{"id":"https://openalex.org/W2024919695","doi":"https://doi.org/10.1080/026782998207361","title":"Calorimetric study of the relationship between molecular structure and liquid crystallinity of rod-like mesogens II. Heat capacities and phase transitions of 4-(trans-4-propylcyclohexyl)benzonitrile","display_name":"Calorimetric study of the relationship between molecular structure and liquid crystallinity of rod-like mesogens II. Heat capacities and phase transitions of 4-(trans-4-propylcyclohexyl)benzonitrile","publication_year":1998,"publication_date":"1998-02-01","ids":{"openalex":"https://openalex.org/W2024919695","doi":"https://doi.org/10.1080/026782998207361","mag":"2024919695"},"language":"en","primary_location":{"id":"doi:10.1080/026782998207361","doi":"https://doi.org/10.1080/026782998207361","is_oa":false,"landing_page_url":"https://doi.org/10.1080/026782998207361","pdf_url":null,"source":{"id":"https://openalex.org/S15647332","display_name":"Liquid Crystals","issn_l":"0267-8292","issn":["0267-8292","1366-5855"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Liquid Crystals","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111770663","display_name":"Shuichi Asahina","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"S. ASAHINA","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111858905","display_name":"Michio Sorai","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"M. SORAI","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5086374136","display_name":"Rudolf Eidenschink","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"R. EIDENSCHINK","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.5546,"has_fulltext":false,"cited_by_count":8,"citation_normalized_percentile":{"value":0.61610432,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":93},"biblio":{"volume":"24","issue":"2","first_page":"201","last_page":"210"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10306","display_name":"Liquid Crystal Research Advancements","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10306","display_name":"Liquid Crystal Research Advancements","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12852","display_name":"Chemical Thermodynamics and Molecular Structure","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10474","display_name":"Material Dynamics and Properties","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/rod-like-mesogens","display_name":"rod-like mesogens","score":0.9670000076293945},{"id":"https://openalex.org/keywords/nematic-isotropic-transition","display_name":"nematic-isotropic transition","score":0.7570000290870667},{"id":"https://openalex.org/keywords/molar-heat-capacity","display_name":"molar heat capacity","score":0.9020000100135803},{"id":"https://openalex.org/keywords/heat-of-fusion","display_name":"heat of fusion","score":0.6809999942779541},{"id":"https://openalex.org/keywords/transition-entropy","display_name":"transition entropy","score":0.7319999933242798},{"id":"https://openalex.org/keywords/mesophase-stability","display_name":"mesophase stability","score":0.9390000104904175}],"concepts":[{"id":"https://openalex.org/C13274807","wikidata":"https://www.wikidata.org/wiki/Q203989","display_name":"Liquid crystal","level":2,"score":0.8606990575790405},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.7448394298553467},{"id":"https://openalex.org/C129564387","wikidata":"https://www.wikidata.org/wiki/Q484790","display_name":"Enthalpy of fusion","level":3,"score":0.6775813102722168},{"id":"https://openalex.org/C3288061","wikidata":"https://www.wikidata.org/wiki/Q161064","display_name":"Enthalpy","level":2,"score":0.6676182746887207},{"id":"https://openalex.org/C178017875","wikidata":"https://www.wikidata.org/wiki/Q10328910","display_name":"Mesogen","level":4,"score":0.6345001459121704},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.6173776984214783},{"id":"https://openalex.org/C112964491","wikidata":"https://www.wikidata.org/wiki/Q213659","display_name":"Supercooling","level":2,"score":0.6026403903961182},{"id":"https://openalex.org/C38139870","wikidata":"https://www.wikidata.org/wiki/Q899029","display_name":"Entropy of fusion","level":4,"score":0.5456883907318115},{"id":"https://openalex.org/C60205243","wikidata":"https://www.wikidata.org/wiki/Q179388","display_name":"Heat