{"id":"https://openalex.org/W2035916728","doi":"https://doi.org/10.1021/ic8020172","title":"Zn and Fe Complexes Containing a Redox Active Macrocyclic Biquinazoline Ligand","display_name":"Zn and Fe Complexes Containing a Redox Active Macrocyclic Biquinazoline Ligand","publication_year":2009,"publication_date":"2009-02-25","ids":{"openalex":"https://openalex.org/W2035916728","doi":"https://doi.org/10.1021/ic8020172","mag":"2035916728","pmid":"https://pubmed.ncbi.nlm.nih.gov/19243150"},"language":"en","primary_location":{"id":"doi:10.1021/ic8020172","doi":"https://doi.org/10.1021/ic8020172","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic8020172","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5014941782","display_name":"Priyabrata Banerjee","orcid":"https://orcid.org/0000-0002-3009-5894","observed_orcids":["https://orcid.org/0000-0002-3009-5894"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I251424209","display_name":"Universitat de Girona","ror":"https://ror.org/01xdxns91","country_code":"ES","type":"education","lineage":["https://openalex.org/I251424209"]}],"countries":["DE","ES"],"is_corresponding":false,"raw_author_name":"Priyabrata Banerjee","raw_affiliation_strings":["Max Planck Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany, and Departament de Qu\u00edmica, Universitat de Girona, Campus de Montilivi s/n, E-17071 Girona, Spain"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max Planck Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany, and Departament de Qu\u00edmica, Universitat de Girona, Campus de Montilivi s/n, E-17071 Girona, Spain","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I251424209"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5018219458","display_name":"Anna Company","orcid":"https://orcid.org/0000-0003-4845-4418","observed_orcids":["https://orcid.org/0000-0003-4845-4418"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I251424209","display_name":"Universitat de Girona","ror":"https://ror.org/01xdxns91","country_code":"ES","type":"education","lineage":["https://openalex.org/I251424209"]}],"countries":["DE","ES"],"is_corresponding":false,"raw_author_name":"Anna Company","raw_affiliation_strings":["Max Planck Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany, and Departament de Qu\u00edmica, Universitat de Girona, Campus de Montilivi s/n, E-17071 Girona, Spain"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max Planck Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany, and Departament de Qu\u00edmica, Universitat de Girona, Campus de Montilivi s/n, E-17071 Girona, Spain","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I251424209"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020886062","display_name":"Thomas Weyherm\u00fcller","orcid":"https://orcid.org/0000-0002-0399-7999","observed_orcids":["https://orcid.org/0000-0002-0399-7999"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I251424209","display_name":"Universitat de Girona","ror":"https://ror.org/01xdxns91","country_code":"ES","type":"education","lineage":["https://openalex.org/I251424209"]}],"countries":["DE","ES"],"is_corresponding":false,"raw_author_name":"Thomas Weyherm\u00fcller","raw_affiliation_strings":["Max Planck Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany, and Departament de Qu\u00edmica, Universitat de Girona, Campus de Montilivi s/n, E-17071 Girona, Spain"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max Planck Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany, and Departament de Qu\u00edmica, Universitat de Girona, Campus de Montilivi s/n, E-17071 Girona, Spain","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I251424209"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5090355454","display_name":"Eckhard Bill","orcid":"https://orcid.org/0000-0001-9138-3964","observed_orcids":["https://orcid.org/0000-0001-9138-3964"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I251424209","display_name":"Universitat de Girona","ror":"https://ror.org/01xdxns91","country_code":"ES","type":"education","lineage":["https://openalex.org/I251424209"]}],"countries":["DE","ES"],"is_corresponding":false,"raw_author_name":"Eckhard Bill","raw_affiliation_strings":["Max Planck Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany, and Departament de Qu\u00edmica, Universitat de Girona, Campus de Montilivi s/n, E-17071 Girona, Spain"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max Planck Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany, and Departament de Qu\u00edmica, Universitat de Girona, Campus de Montilivi s/n, E-17071 Girona, Spain","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I251424209"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5024840132","display_name":"Corinna