{"id":"https://openalex.org/W2029338148","doi":"https://doi.org/10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.0.co;2-x","title":"New DNA-binding ruthenium(II) complexes as photo-reagents for mononucleotides and DNA","display_name":"New DNA-binding ruthenium(II) complexes as photo-reagents for mononucleotides and DNA","publication_year":1998,"publication_date":"1998-08-01","ids":{"openalex":"https://openalex.org/W2029338148","doi":"https://doi.org/10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.0.co;2-x","mag":"2029338148"},"language":"en","primary_location":{"id":"doi:10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.0.co;2-x","doi":"https://doi.org/10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.0.co;2-x","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.0.co;2-x","pdf_url":null,"source":{"id":"https://openalex.org/S157344032","display_name":"Journal of Physical Organic Chemistry","issn_l":"0894-3230","issn":["0894-3230","1099-1395"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Physical Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5044864288","display_name":"C\u00e9cile Moucheron","orcid":"https://orcid.org/0000-0001-9293-0165","observed_orcids":["https://orcid.org/0000-0001-9293-0165"]},"institutions":[{"id":"https://openalex.org/I132053463","display_name":"Universit\u00e9 Libre de Bruxelles","ror":"https://ror.org/01r9htc13","country_code":"BE","type":"education","lineage":["https://openalex.org/I132053463"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"C\ufffdcile Moucheron","raw_affiliation_strings":["Physical Organic Chemistry, CP 160/08, Universite\u0301 Libre de Bruxelles, 50 Avenue F. D. Roosevelt, B-1050 Brussels, Belgium","Physical Organic Chemistry, CP 160/08, Universit\u00e9 Libre de Bruxelles, 50 Avenue F. D. Roosevelt, B-1050 Brussels, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical Organic Chemistry, CP 160/08, Universite\u0301 Libre de Bruxelles, 50 Avenue F. D. Roosevelt, B-1050 Brussels, Belgium","institution_ids":["https://openalex.org/I132053463"]},{"raw_affiliation_string":"Physical Organic Chemistry, CP 160/08, Universit\u00e9 Libre de Bruxelles, 50 Avenue F. D. Roosevelt, B-1050 Brussels, Belgium","institution_ids":["https://openalex.org/I132053463"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5032450006","display_name":"Andr\u00e9e Kirsch\u2010De Mesmaeker","orcid":"https://orcid.org/0000-0002-4331-4347","observed_orcids":["https://orcid.org/0000-0002-4331-4347"]},"institutions":[{"id":"https://openalex.org/I132053463","display_name":"Universit\u00e9 Libre de Bruxelles","ror":"https://ror.org/01r9htc13","country_code":"BE","type":"education","lineage":["https://openalex.org/I132053463"]},{"id":"https://openalex.org/I17653759","display_name":"Fund for Scientific Research","ror":"https://ror.org/03q83t159","country_code":"BE","type":"nonprofit","lineage":["https://openalex.org/I17653759"]}],"countries":["BE"],"is_corresponding":true,"raw_author_name":"Andr\ufffde Kirsch-De Mesmaeker","raw_affiliation_strings":["Director of Research at the National Fund for Scientific Research (Belgium)","Physical Organic Chemistry, CP 160/08, Universite\u0301 Libre de Bruxelles, 50 Avenue F. D. Roosevelt, B-1050 Brussels, Belgium","Physical Organic Chemistry, CP 160/08, Universit\u00e9 Libre de Bruxelles, 50 Avenue F. D. Roosevelt, B-1050 Brussels, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Director of Research at the National Fund for Scientific Research (Belgium)","institution_ids":["https://openalex.org/I17653759"]},{"raw_affiliation_string":"Physical Organic Chemistry, CP 160/08, Universite\u0301 Libre de Bruxelles, 50 Avenue F. D. Roosevelt, B-1050 Brussels, Belgium","institution_ids":["https://openalex.org/I132053463"]},{"raw_affiliation_string":"Physical Organic Chemistry, CP 160/08, Universit\u00e9 Libre de Bruxelles, 50 Avenue F. D. Roosevelt, B-1050 Brussels, Belgium","institution_ids":["https://openalex.org/I132053463"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5032450006"],"corresponding_institution_ids":["https://openalex.org/I132053463","https://openalex.org/I17653759"],"apc_list":{"value":3930,"currency":"USD","value_usd":3930},"apc_paid":null,"fwci":0.9259,"has_fulltext":false,"cited_by_count":55,"citation_normalized_percentile":{"value":0.74582911,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"11","issue":"8-9","first_page":"577","last_page":"583"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.9082000255584717,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},"topics":[{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.9082000255584717,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.07039999961853027,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10432","display_name":"DNA and Nucleic Acid Chemistry","score":0.010599999688565731,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ruthenium-ii-complexes","display_name":"ruthenium(II) complexes","score":0.9959999918937683},{"id":"https://openalex.org/keywords/dna-intercalation","display_name":"DNA