{"id":"https://openalex.org/W2037288288","doi":"https://doi.org/10.1021/cm0306461","title":"Electrochemical and Structural Properties of xLi2M\u2018O3\u00b7(1\u2212x)LiMn0.5Ni0.5O2 Electrodes for Lithium Batteries (M\u2018 = Ti, Mn, Zr; 0 \u2264 x \u2a7d 0.3)","display_name":"Electrochemical and Structural Properties of xLi2M\u2018O3\u00b7(1\u2212x)LiMn0.5Ni0.5O2 Electrodes for Lithium Batteries (M\u2018 = Ti, Mn, Zr; 0 \u2264 x \u2a7d 0.3)","publication_year":2004,"publication_date":"2004-04-20","ids":{"openalex":"https://openalex.org/W2037288288","doi":"https://doi.org/10.1021/cm0306461","mag":"2037288288"},"language":"en","primary_location":{"id":"doi:10.1021/cm0306461","doi":"https://doi.org/10.1021/cm0306461","is_oa":false,"landing_page_url":"https://doi.org/10.1021/cm0306461","pdf_url":null,"source":{"id":"https://openalex.org/S66104727","display_name":"Chemistry of Materials","issn_l":"0897-4756","issn":["0897-4756","1520-5002"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry of Materials","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110324109","display_name":"Jeom-Soo Kim","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jeom-Soo Kim","raw_affiliation_strings":["Electrochemical Technology Program, Chemical Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Electrochemical Technology Program, Chemical Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005922926","display_name":"Christopher S. Johnson","orcid":"https://orcid.org/0000-0003-4357-6889","observed_orcids":["https://orcid.org/0000-0003-4357-6889"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Christopher S. Johnson","raw_affiliation_strings":["Electrochemical Technology Program, Chemical Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Electrochemical Technology Program, Chemical Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5052133858","display_name":"John T. Vaughey","orcid":"https://orcid.org/0000-0002-2556-6129","observed_orcids":["https://orcid.org/0000-0002-2556-6129"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"John T. Vaughey","raw_affiliation_strings":["Electrochemical Technology Program, Chemical Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Electrochemical Technology Program, Chemical Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005769938","display_name":"Michael M. Thackeray","orcid":"https://orcid.org/0000-0003-1571-886X","observed_orcids":["https://orcid.org/0000-0003-1571-886X"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Michael M. Thackeray","raw_affiliation_strings":["Electrochemical Technology Program, Chemical Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Electrochemical Technology Program, Chemical Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439","institution_ids":["https://openalex.org/I1282105669"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113659885","display_name":"Stephen A. Hackney","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I11957088","display_name":"Michigan Technological University","ror":"https://ror.org/0036rpn28","country_code":"US","type":"education","lineage":["https://openalex.org/I11957088"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Stephen A. Hackney","raw_affiliation_strings":["Department of Metallurgical and Materials Engineering, Michigan Technological University, Houghton, Michigan 49931"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Metallurgical and Materials Engineering, Michigan Technological University, Houghton, Michigan 49931","institution_ids":["https://openalex.org/I11957088"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010131613","display_name":"Won\u2010Sub Yoon","orcid":"https://orcid.org/0000-0002-6922-2088","observed_orcids":["https://orcid.org/0000-0002-6922-2088"]},"institutions":[{"id":"https://openalex.org/I200870766","display_name":"Brookhaven National Laboratory","ror":"https://ror.org/02ex6cf31","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I200870766","https://openalex.org/I39565521","https://openalex.org/I4210142672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Wonsub Yoon","raw_affiliation_strings":["Brookhaven National Laboratory, Upton, New York 11973","Brookhaven National Laboratory Upton, New York, 11973"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Brookhaven National Laboratory, Upton, New York 11973","institution_ids":["https://openalex.org/I200870766"]},{"raw_affiliation_string":"Brookhaven National Laboratory Upton, New York, 