R. Hess","orcid":"https://orcid.org/0000-0002-9607-9184","observed_orcids":["https://orcid.org/0000-0002-9607-9184"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I251424209","display_name":"Universitat de Girona","ror":"https://ror.org/01xdxns91","country_code":"ES","type":"education","lineage":["https://openalex.org/I251424209"]}],"countries":["DE","ES"],"is_corresponding":true,"raw_author_name":"Corinna R. Hess","raw_affiliation_strings":["Max Planck Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany, and Departament de Qu\u00edmica, Universitat de Girona, Campus de Montilivi s/n, E-17071 Girona, Spain"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max Planck Institut f\u00fcr Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 M\u00fclheim an der Ruhr, Germany, and Departament de Qu\u00edmica, Universitat de Girona, Campus de Montilivi s/n, E-17071 Girona, Spain","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I251424209"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5024840132"],"corresponding_institution_ids":["https://openalex.org/I149899117","https://openalex.org/I251424209"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.161,"has_fulltext":false,"cited_by_count":38,"citation_normalized_percentile":{"value":0.4937204,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"48","issue":"7","first_page":"2944","last_page":"2955"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.18930000066757202,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.18930000066757202,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.17350000143051147,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.15160000324249268,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/macrocyclic-ligands","display_name":"macrocyclic ligands","score":0.8820000290870667},{"id":"https://openalex.org/keywords/zinc-complexes","display_name":"zinc complexes","score":0.7950000166893005},{"id":"https://openalex.org/keywords/iron-complexes","display_name":"iron complexes","score":0.9950000047683716},{"id":"https://openalex.org/keywords/redox-non-innocent-ligands","display_name":"redox non-innocent ligands","score":0.890999972820282},{"id":"https://openalex.org/keywords/ligand-centered-reduction","display_name":"ligand-centered reduction","score":0.7250000238418579},{"id":"https://openalex.org/keywords/radical-dianion","display_name":"radical dianion","score":0.7839999794960022},{"id":"https://openalex.org/keywords/antiferromagnetic-coupling","display_name":"antiferromagnetic coupling","score":0.9150000214576721},{"id":"https://openalex.org/keywords/pi-radicals","display_name":"\u03c0-radicals","score":0.8330000042915344},{"id":"https://openalex.org/keywords/electronic-structure","display_name":"electronic structure","score":0.7400000095367432},{"id":"https://openalex.org/keywords/coordination-chemistry","display_name":"coordination chemistry","score":0.35899999737739563}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9607535600662231},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.8189849853515625},{"id":"https://openalex.org/C89477785","wikidata":"https://www.wikidata.org/wiki/Q1996115","display_name":"Non-innocent ligand","level":3,"score":0.7780110836029053},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.7600818872451782},{"id":"https://openalex.org/C2776568683","wikidata":"https://www.wikidata.org/wiki/Q23005640","display_name":"Moiety","level":2,"score":0.681479811668396},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.6197933554649353},{"id":"https://openalex.org/C2775832776","wikidata":"https://www.wikidata.org/wiki/Q65122087","display_name":"Ferrous","level":2,"score":0.5240978002548218},{"id":"https://openalex.org/C2779432074","wikidata":"https://www.wikidata.org/wiki/Q25323956","display_name":"Macrocyclic ligand","level":3,"score":0.5193337202072144},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4825674593448639},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.35024145245552063},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.34848880767822266},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.10908582806587219},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0}],"mesh":[{"descriptor_ui":"D003198","descriptor_name":"Computer Simulation","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D007501","descriptor_name":"Iron","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008024","descriptor_name":"Ligands","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008956","descriptor_name":"Models, Chemical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008958","descriptor_name":"Models, Molecular","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D009942","descriptor_name":"Organometallic