{"id":"https://openalex.org/W2023979150","doi":"https://doi.org/10.1021/ic0515002","title":"Linear-Type S-Bridged Triruthenium Complexes with Aliphatic Aminothiolate Ligands: Synthesis, Characterization, and Properties","display_name":"Linear-Type S-Bridged Triruthenium Complexes with Aliphatic Aminothiolate Ligands: Synthesis, Characterization, and Properties","publication_year":2005,"publication_date":"2005-12-06","ids":{"openalex":"https://openalex.org/W2023979150","doi":"https://doi.org/10.1021/ic0515002","mag":"2023979150","pmid":"https://pubmed.ncbi.nlm.nih.gov/16390081"},"language":"en","primary_location":{"id":"doi:10.1021/ic0515002","doi":"https://doi.org/10.1021/ic0515002","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic0515002","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5036924040","display_name":"Noriyuki Matsuura","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Noriyuki Matsuura","raw_affiliation_strings":["Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan","institution_ids":["https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021195091","display_name":"A. Igashira-Kamiyama","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Asako Igashira-Kamiyama","raw_affiliation_strings":["Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan","institution_ids":["https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110028584","display_name":"Tatsuya Kawamoto","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Tatsuya Kawamoto","raw_affiliation_strings":["Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan","institution_ids":["https://openalex.org/I98285908"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5090678127","display_name":"Takumi Konno","orcid":"https://orcid.org/0000-0003-4612-5418","observed_orcids":["https://orcid.org/0000-0003-4612-5418"]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Takumi Konno","raw_affiliation_strings":["Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan","institution_ids":["https://openalex.org/I98285908"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5090678127"],"corresponding_institution_ids":["https://openalex.org/I98285908"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.1142,"has_fulltext":false,"cited_by_count":11,"citation_normalized_percentile":{"value":0.74433201,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":95},"biblio":{"volume":"45","issue":"1","first_page":"401","last_page":"408"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.4097000062465668,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.4097000062465668,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.22599999606609344,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.16539999842643738,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/triruthenium-complexes","display_name":"triruthenium complexes","score":0.9729999899864197},{"id":"https://openalex.org/keywords/cysteamine","display_name":"cysteamine","score":0.9869999885559082},{"id":"https://openalex.org/keywords/cysteine","display_name":"cysteine","score":0.5839999914169312},{"id":"https://openalex.org/keywords/optical-resolution","display_name":"optical resolution","score":0.7580000162124634},{"id":"https://openalex.org/keywords/one-electron-redox","display_name":"one-electron redox","score":0.847000002861023},{"id":"https://openalex.org/keywords/spin-ground-state","display_name":"spin ground state","score":0.7120000123977661},{"id":"https://openalex.org/keywords/electrochemistry","display_name":"electrochemistry","score":0.7480000257492065},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.6380000114440918}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9524233341217041},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.6050716042518616},{"id":"https://openalex.org/C198819137","wikidata":"https://www.wikidata.org/wiki/Q188884","display_name":"Octahedron","level":3,"score":0.5940070152282715},{"id":"https://openalex.org/C124668440","wikidata":"https://www.wikidata.org/wiki/Q2305173","display_name":"Chirality (physics)","level":5,"score":0.5846033096313477},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.5305407643318176},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.49886584281921387},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.4670174717903137},{"id":"https://openalex.org/C486523","wikidata":"https://www.wikidata.org/wiki/Q494483","display_name":"Enantiomer","level":2,"score":0.46460217237472534},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.43434110283851624},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.4162561595439911},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.2782824635505676},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.13604918122291565},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0774838924407959},{"id":"https://openalex.org/C52703039","wikidata":"https://www.wikidata.org/wiki/Q5101837","display_name":"Chiral symmetry breaking","level":3,"score":0.0},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.0},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.0},{"id":"https://openalex.org/C7602139","wikidata":"https://www.wikidata.org/wiki/Q6718","display_name":"Quark","level":2,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C20621625","wikidata":"https://www.wikidata.org/wiki/Q6961432","display_name":"Nambu\u2013Jona-Lasinio