capacity","level":2,"score":0.5324799418449402},{"id":"https://openalex.org/C149288129","wikidata":"https://www.wikidata.org/wiki/Q185357","display_name":"Phase transition","level":2,"score":0.5173441767692566},{"id":"https://openalex.org/C13530604","wikidata":"https://www.wikidata.org/wiki/Q15318","display_name":"Melting point","level":2,"score":0.5104402899742126},{"id":"https://openalex.org/C3535393","wikidata":"https://www.wikidata.org/wiki/Q3333391","display_name":"Mesophase","level":3,"score":0.4647480845451355},{"id":"https://openalex.org/C2779953769","wikidata":"https://www.wikidata.org/wiki/Q412567","display_name":"Benzonitrile","level":2,"score":0.44866806268692017},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.4117535948753357},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2312006950378418},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.11296790838241577},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.0},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0},{"id":"https://openalex.org/C2994273327","wikidata":"https://www.wikidata.org/wiki/Q203989","display_name":"Liquid crystalline","level":3,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1080/026782998207361","doi":"https://doi.org/10.1080/026782998207361","is_oa":false,"landing_page_url":"https://doi.org/10.1080/026782998207361","pdf_url":null,"source":{"id":"https://openalex.org/S15647332","display_name":"Liquid Crystals","issn_l":"0267-8292","issn":["0267-8292","1366-5855"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Liquid Crystals","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":15,"referenced_works":["https://openalex.org/W22341996","https://openalex.org/W1964146155","https://openalex.org/W1966658873","https://openalex.org/W1976372669","https://openalex.org/W1991150619","https://openalex.org/W1992783779","https://openalex.org/W2008634851","https://openalex.org/W2036902820","https://openalex.org/W2054078748","https://openalex.org/W2058785398","https://openalex.org/W2059172130","https://openalex.org/W2111811356","https://openalex.org/W2163542599","https://openalex.org/W2321125459","https://openalex.org/W2727958001"],"related_works":["https://openalex.org/W1991150619","https://openalex.org/W1976516103","https://openalex.org/W2144922151","https://openalex.org/W2055856542","https://openalex.org/W2002360054","https://openalex.org/W2005730462","https://openalex.org/W1986922675","https://openalex.org/W2051580101","https://openalex.org/W1981869158","https://openalex.org/W2009195648"],"abstract_inverted_index":{"The":[0,42,98],"molar":[1,85,99],"heat":[2,86],"capacity":[3],"of":[4,11,103,111],"the":[5,63,95,135,143,154],"rod-like":[6],"compound":[7],"4-(trans-4-propylcyclohexyl)benzonitrile":[8],"(3-CBCN),":[9],"purity":[10],"99.8mol%,":[12],"has":[13,138],"been":[14,89,139],"measured":[15,90],"with":[16,153],"an":[17],"adiabatic":[18],"calorimeter":[19],"at":[20,47],"temperatures":[21],"between":[22,124],"15":[23],"and":[24,33,38,44,53,70,100,114,127],"385K.":[25],"3-CBCN":[26,78,104],"is":[27],"a":[28,80,122],"nematogenic":[29],"mesogen,":[30],"whose":[31,84],"melting":[32,96],"clearing":[34],"points":[35],"are":[36,49,66,105],"316.33":[37],"319.09":[39],"K,":[40],"respectively.":[41,77],"enthalpy":[43,145],"entropy":[45],"gained":[46],"fusion":[48],"20.4":[50],"kJmol":[51,68],"-1":[52,57,69,74,76],"64.4":[54],"J":[55,72],"K":[56,73,93],"mol":[58,75],"-1,":[59],"respectively;":[60],"those":[61,110],"for":[62,134],"nematic-to-isotropic":[64,136],"transition":[65,101,137,144],"1.1":[67],"3.5":[71],"exhibits":[79],"supercooled":[81],"nematic":[82],"phase,":[83],"capacities":[87],"have":[88],"from":[91],"25":[92],"below":[94],"point.":[97],"entropies":[102],"discussed":[106],"in":[107],"relation":[108],"to":[109,120,141,148],"4-propylbiphenyl-4-carbonitrile":[112],"(3-BBCN)":[113],"trans,trans-4'-propylbicyclohexyl-":[115],"4-carbonitrile":[116],"(3-CCCN).":[117],"There":[118],"seems":[119],"exist":[121],"correlation":[123],"these":[125],"values":[126],"mesophase":[128],"stability.":[129],"Finally,":[130],"Eidenschink's":[131],"theoretical":[132],"model":[133,150],"applied":[140],"3-CBCN;":[142],"estimated":[146],"according":[147],"this":[149],"agrees":[151],"well":[152],"observed":[155],"value.":[156]},"counts_by_year":[{"year":2017,"cited_by_count":1}],"updated_date":"2026-08-15T07:11:24.734988","created_date":"2016-06-24T00:00:00"}