{"id":"https://openalex.org/W2034433488","doi":"https://doi.org/10.1021/ic901647n","title":"Copper Halide-Incorporated Tellurium\u2212Iron Carbonyl Complexes: Transformation, Electrochemical Properties, and Theoretical Calculations","display_name":"Copper Halide-Incorporated Tellurium\u2212Iron Carbonyl Complexes: Transformation, Electrochemical Properties, and Theoretical Calculations","publication_year":2009,"publication_date":"2009-10-15","ids":{"openalex":"https://openalex.org/W2034433488","doi":"https://doi.org/10.1021/ic901647n","mag":"2034433488","pmid":"https://pubmed.ncbi.nlm.nih.gov/19831367"},"language":"en","primary_location":{"id":"doi:10.1021/ic901647n","doi":"https://doi.org/10.1021/ic901647n","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic901647n","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5034965613","display_name":"Bo-Gaun Chen","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I134161618","display_name":"National Taiwan Normal University","ror":"https://ror.org/059dkdx38","country_code":"TW","type":"education","lineage":["https://openalex.org/I134161618"]}],"countries":["TW"],"is_corresponding":false,"raw_author_name":"Bo-Gaun Chen","raw_affiliation_strings":["Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan, Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan, Republic of China","institution_ids":["https://openalex.org/I134161618"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113840197","display_name":"Chia-Hua Ho","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I134161618","display_name":"National Taiwan Normal University","ror":"https://ror.org/059dkdx38","country_code":"TW","type":"education","lineage":["https://openalex.org/I134161618"]}],"countries":["TW"],"is_corresponding":false,"raw_author_name":"Chia-Hua Ho","raw_affiliation_strings":["Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan, Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan, Republic of China","institution_ids":["https://openalex.org/I134161618"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006139223","display_name":"Chang\u2010Ju Lee","orcid":"https://orcid.org/0000-0001-5584-2115","observed_orcids":["https://orcid.org/0000-0001-5584-2115"]},"institutions":[{"id":"https://openalex.org/I134161618","display_name":"National Taiwan Normal University","ror":"https://ror.org/059dkdx38","country_code":"TW","type":"education","lineage":["https://openalex.org/I134161618"]}],"countries":["TW"],"is_corresponding":false,"raw_author_name":"Chang-Ju Lee","raw_affiliation_strings":["Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan, Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan, Republic of China","institution_ids":["https://openalex.org/I134161618"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5047136847","display_name":"Minghuey Shieh","orcid":"https://orcid.org/0000-0002-1122-0346","observed_orcids":["https://orcid.org/0000-0002-1122-0346"]},"institutions":[{"id":"https://openalex.org/I134161618","display_name":"National Taiwan Normal University","ror":"https://ror.org/059dkdx38","country_code":"TW","type":"education","lineage":["https://openalex.org/I134161618"]}],"countries":["TW"],"is_corresponding":true,"raw_author_name":"Minghuey Shieh","raw_affiliation_strings":["Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan, Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan, Republic of China","institution_ids":["https://openalex.org/I134161618"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5047136847"],"corresponding_institution_ids":["https://openalex.org/I134161618"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.4032,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.82665861,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"48","issue":"22","first_page":"10757","last_page":"10768"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12557","display_name":"Inorganic Chemistry and Materials","score":0.9609000086784363,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12557","display_name":"Inorganic Chemistry and