model","level":4,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ic0515002","doi":"https://doi.org/10.1021/ic0515002","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic0515002","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:16390081","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/16390081","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":61,"referenced_works":["https://openalex.org/W308142229","https://openalex.org/W1963841821","https://openalex.org/W1965047546","https://openalex.org/W1966465995","https://openalex.org/W1968265760","https://openalex.org/W1968440159","https://openalex.org/W1974413999","https://openalex.org/W1976680570","https://openalex.org/W1981362565","https://openalex.org/W1983453208","https://openalex.org/W1983616074","https://openalex.org/W1983794418","https://openalex.org/W1988980471","https://openalex.org/W1992189170","https://openalex.org/W1993020230","https://openalex.org/W1994371315","https://openalex.org/W1997906442","https://openalex.org/W1998406983","https://openalex.org/W1999087548","https://openalex.org/W1999389997","https://openalex.org/W2003384383","https://openalex.org/W2007673706","https://openalex.org/W2010489308","https://openalex.org/W2015734350","https://openalex.org/W2016299230","https://openalex.org/W2019937607","https://openalex.org/W2023530327","https://openalex.org/W2028398654","https://openalex.org/W2029154309","https://openalex.org/W2035497934","https://openalex.org/W2037493344","https://openalex.org/W2039089461","https://openalex.org/W2039354895","https://openalex.org/W2039727005","https://openalex.org/W2041095269","https://openalex.org/W2052350627","https://openalex.org/W2056961730","https://openalex.org/W2064010595","https://openalex.org/W2064148115","https://openalex.org/W2064389925","https://openalex.org/W2064720519","https://openalex.org/W2065209031","https://openalex.org/W2070034178","https://openalex.org/W2072150184","https://openalex.org/W2081912906","https://openalex.org/W2082461836","https://openalex.org/W2084519732","https://openalex.org/W2088631967","https://openalex.org/W2088914683","https://openalex.org/W2088956048","https://openalex.org/W2089436752","https://openalex.org/W2092455636","https://openalex.org/W2113813397","https://openalex.org/W2114532108","https://openalex.org/W2116718906","https://openalex.org/W2145040665","https://openalex.org/W2327413059","https://openalex.org/W2521655760","https://openalex.org/W2538810434","https://openalex.org/W2952734099","https://openalex.org/W3137233545"],"related_works":["https://openalex.org/W1973655694","https://openalex.org/W2092455636","https://openalex.org/W2521655760","https://openalex.org/W2332529186","https://openalex.org/W2102386528","https://openalex.org/W1983453208","https://openalex.org/W2056443963","https://openalex.org/W2131502598","https://openalex.org/W2350374608","https://openalex.org/W2045060447"],"abstract_inverted_index":{"Treatment":[0],"of":[1,22,37,46,61,81,151,163,179],"[RuCl(2)(DMSO)(4)]":[2],"with":[3,24,55,129,140],"2-aminoethanethiol":[4],"(Haet)":[5],"in":[6,27,108,202],"ethanol":[7],"gave":[8],"a":[9,34,75,113,144],"dicationic":[10],"triruthenium":[11,116,153],"complex,":[12,50,191],"[Ru[Ru(aet)(3)](2)]Cl(2)":[13],"([1]Cl(2)).":[14],"Complex":[15],"[1]Cl(2)":[16],"was":[17,31,63,194],"also":[18,209],"obtained":[19],"by":[20,71,87,99,205],"treatment":[21],"RuCl(3).nH(2)O":[23,197],"excess":[25,199],"Haet":[26],"water.":[28],"When":[29],"[1](2+)":[30,135,172],"chromatographed":[32],"on":[33,121,160],"cation-exchange":[35],"column":[36],"SP-Sephadex":[38],"C-25,":[39],"meso":[40],"(DeltaLambda)":[41],"and":[42,68,83,125,136,165,173,183,198],"racemic":[43,59],"(DeltaDelta/LambdaLambda)":[44],"isomers":[45,70],"the":[47,93,122,130,149,152,161],"corresponding":[48,189],"tricationic":[49],"[Ru[Ru(aet)(3)](2)](3+)":[51],"([2](3+)),":[52],"were":[53,85,158],"eluted":[54],"aqueous":[56],"NaNO(3).":[57],"The":[58,78,118,188],"isomer":[60],"[2](3+)":[62,137,174],"optically":[64],"resolved":[65],"into":[66],"DeltaDelta":[67],"LambdaLambda":[69],"using":[72],"[Sb(2)(R,R-tartrato)(2)](2-)":[73],"as":[74],"resolving":[76],"agent.":[77],"molecular":[79],"structures":[80,157],"DeltaLambda-":[82],"DeltaDelta/LambdaLambda-[2](NO(3))(3)":[84],"determined":[86],"X-ray":[88],"crystallography.":[89],"In":[90],"these":[91],"complexes,":[92],"central":[94],"Ru":[95],"atom":[96],"is":[97,208],"coordinated":[98],"six":[100],"thiolato":[101],"groups":[102],"from":[103,196],"two":[104],"terminal":[105],"fac-(S)-[Ru(aet)(3)]":[106],"units":[107],"an":[109],"octahedral":[110],"geometry,":[111],"forming":[112],"linear-type":[114],"S-bridged":[115],"structure.":[117,154],"spectroelectrochemical":[119],"studies":[120],"electronic":[123,156],"absorption":[124],"CD":[126],"spectra,":[127],"together":[128],"electrochemical":[131],"studies,":[132],"demonstrated":[133],"that":[134,171],"are":[138],"interconvertible":[139],"each":[141],"other":[142],"through":[143],"one-electron":[145],"redox":[146],"process,":[147],"retaining":[148],"chirality":[150],"Their":[155],"investigated":[159],"basis":[162],"EPR":[164],"magnetic":[166],"susceptibility":[167],"measurements,":[168],"which":[169,193],"indicated":[170],"have":[175],"spin":[176],"ground":[177],"states":[178],"S(t)":[180,184],"=":[181,185],"0":[182],"1/2,":[186],"respectively.":[187],"L-cysteinato":[190],"[Ru[Ru(L-cys-N,S)(3)](2)](3-),":[192],"formed":[195],"L-cysteine":[200],"(L-H(2)cys)":[201],"water":[203],"followed":[204],"air":[206],"oxidation,":[207],"presented.":[210]},"counts_by_year":[{"year":2022,"cited_by_count":1},{"year":2012,"cited_by_count":2}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}