{"id":"https://openalex.org/W2026972799","doi":"https://doi.org/10.1039/c3ee42328j","title":"Diamine-functionalized metal\u2013organic framework: exceptionally high CO 2 capacities from ambient air and flue gas, ultrafast CO 2 uptake rate, and adsorption mechanism","display_name":"Diamine-functionalized metal\u2013organic framework: exceptionally high CO 2 capacities from ambient air and flue gas, ultrafast CO 2 uptake rate, and adsorption mechanism","publication_year":2013,"publication_date":"2013-11-04","ids":{"openalex":"https://openalex.org/W2026972799","doi":"https://doi.org/10.1039/c3ee42328j","mag":"2026972799"},"language":"en","primary_location":{"id":"doi:10.1039/c3ee42328j","doi":"https://doi.org/10.1039/c3ee42328j","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3ee42328j","pdf_url":null,"source":{"id":"https://openalex.org/S117082959","display_name":"Energy & Environmental Science","issn_l":"1754-5692","issn":["1754-5692","1754-5706"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Energy Environ. Sci.","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101690179","display_name":"Woo Ram Lee","orcid":"https://orcid.org/0000-0002-2450-1315","observed_orcids":["https://orcid.org/0000-0002-2450-1315"]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Woo Ram Lee","raw_affiliation_strings":["Department of Chemistry, Korea University, Seoul 136-713, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Korea University, Seoul 136-713, Korea","institution_ids":["https://openalex.org/I197347611"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102742755","display_name":"Sang Yeon Hwang","orcid":"https://orcid.org/0000-0002-2273-4967","observed_orcids":["https://orcid.org/0000-0002-2273-4967"]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Sang Yeon Hwang","raw_affiliation_strings":["Department of Chemistry, Korea University, Seoul 136-713, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Korea University, Seoul 136-713, Korea","institution_ids":["https://openalex.org/I197347611"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111783825","display_name":"Dae Won Ryu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Dae Won Ryu","raw_affiliation_strings":["Department of Chemistry, Korea University, Seoul 136-713, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Korea University, Seoul 136-713, Korea","institution_ids":["https://openalex.org/I197347611"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111605229","display_name":"Kwang Soo Lim","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Kwang Soo Lim","raw_affiliation_strings":["Department of Chemistry, Korea University, Seoul 136-713, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Korea University, Seoul 136-713, Korea","institution_ids":["https://openalex.org/I197347611"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067470445","display_name":"Sang Soo Han","orcid":"https://orcid.org/0000-0002-7925-8105","observed_orcids":["https://orcid.org/0000-0002-7925-8105"]},"institutions":[{"id":"https://openalex.org/I58716616","display_name":"Korea Institute of Science and Technology","ror":"https://ror.org/05kzfa883","country_code":"KR","type":"facility","lineage":["https://openalex.org/I27494661","https://openalex.org/I2801339556","https://openalex.org/I4210144908","https://openalex.org/I4387152098","https://openalex.org/I58716616"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Sang Soo Han","raw_affiliation_strings":["Center for Computational Science, Korea Institute of Science and Technology (KIST), Hwarangno 14-gil 5, Seongbuk-gu, Seoul 136-791, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Computational Science, Korea Institute of Science and Technology (KIST), Hwarangno 14-gil 5, Seongbuk-gu, Seoul 136-791, Korea","institution_ids":["https://openalex.org/I58716616"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5035536938","display_name":"Dohyun Moon","orcid":"https://orcid.org/0000-0002-6903-0270","observed_orcids":["https://orcid.org/0000-0002-6903-0270"]},"institutions":[{"id":"https://openalex.org/I4387152139","display_name":"Pohang Accelerator Laboratory","ror":"https://ror.org/02gntzb40","country_code":"KR","type":"facility","lineage":["https://openalex.org/I123900574","https://openalex.org/I2801339556","https://openalex.org/I4387152098","https://openalex.org/I4387152139"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Dohyun Moon","raw_affiliation_strings":["Beamline Division, Pohang Accelerator Laboratory, Pohang, Kyungbuk 790-784, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Beamline Division, Pohang Accelerator Laboratory, Pohang, Kyungbuk 790-784, Korea","institution_ids":["https://openalex.org/I4387152139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067483266","display_name":"Jungkyu Choi","orcid":"https://orcid.org/0000-0003-1137-4799","observed_orcids":["https://orcid.org/0000-0003-1137-4799"]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Jungkyu Choi","raw_affiliation_strings":["Department of Chemical & Biological Engineering, Korea University, Seoul 