{"id":"https://openalex.org/W2025282943","doi":"https://doi.org/10.1021/ic00302a005","title":"A general synthetic route to the dirhenium octahydrides Re2H8(PR3)4 from the triply bonded complexes Re2Cl4(PR3)4. An unexpected structure for the complex Re2H8(dppm)2 (dppm = Ph2PCH2PPh2)","display_name":"A general synthetic route to the dirhenium octahydrides Re2H8(PR3)4 from the triply bonded complexes Re2Cl4(PR3)4. An unexpected structure for the complex Re2H8(dppm)2 (dppm = Ph2PCH2PPh2)","publication_year":1989,"publication_date":"1989-02-01","ids":{"openalex":"https://openalex.org/W2025282943","doi":"https://doi.org/10.1021/ic00302a005","mag":"2025282943"},"language":"en","primary_location":{"id":"doi:10.1021/ic00302a005","doi":"https://doi.org/10.1021/ic00302a005","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic00302a005","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5057330382","display_name":"Phillip Edward Fanwick","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Phillip E. Fanwick","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5050879705","display_name":"Dawn R. Root","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Dawn R. Root","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5103682195","display_name":"Richard A. Walton","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Richard A. Walton","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.4688,"has_fulltext":false,"cited_by_count":16,"citation_normalized_percentile":{"value":0.76186294,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":"28","issue":"3","first_page":"395","last_page":"397"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9359999895095825,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9359999895095825,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.025699999183416367,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.014399999752640724,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/diphosphine-ligands","display_name":"diphosphine ligands","score":0.7139999866485596},{"id":"https://openalex.org/keywords/dppm","display_name":"dppm","score":0.847000002861023},{"id":"https://openalex.org/keywords/hydride-complexes","display_name":"hydride complexes","score":0.4830000102519989},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.6140000224113464},{"id":"https://openalex.org/keywords/phosphine-ligands","display_name":"phosphine ligands","score":0.4880000054836273}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9886034727096558},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.4709171950817108},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4525458514690399},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.35421010851860046},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.34950998425483704}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ic00302a005","doi":"https://doi.org/10.1021/ic00302a005","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic00302a005","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2950763278","https://openalex.org/W1971754027","https://openalex.org/W2074344615","https://openalex.org/W3020270595","https://openalex.org/W3019742486","https://openalex.org/W2605363786","https://openalex.org/W3138921338","https://openalex.org/W2953096251","https://openalex.org/W2063078487","https://openalex.org/W7034334082"],"abstract_inverted_index":{"ADVERTISEMENT":[0],"RETURN":[1],"TO":[2],"ISSUEPREVArticleNEXTA":[3],"general":[4],"synthetic":[5],"route":[6],"to":[7,91,96],"the":[8,13,22,66,97,102,131,142,155,158,163,170,176],"dirhenium":[9],"octahydrides":[10],"Re2H8(PR3)4":[11],"from":[12],"triply":[14],"bonded":[15],"complexes":[16],"Re2Cl4(PR3)4.":[17],"An":[18],"unexpected":[19],"structure":[20],"for":[21,162],"complex":[23],"Re2H8(dppm)2":[24],"(dppm":[25],"=":[26],"Ph2PCH2PPh2)Phillip":[27],"E.":[28],"Fanwick,":[29],"Dawn":[30],"R.":[31],"Root,":[32],"and":[33,79,84,113,157,174,190,192],"Richard":[34],"A.":[35],"WaltonCite":[36],"this:":[37],"Inorg.":[38],"Chem.":[39],"1989,":[40],"28,":[41],"3,":[42],"395\u2013397Publication":[43],"Date":[44],"(Print):February":[45],"1,":[46],"1989Publication":[47],"History":[48],"Published":[49],"online1":[50],"May":[51],"2002Published":[52],"inissue":[53],"1":[54],"February":[55],"1989https://pubs.acs.org/doi/10.1021/ic00302a005https://doi.org/10.1021/ic00302a005research-articleACS":[56],"PublicationsRequest":[57],"reuse":[58],"permissionsArticle":[59],"Views78Altmetric-Citations6LEARN":[60],"ABOUT":[61],"THESE":[62],"METRICSArticle":[63],"Views":[64],"are":[65,88,101],"COUNTER-compliant":[67],"sum":[68],"of":[69,104,130],"full":[70],"text":[71],"article":[72,136],"downloads":[73],"since":[74],"November":[75],"2008":[76],"(both":[77],"PDF":[78],"HTML)":[80],"across":[81],"all":[82],"institutions":[83],"individuals.":[85],"These":[86],"metrics":[87],"regularly":[89],"updated":[90,114],"reflect":[92],"usage":[93],"leading":[94],"up":[95],"last":[98],"few":[99],"days.Citations":[100],"number":[103],"other":[105],"articles":[106],"citing":[107],"this":[108],"article,":[109],"calculated":[110],"by":[111],"Crossref":[112,120],"daily.":[115],"Find":[116,166],"more":[117,167],"information":[118,168],"about":[119,154],"citation":[121],"counts.The":[122],"Altmetric":[123,171],"Attention":[124,172],"Score":[125,173],"is":[126,178],"a":[127,134,147],"quantitative":[128],"measure":[129],"attention":[132],"that":[133],"research":[135],"has":[137],"received":[138],"online.":[139],"Clicking":[140],"on":[141,169],"donut":[143],"icon":[144],"will":[145],"load":[146],"page":[148],"at":[149],"altmetric.com":[150],"with":[151,186],"additional":[152],"details":[153],"score":[156,177],"social":[159],"media":[160],"presence":[161],"given":[164],"article.":[165],"how":[175],"calculated.":[179],"Share":[180,195],"Add":[181],"toView":[182],"InAdd":[183],"Full":[184],"Text":[185],"ReferenceAdd":[187],"Description":[188],"ExportRISCitationCitation":[189],"abstractCitation":[191],"referencesMore":[193],"Options":[194],"onFacebookTwitterWechatLinked":[196],"InRedditEmail":[197],"Other":[198],"access":[199],"optionsGet":[200],"e-AlertscloseSupporting":[201],"Info":[202],"(1)\u00bbSupporting":[203],"Information":[204,206],"Supporting":[205],"Get":[207],"e-Alerts":[208]},"counts_by_year":[{"year":2013,"cited_by_count":1}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}