Compounds","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":false},{"descriptor_ui":"D009942","descriptor_name":"Organometallic Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D010084","descriptor_name":"Oxidation-Reduction","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D011799","descriptor_name":"Quinazolines","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D015032","descriptor_name":"Zinc","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D018360","descriptor_name":"Crystallography, X-Ray","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D047028","descriptor_name":"Macrocyclic Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":3,"locations":[{"id":"doi:10.1021/ic8020172","doi":"https://doi.org/10.1021/ic8020172","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic8020172","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:19243150","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/19243150","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:edoc.mpg.de:453063","doi":null,"is_oa":false,"landing_page_url":"http://edoc.mpg.de/453063","pdf_url":null,"source":{"id":"https://openalex.org/S4406922265","display_name":"Max Planck Institute for Plasma Physics","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Inorganic Chemistry, v.48, 2944-2955 (2009)","raw_type":"Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":28,"referenced_works":["https://openalex.org/W1974192439","https://openalex.org/W1975262546","https://openalex.org/W1981614474","https://openalex.org/W1990808848","https://openalex.org/W1999981636","https://openalex.org/W2009638987","https://openalex.org/W2018339708","https://openalex.org/W2023086944","https://openalex.org/W2023271753","https://openalex.org/W2033035711","https://openalex.org/W2039185618","https://openalex.org/W2040891489","https://openalex.org/W2045952721","https://openalex.org/W2058210956","https://openalex.org/W2060526159","https://openalex.org/W2075381111","https://openalex.org/W2078146328","https://openalex.org/W2079193399","https://openalex.org/W2081012283","https://openalex.org/W2088953229","https://openalex.org/W2091047010","https://openalex.org/W2100394721","https://openalex.org/W2143981217","https://openalex.org/W2152630496","https://openalex.org/W2487844439","https://openalex.org/W2488009945","https://openalex.org/W2951680450","https://openalex.org/W3138377932"],"related_works":["https://openalex.org/W3112020345","https://openalex.org/W2022659065","https://openalex.org/W2009950018","https://openalex.org/W2110665858","https://openalex.org/W2045305388","https://openalex.org/W2109122627","https://openalex.org/W2325910083","https://openalex.org/W2605539732","https://openalex.org/W1987040742","https://openalex.org/W7203491785"],"abstract_inverted_index":{"A":[0],"series":[1,81],"of":[2,22,33,67,120],"iron":[3,101],"and":[4,26,42,85,117],"zinc":[5,50],"complexes":[6,36,71,122],"has":[7],"been":[8,38,73],"synthesized,":[9],"coordinated":[10,123],"by":[11,124],"the":[12,34,58,64,97,100,113,125],"macrocyclic":[13],"biquinazoline":[14],"ligand,":[15],"2-4:6-8-bis(3,3,4,4-tetramethyldihydropyrrolo)-10-15-(2,2'-biquinazolino)-[15]-1,3,5,8,10,14-hexaene-1,3,7,9,11,14-N(6)":[16],"(Mabiq).":[17],"The":[18,30,48,110],"Mabiq":[19,60,126],"ligand":[20],"consists":[21],"a":[23,53,107],"bipyrimidine":[24],"moiety":[25],"two":[27],"dihydropyrrole":[28],"units.":[29],"electronic":[31,118],"structures":[32],"metal-Mabiq":[35],"have":[37,72],"characterized":[39],"using":[40],"spectroscopic":[41],"density-functional":[43],"theory":[44],"(DFT)":[45],"computational":[46],"methods.":[47],"parent":[49],"complex":[51],"exhibits":[52],"ligand-centered":[54],"reduction":[55],"to":[56,106],"generate":[57],"metal-coordinated":[59],"radical":[61],"dianion,":[62],"establishing":[63],"redox":[65,80,115],"non-innocence":[66],"this":[68],"ligand.":[69,127],"Iron-Mabiq":[70],"isolated":[74],"in":[75],"three":[76],"oxidation":[77],"states.":[78],"This":[79],"includes":[82],"low-spin":[83,86],"ferric":[84],"ferrous":[87],"species,":[88],"as":[89,91],"well":[90],"an":[92],"intermediate-spin":[93],"Fe(II)":[94],"compound.":[95],"In":[96],"latter":[98],"complex,":[99],"ion":[102],"is":[103],"antiferromagnetically":[104],"coupled":[105],"Mabiq-centered":[108],"pi-radical.":[109],"results":[111],"demonstrate":[112],"rich":[114],"chemistry":[116],"properties":[119],"metal":[121]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":3},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":5},{"year":2016,"cited_by_count":5},{"year":2015,"cited_by_count":6},{"year":2014,"cited_by_count":3}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}