136-713, Korea","Green School, Korea University, Seoul 136-713, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical & Biological Engineering, Korea University, Seoul 136-713, Korea","institution_ids":["https://openalex.org/I197347611"]},{"raw_affiliation_string":"Green School, Korea University, Seoul 136-713, Korea","institution_ids":["https://openalex.org/I197347611"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5052171305","display_name":"Chang Seop Hong","orcid":"https://orcid.org/0000-0002-4329-4745","observed_orcids":["https://orcid.org/0000-0002-4329-4745"]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Chang Seop Hong","raw_affiliation_strings":["Department of Chemistry, Korea University, Seoul 136-713, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Korea University, Seoul 136-713, Korea","institution_ids":["https://openalex.org/I197347611"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5052171305"],"corresponding_institution_ids":["https://openalex.org/I197347611"],"apc_list":null,"apc_paid":null,"fwci":8.1557,"has_fulltext":false,"cited_by_count":332,"citation_normalized_percentile":{"value":0.98832685,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"7","issue":"2","first_page":"744","last_page":"751"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10967","display_name":"Carbon Dioxide Capture Technologies","score":0.9365000128746033,"subfield":{"id":"https://openalex.org/subfields/1506","display_name":"Filtration and Separation"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10967","display_name":"Carbon Dioxide Capture Technologies","score":0.9365000128746033,"subfield":{"id":"https://openalex.org/subfields/1506","display_name":"Filtration and Separation"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.06289999932050705,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12038","display_name":"Covalent Organic Framework Applications","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/metal-organic-frameworks","display_name":"metal-organic frameworks","score":0.8309999704360962},{"id":"https://openalex.org/keywords/co2-capture","display_name":"CO2 capture","score":0.7609999775886536},{"id":"https://openalex.org/keywords/ethylenediamine-functionalization","display_name":"ethylenediamine functionalization","score":0.9070000052452087},{"id":"https://openalex.org/keywords/postsynthetic-modification","display_name":"post-synthetic modification","score":0.7879999876022339},{"id":"https://openalex.org/keywords/co2-adsorption-capacity","display_name":"CO2 adsorption capacity","score":0.593999981880188},{"id":"https://openalex.org/keywords/flue-gas","display_name":"flue gas","score":0.7889999747276306},{"id":"https://openalex.org/keywords/ambient-air","display_name":"ambient air","score":0.6100000143051147},{"id":"https://openalex.org/keywords/isosteric-heat-of-adsorption","display_name":"isosteric heat of adsorption","score":0.8410000205039978},{"id":"https://openalex.org/keywords/adsorption-mechanism","display_name":"adsorption mechanism","score":0.6859999895095825},{"id":"https://openalex.org/keywords/adsorption-kinetics","display_name":"adsorption kinetics","score":0.7329999804496765},{"id":"https://openalex.org/keywords/moisture-tolerance","display_name":"humidity tolerance","score":0.6079999804496765},{"id":"https://openalex.org/keywords/recyclability","display_name":"recyclability","score":0.5899999737739563}],"concepts":[{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.781913161277771},{"id":"https://openalex.org/C167206829","wikidata":"https://www.wikidata.org/wiki/Q2556360","display_name":"Flue gas","level":2,"score":0.6916686296463013},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6672742962837219},{"id":"https://openalex.org/C162711632","wikidata":"https://www.wikidata.org/wiki/Q905514","display_name":"Desorption","level":3,"score":0.5614559650421143},{"id":"https://openalex.org/C2779319593","wikidata":"https://www.wikidata.org/wiki/Q412078","display_name":"Carbamic acid","level":2,"score":0.5184438228607178},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.50966477394104},{"id":"https://openalex.org/C179366358","wikidata":"https://www.wikidata.org/wiki/Q909212","display_name":"Metal-organic framework","level":3,"score":0.5085092782974243},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3711088299751282},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3271382451057434},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.21851789951324463},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.21318352222442627}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/c3ee42328j","doi":"https://doi.org/10.1039/c3ee42328j","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3ee42328j","pdf_url":null,"source":{"id":"https://openalex.org/S117082959","display_name":"Energy & Environmental Science","issn_l":"1754-5692","issn":["1754-5692","1754-5706"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Energy Environ. Sci.","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[{"display_name":"Climate