Materials","score":0.9609000086784363,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.013299999758601189,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.00930000003427267,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/copper-halides","display_name":"copper halides","score":0.5370000004768372},{"id":"https://openalex.org/keywords/skeleton-expansion","display_name":"skeleton expansion","score":0.593999981880188},{"id":"https://openalex.org/keywords/cu-ii-complexes","display_name":"copper(II) complexes","score":0.3630000054836273},{"id":"https://openalex.org/keywords/electrochemical-properties","display_name":"electrochemical properties","score":0.6399999856948853},{"id":"https://openalex.org/keywords/electrocatalytic-hydrogen-evolution-reaction","display_name":"electrocatalytic hydrogen evolution","score":0.5260000228881836},{"id":"https://openalex.org/keywords/electrocatalytic-oxygen-evolution","display_name":"electrocatalytic oxygen evolution","score":0.6060000061988831},{"id":"https://openalex.org/keywords/electrocatalytic-hydrogen-oxidation","display_name":"electrocatalytic hydrogen oxidation","score":0.5230000019073486},{"id":"https://openalex.org/keywords/electrocatalytic-oxygen-reduction","display_name":"electrocatalytic oxygen reduction","score":0.5630000233650208}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9850285053253174},{"id":"https://openalex.org/C538181303","wikidata":"https://www.wikidata.org/wiki/Q1100","display_name":"Tellurium","level":2,"score":0.8812236785888672},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.8649979829788208},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.721682071685791},{"id":"https://openalex.org/C544778455","wikidata":"https://www.wikidata.org/wiki/Q753","display_name":"Copper","level":2,"score":0.7202272415161133},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.5097691416740417},{"id":"https://openalex.org/C204241405","wikidata":"https://www.wikidata.org/wiki/Q461499","display_name":"Transformation (genetics)","level":3,"score":0.41527026891708374},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2614375948905945},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.22292622923851013},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.12329834699630737},{"id":"https://openalex.org/C104317684","wikidata":"https://www.wikidata.org/wiki/Q7187","display_name":"Gene","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ic901647n","doi":"https://doi.org/10.1021/ic901647n","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic901647n","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:19831367","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/19831367","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":60,"referenced_works":["https://openalex.org/W648627940","https://openalex.org/W1963813514","https://openalex.org/W1970549136","https://openalex.org/W1973177652","https://openalex.org/W1976003696","https://openalex.org/W1976561070","https://openalex.org/W1977831187","https://openalex.org/W1978516314","https://openalex.org/W1978750868","https://openalex.org/W1989919087","https://openalex.org/W1993383767","https://openalex.org/W1993983035","https://openalex.org/W1996444500","https://openalex.org/W1997785740","https://openalex.org/W1999630412","https://openalex.org/W2001340417","https://openalex.org/W2004923333","https://openalex.org/W2005144610","https://openalex.org/W2006004191","https://openalex.org/W2006105265","https://openalex.org/W2022887391","https://openalex.org/W2023129297","https://openalex.org/W2023271753","https://openalex.org/W2028837279","https://openalex.org/W2029503616","https://openalex.org/W2029508833","https://openalex.org/W2037708012","https://openalex.org/W2038767330","https://openalex.org/W2042944554","https://openalex.org/W2043711066","https://openalex.org/W2048278064","https://openalex.org/W2050351206","https://openalex.org/W2051340235","https://openalex.org/W2053074788","https://openalex.org/W2063448237","https://openalex.org/W2064657819","https://openalex.org/W2083665844","https://openalex.org/W2085485204","https://openalex.org/W2085966856","https://openalex.org/W2090124291","https://openalex.org/W2093289748","https://openalex.org/W2117359388","https://openalex.org/W2122104339","https://openalex.org/W2126470308","https://openalex.org/