intercalation","score":0.7120000123977661},{"id":"https://openalex.org/keywords/dna-binding","display_name":"DNA binding","score":0.5059999823570251},{"id":"https://openalex.org/keywords/luminescence-quenching","display_name":"luminescence quenching","score":0.8040000200271606},{"id":"https://openalex.org/keywords/photoinduced-electron-transfer","display_name":"photoinduced electron transfer","score":0.7630000114440918},{"id":"https://openalex.org/keywords/guanine","display_name":"guanine","score":0.628000020980835},{"id":"https://openalex.org/keywords/1-10-phenanthroline","display_name":"1,10-phenanthroline","score":0.7720000147819519},{"id":"https://openalex.org/keywords/dppz-ligand","display_name":"dppz ligand","score":0.8040000200271606},{"id":"https://openalex.org/keywords/pi-acceptor-ligands","display_name":"\u03c0-acceptor ligands","score":0.8650000095367432},{"id":"https://openalex.org/keywords/mlct-transitions","display_name":"MLCT transitions","score":0.7929999828338623},{"id":"https://openalex.org/keywords/good-manufacturing-practices","display_name":"good manufacturing practices","score":0.6589999794960022}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9228147268295288},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.8622202277183533},{"id":"https://openalex.org/C192468462","wikidata":"https://www.wikidata.org/wiki/Q533543","display_name":"Chromophore","level":2,"score":0.6253647804260254},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5664303302764893},{"id":"https://openalex.org/C2778301229","wikidata":"https://www.wikidata.org/wiki/Q169313","display_name":"Guanine","level":4,"score":0.5544961094856262},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5464283227920532},{"id":"https://openalex.org/C121745418","wikidata":"https://www.wikidata.org/wiki/Q585536","display_name":"Quenching (fluorescence)","level":3,"score":0.5442916750907898},{"id":"https://openalex.org/C2778367558","wikidata":"https://www.wikidata.org/wiki/Q908729","display_name":"Luminophore","level":3,"score":0.5118417143821716},{"id":"https://openalex.org/C552990157","wikidata":"https://www.wikidata.org/wiki/Q7430","display_name":"DNA","level":2,"score":0.49364814162254333},{"id":"https://openalex.org/C148869448","wikidata":"https://www.wikidata.org/wiki/Q184240","display_name":"Luminescence","level":2,"score":0.4580281376838684},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.4505229890346527},{"id":"https://openalex.org/C137824038","wikidata":"https://www.wikidata.org/wiki/Q175562","display_name":"Intercalation (chemistry)","level":2,"score":0.441983699798584},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.37756848335266113},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.37651723623275757},{"id":"https://openalex.org/C91881484","wikidata":"https://www.wikidata.org/wiki/Q191807","display_name":"Fluorescence","level":2,"score":0.2713906764984131},{"id":"https://openalex.org/C512185932","wikidata":"https://www.wikidata.org/wiki/Q28745","display_name":"Nucleotide","level":3,"score":0.22981733083724976},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.12961161136627197},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0778435468673706},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.07544821500778198},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C104317684","wikidata":"https://www.wikidata.org/wiki/Q7187","display_name":"Gene","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.0}],"mesh":[],"locations_count":5,"locations":[{"id":"doi:10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.0.co;2-x","doi":"https://doi.org/10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.0.co;2-x","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.0.co;2-x","pdf_url":null,"source":{"id":"https://openalex.org/S157344032","display_name":"Journal of Physical Organic Chemistry","issn_l":"0894-3230","issn":["0894-3230","1099-1395"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Physical Organic Chemistry","raw_type":"journal-article"},{"id":"doi:10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.3.co;2-o","doi":"https://doi.org/10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.3.co;2-o","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1099-1395(199808/09)11:8/9<577::aid-poc53>3.3.co;2-o","pdf_url":null,"source":{"id":"https://openalex.org/S157344032","display_name":"Journal of Physical Organic Chemistry","issn_l":"0894-3230","issn":["0894-3230","1099-1395"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Physical Organic Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:dipot.ulb.ac.be:2013/157980","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/157980","pdf_url":null,"source":{"id":"https://openalex.org/S4306401063","display_name":"D\u00e9p\u00f4t institutionnel de l'Universit\u00e9 libre de Bruxelles (Universit\u00e9 Libre de