action","id":"https://metadata.un.org/sdg/13","score":1.0}],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":46,"referenced_works":["https://openalex.org/W1970095940","https://openalex.org/W1976408176","https://openalex.org/W1983902012","https://openalex.org/W1985354366","https://openalex.org/W1996369650","https://openalex.org/W2000302001","https://openalex.org/W2002799357","https://openalex.org/W2007082361","https://openalex.org/W2007489056","https://openalex.org/W2009368971","https://openalex.org/W2010815720","https://openalex.org/W2011661984","https://openalex.org/W2022165195","https://openalex.org/W2024685013","https://openalex.org/W2047480702","https://openalex.org/W2059420540","https://openalex.org/W2065500091","https://openalex.org/W2073662703","https://openalex.org/W2074445234","https://openalex.org/W2076949647","https://openalex.org/W2079597466","https://openalex.org/W2082846892","https://openalex.org/W2086782801","https://openalex.org/W2091161882","https://openalex.org/W2091280238","https://openalex.org/W2092420325","https://openalex.org/W2094145140","https://openalex.org/W2099651626","https://openalex.org/W2101187042","https://openalex.org/W2104943417","https://openalex.org/W2108623890","https://openalex.org/W2114234483","https://openalex.org/W2130360607","https://openalex.org/W2136717834","https://openalex.org/W2136939531","https://openalex.org/W2140743414","https://openalex.org/W2149881251","https://openalex.org/W2151993017","https://openalex.org/W2313722618","https://openalex.org/W2317747468","https://openalex.org/W2326670558","https://openalex.org/W2327021338","https://openalex.org/W2328088879","https://openalex.org/W2329367218","https://openalex.org/W2332893944","https://openalex.org/W3143879557"],"related_works":["https://openalex.org/W2561921067","https://openalex.org/W2130360607","https://openalex.org/W2754120640","https://openalex.org/W4392130743","https://openalex.org/W4386572055","https://openalex.org/W3198270392","https://openalex.org/W3013800662","https://openalex.org/W4386711895","https://openalex.org/W2074445234","https://openalex.org/W2794505765"],"abstract_inverted_index":{"A":[0],"framework":[1],"en-Mg2(dobpdc)":[2],"(1-en;":[3],"en":[4,12,32,157],"=":[5],"ethylenediamine)":[6],"functionalized":[7],"with":[8,182],"the":[9,25,84,114,148,153,160,171],"primary":[10],"amine":[11],"was":[13],"prepared":[14],"via":[15],"postmodification.":[16],"From":[17],"synchrotron":[18],"PXRD":[19],"data,":[20],"it":[21],"is":[22,42,81,106,136,220],"revealed":[23],"that":[24,147,206],"cell":[26],"parameters":[27],"change":[28],"upon":[29],"grafting":[30],"of":[31,40,88,96,122,125,150,156,162,168,175,201],"and":[33,51,54,177],"CO2":[34,38,70,85,94,104,128,151,169,185,196,202,216],"uptake.":[35],"The":[36,93,119,198,213],"adsorbed":[37],"amount":[39,116],"1-en":[41,66,97,126,204,219],"4.57":[43],"mmol":[44,58,73,108],"g\u22121":[45,59,109],"(16.7":[46],"wt%)":[47,61,76],"at":[48,62,77,98,170],"25":[49],"\u00b0C":[50],"1":[52],"bar":[53],"decreases":[55],"to":[56,83,102,131,159,225],"3.00":[57],"(11.7":[60],"150":[63],"\u00b0C.":[64],"Noticeably,":[65],"shows":[67],"a":[68,89,163],"significant":[69],"uptake":[71,217],"(3.62":[72],"g\u22121,":[74],"13.7":[75],"0.15":[78],"bar,":[79],"which":[80,112,135,187],"comparable":[82],"partial":[86],"pressure":[87],"post-combustion":[90],"flue":[91,178],"gas.":[92],"capacity":[95],"0.39":[99],"mbar,":[100],"close":[101],"atmospheric":[103],"concentration,":[105],"2.83":[107],"(11.1":[110],"wt%),":[111],"marks":[113],"highest":[115],"among":[117],"MOFs.":[118],"isosteric":[120],"heat":[121],"adsorption":[123,149,199],"(\u2212Qst)":[124],"in":[127,195,203,207,215],"capture":[129],"corresponds":[130],"49\u201351":[132],"kJ":[133,142],"mol\u22121,":[134],"supported":[137],"by":[138],"DFT":[139],"calculations":[140],"(\u221252.8":[141],"mol\u22121).":[143],"These":[144],"results":[145],"suggest":[146],"onto":[152],"free":[154],"amines":[155],"leads":[158],"formation":[161],"carbamic":[164],"acid.":[165],"Adsorption\u2013desorption":[166],"cyclings":[167],"real":[172],"dilute":[173],"concentrations":[174],"air":[176],"gas":[179],"are":[180],"established":[181],"almost":[183],"retaining":[184],"capacities,":[186],"could":[188],"provide":[189],"superior":[190],"potential":[191],"for":[192,218],"practical":[193],"application":[194],"capture.":[197],"rate":[200],"exceeds":[205],"some":[208],"other":[209],"tested":[210],"porous":[211],"materials.":[212],"recyclability":[214],"maintained":[221],"even":[222],"after":[223],"exposure":[224],"humidity.":[226]},"counts_by_year":[{"year":2026,"cited_by_count":32},{"year":2025,"cited_by_count":37},{"year":2024,"cited_by_count":16},{"year":2023,"cited_by_count":32},{"year":2022,"cited_by_count":24},{"year":2021,"cited_by_count":30},{"year":2020,"cited_by_count":26},{"year":2019,"cited_by_count":38},{"year":2018,"cited_by_count":24},{"year":2017,"cited_by_count":19},{"year":2016,"cited_by_count":22},{"year":2015,"cited_by_count":23},{"year":2014,"cited_by_count":9}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2016-06-24T00:00:00"}