{"id":"https://openalex.org/W2033765893","doi":"https://doi.org/10.1021/jp511074y","title":"Relationship between Activation Volume and Polymer Matrix Effects on Photochromic Performance: Bridging Molecular Parameter to Macroscale Effect","display_name":"Relationship between Activation Volume and Polymer Matrix Effects on Photochromic Performance: Bridging Molecular Parameter to Macroscale Effect","publication_year":2015,"publication_date":"2015-01-26","ids":{"openalex":"https://openalex.org/W2033765893","doi":"https://doi.org/10.1021/jp511074y","mag":"2033765893","pmid":"https://pubmed.ncbi.nlm.nih.gov/25621415"},"language":"en","primary_location":{"id":"doi:10.1021/jp511074y","doi":"https://doi.org/10.1021/jp511074y","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp511074y","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5103745461","display_name":"Kentaro Shima","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I131231118","display_name":"Aoyama Gakuin University","ror":"https://ror.org/002rw7y37","country_code":"JP","type":"education","lineage":["https://openalex.org/I131231118"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Kentaro Shima","raw_affiliation_strings":["Department of Chemistry, School of Science and Engineering , Aoyama Gakuin University , 5-10-1 Fuchinobe , Chuo-ku, Sagamihara , Kanagawa 252-5258 , Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, School of Science and Engineering , Aoyama Gakuin University , 5-10-1 Fuchinobe , Chuo-ku, Sagamihara , Kanagawa 252-5258 , Japan","institution_ids":["https://openalex.org/I131231118"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020605134","display_name":"Katsuya Mutoh","orcid":"https://orcid.org/0000-0002-9778-8329","observed_orcids":["https://orcid.org/0000-0002-9778-8329"]},"institutions":[{"id":"https://openalex.org/I131231118","display_name":"Aoyama Gakuin University","ror":"https://ror.org/002rw7y37","country_code":"JP","type":"education","lineage":["https://openalex.org/I131231118"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Katsuya Mutoh","raw_affiliation_strings":["Department\rof Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan","Department#R#of Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan","institution_ids":["https://openalex.org/I131231118"]},{"raw_affiliation_string":"Department#R#of Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan","institution_ids":["https://openalex.org/I131231118"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100681622","display_name":"Yoichi Kobayashi","orcid":"https://orcid.org/0000-0003-3339-3755","observed_orcids":["https://orcid.org/0000-0003-3339-3755"]},"institutions":[{"id":"https://openalex.org/I131231118","display_name":"Aoyama Gakuin University","ror":"https://ror.org/002rw7y37","country_code":"JP","type":"education","lineage":["https://openalex.org/I131231118"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yoichi Kobayashi","raw_affiliation_strings":["Department\rof Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan","Department#R#of Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan","institution_ids":["https://openalex.org/I131231118"]},{"raw_affiliation_string":"Department#R#of Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan","institution_ids":["https://openalex.org/I131231118"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5066209471","display_name":"Jiro Abe","orcid":"https://orcid.org/0000-0002-0237-815X","observed_orcids":["https://orcid.org/0000-0002-0237-815X"]},"institutions":[{"id":"https://openalex.org/I131231118","display_name":"Aoyama Gakuin University","ror":"https://ror.org/002rw7y37","country_code":"JP","type":"education","lineage":["https://openalex.org/I131231118"]},{"id":"https://openalex.org/I4210086780","display_name":"Japan Science and Technology Agency","ror":"https://ror.org/00097mb19","country_code":"JP","type":"government","lineage":["https://openalex.org/I1319490839","https://openalex.org/I4210086780"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Jiro Abe","raw_affiliation_strings":["CREST, Japan Science and Technology Agency (JST), K\u2019s Gobancho, 7 Gobancho, Chiyoda-ku, Tokyo 102-0076, Japan","Department\rof Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan","Department#R#of Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe,#R#Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CREST, Japan Science and Technology Agency (JST), K\u2019s Gobancho, 7 Gobancho, Chiyoda-ku, Tokyo 102-0076, Japan","institution_ids":["https://openalex.org/I4210086780"]},{"raw_affiliation_string":"Department\rof Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan","institution_ids":["https://openalex.org/I131231118"]},{"raw_affiliation_string":"Department#R#of