766X"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jacob M. Berlin","raw_affiliation_strings":["Department of Chemistry, Massachusetts Institute of Technology, 18-344, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Massachusetts Institute of Technology, 18-344, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139","institution_ids":["https://openalex.org/I63966007"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5080335992","display_name":"Joseph P. Sadighi","orcid":"https://orcid.org/0000-0003-1304-1170","observed_orcids":["https://orcid.org/0000-0003-1304-1170"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Joseph P. Sadighi","raw_affiliation_strings":["Department of Chemistry, Massachusetts Institute of Technology, 18-344, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Massachusetts Institute of Technology, 18-344, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139","institution_ids":["https://openalex.org/I63966007"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5113872660"],"corresponding_institution_ids":["https://openalex.org/I63966007"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.3507,"has_fulltext":false,"cited_by_count":40,"citation_normalized_percentile":{"value":0.91086026,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"27","issue":"12","first_page":"2682","last_page":"2684"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.5634999871253967,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.5634999871253967,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.2563000023365021,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.13429999351501465,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/carbon-dioxide","display_name":"carbon dioxide","score":0.6190000176429749},{"id":"https://openalex.org/keywords/carbon-carbon-bond-formation","display_name":"C\u2013C bond formation","score":0.9480000138282776},{"id":"https://openalex.org/keywords/deprotonation","display_name":"deprotonation","score":0.6589999794960022},{"id":"https://openalex.org/keywords/ipr-ligand","display_name":"IPr ligand","score":0.609000027179718}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9751836061477661},{"id":"https://openalex.org/C118629725","wikidata":"https://www.wikidata.org/wiki/Q2686738","display_name":"Deprotonation","level":3,"score":0.7755157947540283},{"id":"https://openalex.org/C525849907","wikidata":"https://www.wikidata.org/wiki/Q1096","display_name":"Tin","level":2,"score":0.7454473972320557},{"id":"https://openalex.org/C544778455","wikidata":"https://www.wikidata.org/wiki/Q753","display_name":"Copper","level":2,"score":0.6754976511001587},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.6410210728645325},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.6368746757507324},{"id":"https://openalex.org/C140205800","wikidata":"https://www.wikidata.org/wiki/Q5860","display_name":"Carbon fibers","level":3,"score":0.5822020173072815},{"id":"https://openalex.org/C73801178","wikidata":"https://www.wikidata.org/wiki/Q1778579","display_name":"Reinforced carbon\u2013carbon","level":3,"score":0.4818509817123413},{"id":"https://openalex.org/C530467964","wikidata":"https://www.wikidata.org/wiki/Q1997","display_name":"Carbon dioxide","level":2,"score":0.4451356828212738},{"id":"https://openalex.org/C2778695967","wikidata":"https://www.wikidata.org/wiki/Q44791900","display_name":"Chloride","level":2,"score":0.44035103917121887},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.38092535734176636},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.2220192849636078},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.07697618007659912},{"id":"https://openalex.org/C104779481","wikidata":"https://www.wikidata.org/wiki/Q50707","display_name":"Composite number","level":2,"score":0.0},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/om8001729","doi":"https://doi.org/10.1021/om8001729","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om8001729","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320309398","display_name":"California Institute of Technology","ror":"https://ror.org/05dxps055"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":27,"referenced_works":["https://openalex.org/W1963480966","https://openalex.org/W1975851967","https://openalex.org/W1985235311","https://openalex.org/W1985756525","https://openalex.org/W1986323919","https://openalex.org/W1991470376","https://openalex.org/W1992833633","https://openalex.org/W1998085580","https://openalex.org/W2004020013","https://openalex.org/W2019710323","https://openalex.org/W2020257698","https://openalex.org/W2030790616","https://openalex.org/W2038821228","https://openalex.org/W2055218209","https://openalex.org/W2059688064","https://openalex.org/W2067701299","https://openalex.org/W2069984247","https://openalex.org/W2078289736","https://openalex.org/W2081237256","https://openalex.org/W2085109473","https://openalex.org/W2089948654","https://openalex.org/W2109673381","https://openalex.org/W2122153163","https://openalex.org/W2125517342","https://openalex.org/W2950732851","https://openalex.org/W2952809275","https://openalex.org/W4388363517"],"related_works":["https://openalex.org/W2047587420","https://openalex.org/W2072059389","https://openalex.org/W2094926206","https://openalex.org/W1969796715","https://openalex.org/W2159451747","https://openalex.org/W2009407056","https://openalex.org/W4379470081","https://openalex.org/W2131400668","https://openalex.org/W2032124534","https://openalex.org/W2083947543"],"abstract_inverted_index":{"The":[0],"reaction":[1],"of":[2,19],"(IPr)CuO":[3,32],"t-":[4],"Bu":[5],"(IPr":[6],"=":[7],"1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)":[8],"with":[9,27],"triphenylstannane":[10],"forms":[11],"a":[12],"stannyl":[13,24],"complex,":[14],"(IPr)CuSnPh":[15,44],"3,":[16],"by":[17,50],"deprotonation":[18],"the":[20,36],"tin\u2212hydrogen":[21],"bond.":[22],"This":[23],"complex":[25],"reacts":[26],"CO":[28],"2":[29,33],"to":[30],"afford":[31],"CPh":[34],"as":[35,54],"sole":[37],"copper-containing":[38],"species.":[39],"A":[40],"tin\u2212carbon":[41],"bond":[42],"in":[43],"3":[45],"also":[46],"undergoes":[47],"facile":[48],"cleavage":[49],"mild":[51],"acids":[52],"such":[53],"2,4-lutidinium":[55],"chloride.":[56]},"counts_by_year":[{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":2},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":2},{"year":2014,"cited_by_count":5},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}