11973","institution_ids":["https://openalex.org/I200870766"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5088159296","display_name":"Clare P. Grey","orcid":"https://orcid.org/0000-0001-5572-192X","observed_orcids":["https://orcid.org/0000-0001-5572-192X","https://orcid.org/0000-0002-9488-1739"]},"institutions":[{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Clare P. Grey","raw_affiliation_strings":["Department of Chemistry, State University of New York, Stony Brook, New York 11794"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, State University of New York, Stony Brook, New York 11794","institution_ids":["https://openalex.org/I59553526"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":11.452,"has_fulltext":false,"cited_by_count":512,"citation_normalized_percentile":{"value":0.98712197,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":98,"max":100},"biblio":{"volume":"16","issue":"10","first_page":"1996","last_page":"2006"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10663","display_name":"Advanced Battery Technologies Research","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/2203","display_name":"Automotive Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/lithium-batteries","display_name":"lithium batteries","score":0.6320000290870667},{"id":"https://openalex.org/keywords/composite-cathode-materials","display_name":"composite cathode materials","score":0.6349999904632568},{"id":"https://openalex.org/keywords/li2mno3","display_name":"Li2MnO3","score":0.8700000047683716},{"id":"https://openalex.org/keywords/li2tio3","display_name":"Li2TiO3","score":0.9440000057220459},{"id":"https://openalex.org/keywords/li2zro3","display_name":"Li2ZrO3","score":1.0},{"id":"https://openalex.org/keywords/solid-solutions","display_name":"solid solutions","score":0.4189999997615814},{"id":"https://openalex.org/keywords/short-range-order","display_name":"short-range order","score":0.8679999709129333},{"id":"https://openalex.org/keywords/electrochemical-activity","display_name":"electrochemical activity","score":0.6869999766349792},{"id":"https://openalex.org/keywords/cycling-capacity","display_name":"cycling capacity","score":0.5870000123977661},{"id":"https://openalex.org/keywords/high-voltage-cathodes","display_name":"high-voltage cathodes","score":0.574999988079071}],"concepts":[{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.7122894525527954},{"id":"https://openalex.org/C2778541603","wikidata":"https://www.wikidata.org/wiki/Q152763","display_name":"Lithium (medication)","level":2,"score":0.6576399803161621},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6515945792198181},{"id":"https://openalex.org/C146088050","wikidata":"https://www.wikidata.org/wiki/Q744818","display_name":"Transmission electron microscopy","level":2,"score":0.5438436269760132},{"id":"https://openalex.org/C207114421","wikidata":"https://www.wikidata.org/wiki/Q133900","display_name":"Diffraction","level":2,"score":0.4964786171913147},{"id":"https://openalex.org/C138999460","wikidata":"https://www.wikidata.org/wiki/Q787619","display_name":"Solid solution","level":2,"score":0.48940983414649963},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.4725998044013977},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.469144731760025},{"id":"https://openalex.org/C50515024","wikidata":"https://www.wikidata.org/wiki/Q826582","display_name":"X-ray crystallography","level":3,"score":0.44641435146331787},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.4333254098892212},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.21084943413734436},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.16785508394241333},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.11192411184310913},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.06982901692390442},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.05790629982948303},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C134018914","wikidata":"https://www.wikidata.org/wiki/Q162606","display_name":"Endocrinology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/cm0306461","doi":"https://doi.org/10.1021/cm0306461","is_oa":false,"landing_page_url":"https://doi.org/10.1021/cm0306461","pdf_url":null,"source":{"id":"https://openalex.org/S66104727","display_name":"Chemistry of Materials","issn_l":"0897-4756","issn":["0897-4756","1520-5002"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry of Materials","raw_type":"journal-article"},{"id":"pmh:oai:digitalcommons.mtu.edu:michigantech-p-27192","doi":null,"is_oa":false,"landing_page_url":"https://digitalcommons.mtu.edu/michigantech-p/7890","pdf_url":null,"source":{"id":"https://openalex.org/S4377196391","display_name":"Digital Commons - Michigan Tech (Michigan Technological University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I11957088","host_organization_name":"Michigan Technological University","host_organization_lineage":["https://openalex.org/I11957088"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Michigan Tech Publications, Part 1","raw_type":"text"}],"best_oa_location":null,"sustainable_development_goals":[{"score":0.75,"display_name":"Affordable and clean energy","id":"https://metadata.un.org/sdg/7"}],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":33,"referenced_works":["https://openalex.org/W227638552","https://openalex.org/W410190572","https://openalex.org/W1785442443","https://openalex.org/W1789005154","https://openalex.org/W1966292189","https://openalex.org/W1976572187","https://openalex.org/W1985895439","https://openalex.org/W1987006772","https://openalex.org/W1988648323","https://openalex.org/W1991422079","https://openalex.org/W1992805382","https://openalex.org/W1997949062","https://openalex.org/W2004254424","https://openalex.org/W2006275056","https://openalex.org/W2014079447","https://openalex.org/W2014416110","https://openalex.org/W2016482431","https://openalex.org/W2025850574","https://openalex.org/W2044833727","https://openalex.org/W2058634500","https://openalex.org/W2065902691","https://openalex.org/W2092707335","https://openalex.org/W2093670759","https://openalex.org/W2158327121","https://openalex.org/W2166909768","https://openalex.org/W2166917459","https://openalex.org/W2232898241","https://openalex.org/W2321634820","https://openalex.org/W2323780975","https://openalex.org/W2898712814","https://openalex.org/W2949665843","https://openalex.org/W2953172382","https://openalex.org/W3215230530"],"related_works":["https://openalex.org/W2073969472","https://openalex.org/W4236775447","https://openalex.org/W2079614455","https://openalex.org/W1980696225","https://openalex.org/W1972907392","https://openalex.org/W2366179572","https://openalex.org/W3032208078","https://openalex.org/W2075016343","https://openalex.org/W2039206461","https://openalex.org/W1532979236"],"abstract_inverted_index":{"Electrochemical":[0],"and":[1,32,44,82],"structural":[2],"properties":[3],"of":[4,120],"xLi2M\u2032O":[5],"3\u00b7(1-x)LiMn0.5Ni0.5O2":[6],"electrodes":[7,111],"(M\u2032":[8],"=":[9,42,114],"Ti,":[10],"Mn,":[11,45],"Zr;":[12],"0":[13],"\u2264":[14,16],"x":[15,113],"0.3)":[17],"for":[18,40],"lithium":[19,107],"batteries":[20],"are":[21,75,85],"reported.":[22],"Powder":[23],"X-ray":[24],"diffraction,":[25],"lattice":[26],"imaging":[27],"by":[28],"transmission":[29],"electron":[30],"microscopy,":[31],"nuclear":[33],"magnetic":[34],"resonance":[35],"spectroscopy":[36],"provide":[37,116],"evidence":[38],"that,":[39],"M\u2032":[41],"Ti":[43],"the":[46,53,73,95,124],"Li2M\u2032O3":[47],"component":[48,56,98],"is":[49],"structurally":[50],"integrated":[51],"into":[52,94],"LiMn0.5Ni0.5O":[54],"2":[55],"to":[57],"yield":[58],"\"composite\"":[59],"structures":[60],"with":[61,112],"domains":[62],"having":[63],"short-range":[64],"order,":[65],"rather":[66],"than":[67],"true":[68],"solid":[69],"solutions":[70],"in":[71,106,118],"which":[72],"cations":[74],"uniformly":[76],"distributed":[77],"within":[78],"discrete":[79],"layers.":[80],"Li2TiO3":[81],"Li2ZrO3":[83],"components":[84],"electrochemically":[86],"inactive,":[87],"whereas":[88],"electrochemical":[89],"activity":[90],"can":[91],"be":[92],"induced":[93],"Li2MnO":[96],"3":[97],"above":[99],"4.3":[100],"V":[101],"vs":[102],"Li0.":[103],"When":[104],"cycled":[105],"cells,":[108],"xLi2MnO3\u00b7(1-x)LiMn0.5Ni":[109],"0.5O2":[110],"0.3":[115],"capacities":[117],"excess":[119],"300":[121],"mA\u00b7h/g":[122],"over":[123],"range":[125],"4.6-1.45":[126],"V.":[127]},"counts_by_year":[{"year":2026,"cited_by_count":8},{"year":2025,"cited_by_count":10},{"year":2024,"cited_by_count":12},{"year":2023,"cited_by_count":7},{"year":2022,"cited_by_count":19},{"year":2021,"cited_by_count":22},{"year":2020,"cited_by_count":24},{"year":2019,"cited_by_count":29},{"year":2018,"cited_by_count":30},{"year":2017,"cited_by_count":37},{"year":2016,"cited_by_count":52},{"year":2015,"cited_by_count":52},{"year":2014,"cited_by_count":39},{"year":2013,"cited_by_count":60},{"year":2012,"cited_by_count":27}],"updated_date":"2026-10-13T10:08:12.033832","created_date":"2016-06-24T00:00:00"}