Bruxelles)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I132053463","host_organization_name":"Universit\u00e9 Libre de Bruxelles","host_organization_lineage":["https://openalex.org/I132053463"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"info:eu-repo/semantics/conferenceContribution"},{"id":"pmh:oai:dipot.ulb.ac.be:2013/171807","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/171807","pdf_url":null,"source":{"id":"https://openalex.org/S4306401063","display_name":"D\u00e9p\u00f4t institutionnel de l'Universit\u00e9 libre de Bruxelles (Universit\u00e9 Libre de Bruxelles)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I132053463","host_organization_name":"Universit\u00e9 Libre de Bruxelles","host_organization_lineage":["https://openalex.org/I132053463"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"info:eu-repo/semantics/conferencePoster"},{"id":"pmh:oai:dipot.ulb.ac.be:2013/77062","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/77062","pdf_url":null,"source":{"id":"https://openalex.org/S4306401063","display_name":"D\u00e9p\u00f4t institutionnel de l'Universit\u00e9 libre de Bruxelles (Universit\u00e9 Libre de Bruxelles)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I132053463","host_organization_name":"Universit\u00e9 Libre de Bruxelles","host_organization_lineage":["https://openalex.org/I132053463"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of physical organic chemistry, 11","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":27,"referenced_works":["https://openalex.org/W9467428","https://openalex.org/W74691089","https://openalex.org/W328635730","https://openalex.org/W1968158760","https://openalex.org/W1968330562","https://openalex.org/W1985795337","https://openalex.org/W1986197536","https://openalex.org/W1988094249","https://openalex.org/W1989651677","https://openalex.org/W1991163357","https://openalex.org/W1995661103","https://openalex.org/W2000093684","https://openalex.org/W2005252051","https://openalex.org/W2018837467","https://openalex.org/W2024390131","https://openalex.org/W2025078740","https://openalex.org/W2060335449","https://openalex.org/W2070278984","https://openalex.org/W2081335459","https://openalex.org/W2090872831","https://openalex.org/W2092329486","https://openalex.org/W2122595849","https://openalex.org/W2131137528","https://openalex.org/W2154914577","https://openalex.org/W2166449844","https://openalex.org/W2341886455","https://openalex.org/W4381511361"],"related_works":["https://openalex.org/W1995661103","https://openalex.org/W1997658099","https://openalex.org/W1984877116","https://openalex.org/W7066608688","https://openalex.org/W328635730","https://openalex.org/W2080777649","https://openalex.org/W1991163357","https://openalex.org/W2049419333","https://openalex.org/W2945679329","https://openalex.org/W1975993567"],"abstract_inverted_index":{"The":[0,38,69],"spectroscopic":[1],"properties":[2],"of":[3,26,79,99,115,122,134,143],"two":[4,70],"photoprobes":[5],"for":[6,47,58],"DNA,":[7],"Ru(phen)2(PHEHAT)2+":[8,48],"and":[9,22,44,56,151],"Ru(TAP)2(PHEHAT)2+":[10,59,100],"(phen":[11],"=":[12,15,18],"1,10-phenanthroline,":[13],"TAP":[14,66],"1,4,5,8-tetraazaphenanthrene,":[16],"PHEHAT":[17,51],"1,10-phenanthrolino[5,6-b]-1,4,5,8,9,12-hexaazatriphenylene),":[19],"were":[20],"examined":[21],"compared":[23],"with":[24,62,117],"those":[25],"complexes":[27,71],"containing":[28],"either":[29],"an":[30],"extended":[31],"planar":[32],"ligand":[33],"(DPPZ)":[34],"or":[35,145],"\u03c0-acceptor":[36],"ligands.":[37],"orbitals":[39],"involved":[40],"in":[41,76,87,112],"the":[42,50,54,63,77,93,97,113,132,140,148,154],"absorption":[43],"emission":[45],"processes":[46],"imply":[49],"ligand,":[52],"whereas":[53],"chromophore":[55],"luminophore":[57],"are":[60],"associated":[61],"Ru(II)":[64],"\u2192":[65],"MLCT":[67],"transition.":[68],"exhibit":[72],"completely":[73],"different":[74],"behaviour":[75],"presence":[78,114,133],"DNA.":[80,106],"Whereas":[81],"Ru(phen)2(PHEHAT)2+,":[82],"which":[83],"does":[84],"not":[85],"emit":[86],"water,":[88],"luminesces":[89],"upon":[90],"intercalation":[91],"between":[92],"DNA":[94,146,162],"base":[95],"pairs,":[96],"luminescence":[98],"is":[101,109,159],"quenched":[102],"by":[103],"binding":[104],"to":[105,147,153],"Emission":[107],"quenching":[108,119],"also":[110],"observed":[111],"GMP,":[116],"a":[118,135,160],"rate":[120],"constant":[121],"1.25":[123],"\u00d7":[124],"109":[125],"l":[126],"mol\u22121":[127],"s\u22121.":[128],"This":[129],"strongly":[130],"suggests":[131],"photo-induced":[136],"electron":[137],"transfer":[138],"from":[139],"guanine":[141],"residues":[142],"GMP":[144],"excited":[149],"complex":[150,158],"leads":[152],"conclusion":[155],"that":[156],"this":[157],"good":[161],"photoreagent.":[163],"\u00a9":[164],"1998":[165],"John":[166],"Wiley":[167],"&":[168],"Sons,":[169],"Ltd.":[170]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":5},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}