W2128603541","https://openalex.org/W2129915425","https://openalex.org/W2130419893","https://openalex.org/W2132916274","https://openalex.org/W2142014110","https://openalex.org/W2142673585","https://openalex.org/W2143981217","https://openalex.org/W2144332006","https://openalex.org/W2155304007","https://openalex.org/W2161288829","https://openalex.org/W2169662534","https://openalex.org/W2233365006","https://openalex.org/W2739714964","https://openalex.org/W2943612633","https://openalex.org/W2952258734","https://openalex.org/W4212980050"],"related_works":["https://openalex.org/W1996444500","https://openalex.org/W1973691056","https://openalex.org/W1967754245","https://openalex.org/W1963813514","https://openalex.org/W2296551689","https://openalex.org/W213467144","https://openalex.org/W2163526889","https://openalex.org/W2004923333","https://openalex.org/W2051692156","https://openalex.org/W2115281588"],"abstract_inverted_index":{"When":[0,53],"the":[1,54,235,251,253,255,259,262,273,280,283,295],"tellurium-capped":[2],"tri-iron":[3],"carbonyl":[4],"cluster":[5,256],"[Et(4)N](2)[TeFe(3)(CO)(9)]":[6,238],"was":[7,99,115,211],"treated":[8],"with":[9,44,126,153,190,239],"1":[10,154,191],"equiv":[11,155,192,241],"of":[12,63,156,171,193,237,242,261,272,275,282,287,298],"CuX":[13,51,243],"in":[14,74,110,248,270],"THF":[15],"at":[16,59,79,158,195,294],"0":[17,80,159],"degrees":[18,81,160],"C,":[19,82],"CuX-incorporated":[20,263],"clusters":[21,84,140,174,201,267],"[Et(4)N](2)[TeFe(3)(CO)(9)CuX]":[22],"(X":[23,65,71,86,142,203,244],"=":[24,66,72,87,143,204,245],"Cl,":[25,67,88,144,205,246],"[Et(4)N](2)[1a];":[26],"Br,":[27,90,146,207],"[Et(4)N](2)[1b];":[28],"I,":[29,92,148],"[Et(4)N](2)[1c])":[30],"were":[31,56,94,176,230],"formed,":[32],"respectively.":[33,96],"X-ray":[34,103,162,214],"analysis":[35,104,163,215],"showed":[36,164],"that":[37,165,175],"1a-1c":[38,132],"each":[39,169],"exhibited":[40],"a":[41,60,107,179,183,223],"TeFe(3)":[42,108,173,219],"core":[43],"one":[45,50,112,121],"Fe-Fe":[46],"bond":[47],"bridged":[48,117],"by":[49,102,120,178,213,222,291],"fragment.":[52],"reactions":[55],"carried":[57],"out":[58],"molar":[61],"ratio":[62],"1:2":[64],"Br)":[68,247],"or":[69,77,265],"1:3":[70],"I)":[73],"tetrahydrofuran":[75],"(THF)":[76],"MeCN":[78],"Cu(2)X(2)-incorporated":[83],"[Et(4)N](2)[TeFe(3)(CO)(9)Cu(2)X(2)]":[85],"[Et(4)N](2)[2a];":[89],"[Et(4)N](2)[2b];":[91],"[Et(4)N](2)[2c])":[93],"obtained,":[95],"Cluster":[97,209],"2a":[98],"structurally":[100],"characterized":[101],"to":[105,136,216],"display":[106],"core,":[109],"which":[111,288],"TeFe(2)":[113],"plane":[114],"asymmetrically":[116],"and":[118,123,167,188,228,258,279],"capped":[119],"mu(3)-CuCl":[122],"another":[124],"mu(4)-CuCl":[125],"two":[127,172,218],"Cu":[128],"atoms":[129],"bonded.":[130],"Complexes":[131],"underwent":[133],"skeleton":[134],"expansion":[135],"form":[137],"Cu(3)X-incorporated":[138],"di-TeFe(3)":[139,200,266],"[{TeFe(3)(CO)(9)}(2)Cu(3)X](2-)":[141],"3a;":[145],"3b;":[147],"3c),":[149],"respectively,":[150],"upon":[151],"treatment":[152],"[Cu(MeCN)(4)][BF(4)]":[157,194],"C.":[161],"3b":[166],"3c":[168],"consisted":[170],"linked":[177,221],"Cu(3)X":[180],"moiety.":[181,225],"However,":[182],"similar":[184],"reaction":[185,236],"for":[186],"1a":[187],"1b":[189],"room":[196],"temperature":[197],"produced":[198,232],"Cu(4)X(2)-linked":[199],"[{TeFe(3)(CO)(9)}(2)Cu(4)X(2)](2-)":[202],"4a;":[206],"4b).":[208],"4a":[210,227],"shown":[212],"have":[217],"cores":[220],"Cu(4)Cl(2)":[224],"Clusters":[226],"4b":[229],"also":[231],"directly":[233],"from":[234],"4":[240],"THF.":[249],"Furthermore,":[250],"nature,":[252],"formation,":[254],"transformation,":[257],"electrochemistry":[260],"mono-":[264],"are":[268,289],"explained":[269],"terms":[271],"effects":[274],"tellurium,":[276],"copper":[277],"halide,":[278],"size":[281],"metal":[284],"skeleton,":[285],"all":[286],"elucidated":[290],"molecular":[292],"calculations":[293],"B3LYP":[296],"level":[297],"density":[299],"functional":[300],"theory.":[301]},"counts_by_year":[{"year":2021,"cited_by_count":1},{"year":2019,"cited_by_count":3},{"year":2017,"cited_by_count":4},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}