{"id":"https://openalex.org/W2033839986","doi":"https://doi.org/10.1002/oms.1210291103","title":"Electrospray mass spectra of protein cations formed in basic solutions","display_name":"Electrospray mass spectra of protein cations formed in basic solutions","publication_year":1994,"publication_date":"1994-11-01","ids":{"openalex":"https://openalex.org/W2033839986","doi":"https://doi.org/10.1002/oms.1210291103","mag":"2033839986"},"language":"en","primary_location":{"id":"doi:10.1002/oms.1210291103","doi":"https://doi.org/10.1002/oms.1210291103","is_oa":false,"landing_page_url":"https://doi.org/10.1002/oms.1210291103","pdf_url":null,"source":{"id":"https://openalex.org/S4210228587","display_name":"Organic Mass Spectrometry","issn_l":"0030-493X","issn":["0030-493X","2376-3884"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic Mass Spectrometry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5113522825","display_name":"J. C. Yves Le Blanc","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I204722609","display_name":"Queen's University","ror":"https://ror.org/02y72wh86","country_code":"CA","type":"education","lineage":["https://openalex.org/I204722609"]},{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":true,"raw_author_name":"J. C. Y. Le Blanc","raw_affiliation_strings":["Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada","J. C. Y. Le Blanc, Department of Chemistry, Queen's University, Kingston, Ontario, K7L 3N6, Canada","K. W. M. Siu, Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada","institution_ids":["https://openalex.org/I4210159778"]},{"raw_affiliation_string":"J. C. Y. Le Blanc, Department of Chemistry, Queen's University, Kingston, Ontario, K7L 3N6, Canada","institution_ids":["https://openalex.org/I204722609"]},{"raw_affiliation_string":"K. W. M. Siu, Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada","institution_ids":["https://openalex.org/I4210159778"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049639928","display_name":"Jianyao Wang","orcid":"https://orcid.org/0000-0003-2559-8849","observed_orcids":["https://orcid.org/0000-0003-2559-8849"]},"institutions":[{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Jianyao Wang","raw_affiliation_strings":["Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada","institution_ids":["https://openalex.org/I4210159778"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5072797742","display_name":"Roger Guevremont","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Roger Guevremont","raw_affiliation_strings":["Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada","institution_ids":["https://openalex.org/I4210159778"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5102801878","display_name":"K. W. Michael Siu","orcid":"https://orcid.org/0000-0002-9551-6506","observed_orcids":["https://orcid.org/0000-0002-9551-6506"]},"institutions":[{"id":"https://openalex.org/I204722609","display_name":"Queen's University","ror":"https://ror.org/02y72wh86","country_code":"CA","type":"education","lineage":["https://openalex.org/I204722609"]},{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":true,"raw_author_name":"K. W. M. Siu","raw_affiliation_strings":["Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada","J. C. Y. Le Blanc, Department of Chemistry, Queen's University, Kingston, Ontario, K7L 3N6, Canada","K. W. M. Siu, Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada","institution_ids":["https://openalex.org/I4210159778"]},{"raw_affiliation_string":"J. C. Y. Le Blanc, Department of Chemistry, Queen's University, Kingston, Ontario, K7L 3N6, Canada","institution_ids":["https://openalex.org/I204722609"]},{"raw_affiliation_string":"K. W. M. Siu, Institute for Environmental Research and Technology, National Research Council of Canada, Montreal Road, Ottawa, Ontario, K1A OR6, Canada","institution_ids":["https://openalex.org/I4210159778"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5102801878","https://openalex.org/A5113522825"],"corresponding_institution_ids":["https://openalex.org/I204722609","https://openalex.org/I4210159778"],"apc_list":null,"apc_paid":null,"fwci":1.5277,"has_fulltext":false,"cited_by_count":43,"citation_normalized_percentile":{"value":0.79206049,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"29","issue":"11","first_page":"587","last_page":"593"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12776","display_name":"Electrohydrodynamics and Fluid Dynamics","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10519","display_name":"Advanced Proteomics Techniques and Applications","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/gramicidin-s","display_name":"gramicidin S","score":0.8870000243186951},{"id":"https://openalex.org/keywords/nitrogen-containing-bases","display_name":"nitrogen-containing bases","score":0.7590000033378601},{"id":"https://openalex.org/keywords/proton-affinity","display_name":"proton affinity","score":0.8650000095367432},{"id":"https://openalex.org/keywords/collision-induced-dissociation","display_name":"collision-induced dissociation","score":0.7559999823570251},{"id":"https://openalex.org/keywords/alkaline-media","display_name":"alkaline solution","score":0.6110000014305115},{"id":"https://openalex.org/keywords/solution-ph","display_name":"solution