Chemistry, School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe,#R#Chuo-ku, Sagamihara, Kanagawa 252-5258, Japan","institution_ids":["https://openalex.org/I131231118"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5066209471"],"corresponding_institution_ids":["https://openalex.org/I131231118","https://openalex.org/I4210086780"],"apc_list":null,"apc_paid":null,"fwci":0.6002,"has_fulltext":false,"cited_by_count":9,"citation_normalized_percentile":{"value":0.61264913,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":98},"biblio":{"volume":"119","issue":"7","first_page":"1087","last_page":"1093"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11708","display_name":"Photochromic and Fluorescence Chemistry","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11708","display_name":"Photochromic and Fluorescence Chemistry","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10306","display_name":"Liquid Crystal Research Advancements","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10810","display_name":"Polymer composites and self-healing","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photochromism","display_name":"photochromism","score":0.9210000038146973},{"id":"https://openalex.org/keywords/activation-volume","display_name":"activation volume","score":0.765999972820282},{"id":"https://openalex.org/keywords/ophthalmic-lenses","display_name":"ophthalmic lenses","score":0.7760000228881836},{"id":"https://openalex.org/keywords/polymer-matrix-effects","display_name":"polymer matrix effects","score":0.7680000066757202},{"id":"https://openalex.org/keywords/pressure-effects","display_name":"pressure effects","score":0.7590000033378601},{"id":"https://openalex.org/keywords/thermal-back-reaction","display_name":"thermal back reaction","score":0.921999990940094},{"id":"https://openalex.org/keywords/diradicals","display_name":"biradicals","score":0.6930000185966492}],"concepts":[{"id":"https://openalex.org/C81180622","wikidata":"https://www.wikidata.org/wiki/Q899324","display_name":"Photochromism","level":2,"score":0.9969197511672974},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5800611972808838},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5677229166030884},{"id":"https://openalex.org/C2776663404","wikidata":"https://www.wikidata.org/wiki/Q5479379","display_name":"Photoswitch","level":2,"score":0.5531283617019653},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5190718770027161},{"id":"https://openalex.org/C2780874372","wikidata":"https://www.wikidata.org/wiki/Q328692","display_name":"Imidazole","level":2,"score":0.5020642280578613},{"id":"https://openalex.org/C2778150588","wikidata":"https://www.wikidata.org/wiki/Q8884513","display_name":"Azobenzene","level":3,"score":0.48584434390068054},{"id":"https://openalex.org/C2780258612","wikidata":"https://www.wikidata.org/wiki/Q4180469","display_name":"Diarylethene","level":3,"score":0.48582908511161804},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.41397011280059814},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17445752024650574},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.14897805452346802}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/jp511074y","doi":"https://doi.org/10.1021/jp511074y","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp511074y","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},{"id":"pmid:25621415","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/25621415","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The journal of physical chemistry. A","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G5099049861","display_name":null,"funder_award_id":"26107010","funder_id":"https://openalex.org/F4320320912","funder_display_name":"Ministry of Education, Culture, Sports, Science and Technology"},{"id":"https://openalex.org/G5206893338","display_name":"Developments and Applications of Nonlinear Photoresponsive Photochromic Materials","funder_award_id":"15K17846","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"}],"funders":[{"id":"https://openalex.org/F4320320912","display_name":"Ministry of Education, Culture, Sports, Science and Technology","ror":"https://ror.org/048rj2z13"},{"id":"https://openalex.org/F4320334764","display_name":"Japan Society for the Promotion of Science","ror":"https://ror.org/00hhkn466"},{"id":"https://openalex.org/F4320334789","display_name":"Japan Science and Technology Agency","ror":"https://ror.org/00097mb19"},{"id":"https://openalex.org/F4320338075","display_name":"Core Research for Evolutional Science and Technology","ror":"https://ror.org/00097mb19"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":50,"referenced_works":["https://openalex.org/W1559264985","https://openalex.org/W1577903243","https://openalex.org/W1935025948","https://openalex.org/W1965271989","https://openalex.org/W1970861569","https://openalex.org/W1971254189","https://openalex.org/W1980282975","https://openalex.org/W1981640824","https://openalex.org/W1990690596","https://openalex.org/W1998070214","https://openalex.org/W2003406884","https://openalex.org/W2008631272","https://openalex.org/W2013343628","https://openalex.org/W2022646701","https://openalex.org/W2027786122","https://openalex.org/W2028796447","https://openalex.org/W2030305267","https://openalex.org/W2030410460","https://openalex.org/W2038665403","https://openalex.org/W2045102664","https://openalex.org/W2048364478","https://openalex.org/W2051074850","https://openalex.org/W2052819051","https://openalex.org/W2055381081","https://openalex.org/W2055610356","https://openalex.org/W2063840891","https://openalex.org/W2071712203","https://openalex.org/W2075111853","https://openalex.org/W2080155722","https://openalex.org/W2082906655","https://openalex.org/W2084287827","https://openalex.org/W2088810569","https://openalex.org/W2088916796","https://openalex.org/W2090329067","https://openalex.org/W2093935173","https://openalex.org/W2096777394","https://openalex.org/W2114162092","https://openalex.org/W2115507694","https://openalex.org/W2157647075","https://openalex.org/W2159636613","https://openalex.org/W2320067119","https://openalex.org/W2321950197","https://openalex.org/W2323082192","https://openalex.org/W2323993416","https://openalex.org/W2324940201","https://openalex.org/W2326033492","https://openalex.org/W2327383055","https://openalex.org/W2329683927","https://openalex.org/W2342620475","https://openalex.org/W4250316370"],"related_works":["https://openalex.org/W2080155722","https://openalex.org/W2074301547","https://openalex.org/W2028796447","https://openalex.org/W2161394281","https://openalex.org/W4415213002","https://openalex.org/W190585632","https://openalex.org/W2949390969","https://openalex.org/W2615064793","https://openalex.org/W2075962827","https://openalex.org/W60575133"],"abstract_inverted_index":{"Photochromic":[0],"compounds":[1,201],"have":[2],"attracted":[3],"attention":[4],"as":[5],"ophthalmic":[6,67],"lenses":[7],"because":[8,30,177],"of":[9,21,31,54,57,74,89,93,126,137,150],"their":[10,28],"reversible":[11],"color":[12],"modulation":[13],"upon":[14],"irradiation":[15],"with":[16,36],"light.":[17],"However,":[18],"the":[19,22,32,37,41,44,48,52,55,58,66,75,87,90,101,105,119,123,134,138,148,151,155,161,169,174,178,185,191,206,209],"efficiency":[20],"photochromism":[23],"is":[24,61,165,181],"strongly":[25],"affected":[26,183],"by":[27,184],"surrounding":[29],"structural":[33,59,106,152],"changes":[34,60,107],"concomitant":[35],"photochromism,":[38],"which":[39],"causes":[40],"decrease":[42],"in":[43,47,112,173,208],"photochromic":[45,81,91,124,156,171,179,200,215],"performance":[46],"polymer":[49,175,210],"matrix.":[50],"Therefore,":[51],"clarification":[53],"degree":[56,149],"necessary":[62],"to":[63,65,146,197],"apply":[64],"lenses.":[68],"Bridged":[69],"imidazole":[70,95,128],"dimers":[71,96],"are":[72,203],"one":[73],"fast":[76,199],"photoswitch":[77],"molecules":[78],"possessing":[79],"high":[80],"quantum":[82],"yield":[83],"and":[84,212],"durability.":[85],"Although":[86],"enhancement":[88],"properties":[92,125],"bridged":[94,127],"has":[97,108],"been":[98,110],"vigorously":[99],"studied,":[100],"quantitative":[102],"information":[103,196],"about":[104],"not":[109,182],"revealed":[111,159],"detail.":[113],"In":[114],"this":[115],"study,":[116],"we":[117],"investigated":[118],"pressure":[120,213],"effects":[121],"on":[122],"dimers.":[129],"The":[130],"activation":[131,163],"volume":[132,164],"for":[133,167,205],"thermal":[135],"back-reaction":[136],"photogenerated":[139],"biradical":[140],"species":[141],"becomes":[142],"an":[143],"effective":[144],"measure":[145],"predict":[147],"change":[153],"during":[154],"reaction.":[157],"We":[158],"that":[160,202],"smaller":[162],"suitable":[166,204],"keeping":[168],"efficient":[170],"reaction":[172,180],"matrix":[176,211],"surroundings.":[186],"These":[187],"fundamental":[188],"insights":[189],"into":[190],"molecular":[192],"dynamics":[193],"provide":[194],"valuable":[195],"develop":[198],"use":[207],"sensitive":[214],"materials.":[216]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":4}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}