pH","score":0.49300000071525574}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8874212503433228},{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.8196649551391602},{"id":"https://openalex.org/C194451485","wikidata":"https://www.wikidata.org/wiki/Q1327575","display_name":"Electrospray","level":3,"score":0.6036126613616943},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.573070228099823},{"id":"https://openalex.org/C40325409","wikidata":"https://www.wikidata.org/wiki/Q2360668","display_name":"Mass spectrum","level":3,"score":0.5565255284309387},{"id":"https://openalex.org/C162356407","wikidata":"https://www.wikidata.org/wiki/Q180809","display_name":"Mass spectrometry","level":2,"score":0.49569571018218994},{"id":"https://openalex.org/C54516573","wikidata":"https://www.wikidata.org/wiki/Q2294","display_name":"Proton","level":2,"score":0.4868128001689911},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.48591795563697815},{"id":"https://openalex.org/C53323650","wikidata":"https://www.wikidata.org/wiki/Q1118362","display_name":"Proton affinity","level":4,"score":0.4566340744495392},{"id":"https://openalex.org/C537208039","wikidata":"https://www.wikidata.org/wiki/Q627","display_name":"Nitrogen","level":2,"score":0.44339752197265625},{"id":"https://openalex.org/C40684141","wikidata":"https://www.wikidata.org/wiki/Q902061","display_name":"Electrospray ionization","level":3,"score":0.4419284164905548},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.42255908250808716},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.4051763415336609},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3462541401386261},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.13494271039962769},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12663868069648743},{"id":"https://openalex.org/C30095370","wikidata":"https://www.wikidata.org/wiki/Q899488","display_name":"Protonation","level":3,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/oms.1210291103","doi":"https://doi.org/10.1002/oms.1210291103","is_oa":false,"landing_page_url":"https://doi.org/10.1002/oms.1210291103","pdf_url":null,"source":{"id":"https://openalex.org/S4210228587","display_name":"Organic Mass Spectrometry","issn_l":"0030-493X","issn":["0030-493X","2376-3884"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic Mass Spectrometry","raw_type":"journal-article"},{"id":"pmh:oai:cisti-icist.nrc-cnrc.ca:cistinparc:8898262","doi":null,"is_oa":false,"landing_page_url":"https://nrc-publications.canada.ca/eng/view/object/?id=48ba3db4-92f3-4488-9434-558e9f0f6c6d","pdf_url":null,"source":{"id":"https://openalex.org/S7407055245","display_name":"NPARC","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":32,"referenced_works":["https://openalex.org/W1964015289","https://openalex.org/W1967699885","https://openalex.org/W1969242164","https://openalex.org/W1973588530","https://openalex.org/W1980310871","https://openalex.org/W1982682864","https://openalex.org/W1989510416","https://openalex.org/W1998881957","https://openalex.org/W1999153920","https://openalex.org/W2019748786","https://openalex.org/W2021419574","https://openalex.org/W2022042248","https://openalex.org/W2023993152","https://openalex.org/W2025914365","https://openalex.org/W2030043624","https://openalex.org/W2033210824","https://openalex.org/W2039552227","https://openalex.org/W2043250176","https://openalex.org/W2044209606","https://openalex.org/W2056825341","https://openalex.org/W2062551574","https://openalex.org/W2068248648","https://openalex.org/W2070458959","https://openalex.org/W2090470824","https://openalex.org/W2108112365","https://openalex.org/W2111978895","https://openalex.org/W2131796417","https://openalex.org/W2145571626","https://openalex.org/W2739616593","https://openalex.org/W2896868837","https://openalex.org/W4238867104","https://openalex.org/W4301131420"],"related_works":["https://openalex.org/W4386378192","https://openalex.org/W2044686648","https://openalex.org/W4406077356","https://openalex.org/W2131796417","https://openalex.org/W3207529685","https://openalex.org/W2047586621","https://openalex.org/W2036458219","https://openalex.org/W2073436366","https://openalex.org/W1998881957","https://openalex.org/W2076762205"],"abstract_inverted_index":{"Abstract":[0],"The":[1,21],"electrospray":[2,86],"mass":[3],"spectra":[4],"of":[5,15,24,49,57,103],"gramicidin":[6],"S":[7],"cations":[8],"that":[9,55],"originated":[10],"from":[11],"0.2":[12],"M":[13],"solutions":[14],"18":[16],"nitrogen\u2010containing":[17],"bases":[18,74],"were":[19,35,106],"examined.":[20],"relative":[22],"abundances":[23],"the":[25,30,41,46,50,58,63,72,82,90],"[M":[26,31,59,64],"+":[27,32,60,65],"2H]2+":[28,61],"to":[29,37,96],"H]+":[33,66],"ion":[34],"found":[36],"correlate":[38],"not":[39],"with":[40,45,71],"solution":[42],"pH":[43],"but":[44],"proton":[47,99],"affinities":[48],"bases.":[51],"It":[52],"is":[53],"postulated":[54],"some":[56],"and":[62,87],"ions":[67],"exist":[68],"as":[69],"adducts":[70,78,105],"nitrogen":[73],"in":[75,89],"solution,":[76],"these":[77,104],"being":[79],"desorbed":[80],"into":[81],"gas":[83],"phase":[84],"during":[85],"dissociated":[88],"lens":[91],"region":[92],"via":[93],"collision\u2010induced":[94],"dissociations":[95],"yield":[97],"apparent":[98],"attachment":[100],"spectra.":[101],"Some":[102],"observed":[107],"under":[108],"nominally":[109],"zero":[110],"collision":[111],"energy":[112],"conditions.":[113]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2019,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":2},{"year":2014,"cited_by_count":6},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":2}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}